American Journal of Analytical Chemistry
Volume 4, Issue 9 (September 2013)
ISSN Print: 2156-8251 ISSN Online: 2156-8278
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Non-Isothermal Degradation and Kinetics Studies of Some Quinaldine Azo Dye Complexes ()
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ABSTRACT
4-(R-Phenylazo)-2-methyl quinoline derivatives form (1:1) complexes with nickel chloride, nickel acetate and copper acetate which were syntheses. The three complexes are non-electrolyte in dimethylsulfoxide (DMF). The results of electronic and magnetic measurements show that these complexes are of octahedral structures. The oxygen and nitrogen donate their lone-pair electrons to metal ion to form chelates with formula [MLRm.nH2O]. The relative stabilities of the complexes have been calculated from TG curve using Coats-Redfern and Ozawa methods.
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