Author(s)

Takanori Miyake¹, Tetsuo Honma², Hiroshi Arimatsu¹, Hiroto Fukunishi¹, Huimin Liu¹, Makoto Sano¹, Yuuki Kakutani¹, Mitsumasa Okada¹, Kaori Shimizu¹, Setsuo Yoshida³, Kazumasa Suetsugu³

¹Faculty of Urban and Environmental Engineering, Kansai University, Suita, Osaka, Japan.
²Japan Synchrotron Radiation Institute (JASRI), Sayo-cho, Hyogo, Japan.
³TOSOH Corporation, Shunan, Yamaguchi, Japan.

Lead dissolved in water must be removed in order not to cause diseases, especially from high pH aqueous solution. Various oxides having high specific surface area are often applied to remove lead in water media. To improve removal ability for lead species, it is necessary to understand the adsorbed structure of lead species on oxides. At first, the adsorption behavior of lead from high pH solution in the presence of Ca²⁺ and Na+ was compared. Lead and calcium species were adsorbed up to the monolayer, and the adsorption isotherm was analyzed as Langmuir-type adsorption. In the presence of Ca²⁺, the amount of removed lead was reduced. To clarify this influence of Ca²⁺, X-ray absorption spectroscopy was adopted. It was for the first time revealed that lead species at pH > 12 and pH < 10.5 differed, and that lead species adsorbed on various oxides had a similar structure.

X-Ray Absorption Spectroscopy, Water Purification, Lead Removal, Manganese Oxide, Adsorption

Miyake, T. , Honma, T. , Arimatsu, H. , Fukunishi, H. , Liu, H. , Sano, M. , Kakutani, Y. , Okada, M. , Shimizu, K. , Yoshida, S. and Suetsugu, K. (2020) X-Ray Absorption Spectroscopy Analysis of Lead Species Adsorbed on Various Oxides from High pH Solution. Journal of Environmental Protection, 11, 807-820. doi: 10.4236/jep.2020.1110050.