Author(s)

Adnan A. S. El Khaldy^1*, Alaa M. Abu Shanab², Yannic Boni¹

¹Department of Physics, Chemistry, and Mathematics, College of Engineering, Technology and Physical Sciences, Alabama A & M University, Normal, AL, USA.
²Chemistry Department, Al-Aqsa University, Gaza, Palestine.

A series of new complexes, CpTiCl[S₂P(OR)₂]₂ (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S₂POGO]₂ (where G) –CH₂CMe₂CH₂-, -CMe₂CMe₂-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl or -alkylene dithiophosphoric acid to cyclopentadienyl titanium trichloride in 1:2 molar ratio and refluxed in benzene solution. The new compounds were characterized by molecular weight measurements elemental analyses and spectroscopic studies (¹H, ¹³C, and ³¹P NMR, and in-frared). We suggest a distorted tetrahedron structure of these new complexes and the dithioligand behaves as bidentate ligand.

Chloro Cyclopentadienyl Titanium (IV) Bis Dialkyl, Alkylene Dithiophos-phate

Khaldy, A. , Shanab, A. and Boni, Y. (2017) Synthesis and Spectroscopic Characterization of Eight Chloro Cyclopentadienyl Titanium Bis (O, O-Dialkyl and Alkylene Dithiophosphate) Compounds. International Journal of Organic Chemistry, 7, 145-152. doi: 10.4236/ijoc.2017.72012.