Rural households represent, by far, the greater percentage of dwellings globally without access to the electricity supply. For reasons of low loads, distance from the grid and speed of deployment, distributed energy systems are now considered viable options for rural electrification. This paper presents the status of solar Photovoltaic (PV) in Nigeria and discusses the way forward for aggressive PV penetration in Nigeria’s energy mix, especially in rural communities. At present, distributed PV penetration in Nigeria is comparatively low based on the International Energy Association’s recommended PV market potential. This shows that there is a gap between the government’s policy targets and reality. The solar resource potential across the six geo-political zones in Nigeria is also presented, which ranges from 3.393 - 6.669 kWh/m²/day, with the Northern zones exhibiting better potentials over the Southern zones. It is shown that the levelised cost of electricity from PV system ranges from 0.387 - 0.475 $/kWh, whereas it is 0.947 US$/kWh and 0.559 US$/kWh for the diesel generator and glass-covered kerosene lamp, respectively. While this study shows that PV for rural household lighting is more affordable as compared to glass-covered kerosene lamps and fossil-fuelled generators for lighting, fiscal and energy policies for market creation are critical if PV systems are to deliver on their promise for rural electrification and climate change mitigation.