Determination of Five (5) Possible Contaminants in Recycled Cardboard Packages and Food Simulants Using Ultrasound Assisted Extraction Coupled to GC-MS - Materials Sciences and Applications

MSA > Vol.5 No.10, August 2014

Volume 5, Issue 10 (August 2014)

ISSN Print: 2153-117X ISSN Online: 2153-1188

Google-based Impact Factor: 0.97 Citations

Determination of Five (5) Possible Contaminants in Recycled Cardboard Packages and Food Simulants Using Ultrasound Assisted Extraction Coupled to GC-MS ()

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DOI: 10.4236/msa.2014.510075 4,122 Downloads 5,548 Views Citations

Author(s)

Ioanna-Efpraxia Parigoridi, Konstantoula Akrida-Demertzi, Panagiotis G. Demertzis

Affiliation(s)

Laboratory of Food Chemistry, Department of Chemistry, University of Ioannina, Ioannina, Greece.

ABSTRACT

A modified analytical procedure has been developed to test for 5 organic pollutants [benzophenone, 2 diisopropylnaphthalenes (DIPNs) {2,6- and 2,7-diisopropylnapthalene} and 2 hydrogenated terphenyls (HTPs) {m-terphenyl and o-terphenyl}] that can be found as residues in recycled cardboards intended for use as food packaging materials and to test for migration levels of these compounds in a food simulant (Tenax). A main objective was to develop a modified rapid and reliable method for the identification and quantification of these compounds at low concentrations. The method was based on ultrasound-assisted solvent extraction (UAE) followed by gas chromatography-mass spectrometry (GC-MS) analysis. The developed method was applied to analyze 3 commercially available recycled carton board food-packaging materials and also to study the potential migration of the 5 organic pollutants from these materials into Tenax to check if these recycled cardboards can be considered as suitable for use in direct contact with foodstuffs. The limits of detection (LODs) of standard solutions of the 5 compounds were determined at a signal-to-noise ratio of 3. The LODs and the limits of quantification (LOQs) of examined pollutants ranged between 0.005 to 0.5 mg/kg, and 0.1 to 1 mg/kg, respectively. The extremely low amounts of most contaminants that migrate from packaging materials to Tenax indicate that the recycled cardboards tested can be safely used for direct food contact applications.

KEYWORDS

Gas Chromatography-Mass Spectrometry, Ultrasound-Assisted Solvent Extraction, Organic Pollutants, Recycled Cardboard

Share and Cite:

Parigoridi, I. , Akrida-Demertzi, K. and Demertzis, P. (2014) Determination of Five (5) Possible Contaminants in Recycled Cardboard Packages and Food Simulants Using Ultrasound Assisted Extraction Coupled to GC-MS. Materials Sciences and Applications, 5, 745-751. doi: 10.4236/msa.2014.510075.

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