Open Journal of Inorganic Chemistry

Volume 11, Issue 2 (April 2021)

ISSN Print: 2161-7406   ISSN Online: 2161-7414

Google-based Impact Factor: 1.08  Citations  

Syntheses and Characterization of Two Novel Copper(II) Malonate Complexes Functionalized with 3,3’-Bis(pyrazolyl)pentane and 4,4’-Trimethylenedipyridine

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DOI: 10.4236/ojic.2021.112003    310 Downloads   986 Views  

ABSTRACT

Two novel copper complexes (1,2) with N,O-donor ligands were synthesized by reaction of copper(II) malonates with 3,3’-bis(pyrazolyl)pentane and 4,4’-trimethylenedipyridine in methanol at moderate temperature. These compounds were characterized by elemental analysis, UV-VIS, IR spectroscopies and powder X-ray diffraction analyses. Compound (1) melts at higher temperature (202°C) than compound (2) (100°C). The IR spectra showed typical vibrations related to C=N and C=C, characteristic of pyrazolyl and pyridine ligands.

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Djoumbissie, A. , Djampouo, A. , Fomuta, T. , Doungmo, G. , Djimassingar, G. , Kuate, A. and Ngoune, J. (2021) Syntheses and Characterization of Two Novel Copper(II) Malonate Complexes Functionalized with 3,3’-Bis(pyrazolyl)pentane and 4,4’-Trimethylenedipyridine. Open Journal of Inorganic Chemistry, 11, 43-53. doi: 10.4236/ojic.2021.112003.

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