Based on the continuation of our past study, the present analysis is conducted to examine recent effects of the urbanization process occurring over the entire district of Rome. Overlays of ALOS AVNIR-2 and SENTINEL-2A satellite images, collected over a 6 years period, were validated via Geographic Information System (GIS) techniques, in a particular procedure applied to urban land and agricultural transformations. The use of Copernicus SENTINEL-2A imagery has improved the previous results on urban processes, by reducing the uncertainty of the discrimination of land cover classes and facilitating the photo-interpretation. Statistical analysis was performed via the Urban Area Profile index in order to quantify the sprawl phenomenon, by defining several landscape metrics. This work, to be enriched in the future by means of complementary information available from Copernicus radar sensors, like the one onboard Sentinel-1, completes the series of observations on land use published by the Italian National Institute for Environmental Protection and Research, which stopped back in 2008.