Processability of Biobased Thermoset Resins and Flax Fibres Reinforcements Using Vacuum Assisted Resin Transfer Moulding

Abstract


Biocomposite panels consisting of biobased thermoset resins (EP, PU, UP, and tannin) and flax fibre reinforcements were produced using the vacuum assisted resin transfer moulding process. Panels based on a conventional chemical-based resin matrix were also produced, and investigated comparatively. Rheometric analyses were performed to evaluate the suitability of these resins for liquid composite moulding. Tensile, shear, and impactbending tests have been carried out to assess the quality and mechanical performance of manufactured laminates. The impregnation quality was assessed by means of ultrasonic-C-scanning and microscopy. It turned out that the properties of the biobased composite panels made of biobased epoxy resin and a biobased UP-resin from the company Nuplex in New Zealand were onlay slightly inferior to those produced with a conventional epoxy resin. A biobased PU-resin from the company USSC in the USA developed voids during curing. A tannin-based resin containing of formaldehyde was not processable.


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J. Schuster, Q. Govignon and S. Bickerton, "Processability of Biobased Thermoset Resins and Flax Fibres Reinforcements Using Vacuum Assisted Resin Transfer Moulding," Open Journal of Composite Materials, Vol. 4 No. 1, 2014, pp. 1-11. doi: 10.4236/ojcm.2014.41001.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] M. Shibata and K. Nakai, “Preparation and Properties of Biocomposites Composed of Bio-Based Epoxy Resin, Tannin Acid, and Microfibrillated Cellulose,” Journal of Polymer Science: Part B: Polymer Physics, Vol. 48, No. 4, 2008, pp. 425-433. http://dx.doi.org/10.1002/polb.21903
[2] A. M. Stashevski and H. J. Deppe, “The Application of Tannine Resins as Adhesives for Wood Particle Boards,” HOLZ als Rohund Werkstoff, Vol. 31, No. 11, 1973, pp. 417-419.
http://dx.doi.org/10.1007/BF02613949
[3] C. Wang, L. Yang, B. Ni and L. Wang, “Thermal and Mechanical Properties of Cast Polyurethane Resin Based on Soybean Oil,” Journal of Applied Polymer Science, Vol. 112, No. 3, 2009, pp. 1122-1127.
http://dx.doi.org/10.1002/app.29537
[4] A. K. Mohanty, M. Misra and G. Hinrichsen, “Biofibres, Biodegradable Polymers and Biocomposites: An Overview,” Macromoleculare Engineering, Vol. 276, No. 3-4, 2000, pp. 1-24.
http://dx.doi.org/10.1002/(SICI)1439-2054(20000301)276:1<1::AID-MAME1>3.0.CO;2-W
[5] P. Pan, B. Zhu, T. Dong, S. Serizawa, M. Iji and Y. Inoue, “Kenaf Fiber/Poly(e-caprolactone) Biocomposite with Enhanced Crystallization Rate and Mechanical Properties,” Journal of Applied Polymer Science, Vol. 107, No. 6, 2008, pp. 3512-3519.
http://dx.doi.org/10.1002/app.27470
[6] M. J. John and S. Thomas, “Biofibres and Biocomposites,” Carbohydrate Polymers, Vol. 71, No. 3, 2008, pp. 343-364. http://dx.doi.org/10.1016/j.carbpol.2007.05.040
[7] H. Y. Cheung, K. T. Lau, Y. F. Pow, Y. Q. Zhao and D. Hui, “Biodegradation of a Silkworm Silk/PLA Composite,” Composites Part: B, Vol. 41, No. 3, 2010 pp. 223-228.
http://dx.doi.org/10.1016/j.compositesb.2009.09.004
[8] S. K. Majhi, S. K. Nayak, S. Mohanty and L. Unnikrishnan, “Mechanical and Fracture Behavior of Banana Fiber Reinforced Polylactic Acid Biocomposites,” International Journal Plastic Technology, Vol. 14, No. 1, 2010, pp. 57-75. http://dx.doi.org/10.1007/s12588-010-0010-6
[9] A. Le Duiqou, P. Davies and C. Baley, “Analyse Ducyvle de vie d’un Biocomposite,” Matériaux & Techniques, Vol. 98, No. 2, 2010, pp. 143-150.
http://dx.doi.org/10.1051/mattech/2010021
[10] R. Moriana, F. Vilaplana, S. Karlsson and A. RibesGreus, “Improved Thermo-Mechanical Properties By The Addition of Natural Fibres in Starch Based Sustainable Biocomposites,” Composites Part: A, Vol. 42, No. 1, 2011, pp. 30-40.
http://dx.doi.org/10.1016/j.compositesa.2010.10.001
[11] W. Liu, L. T. Drzal, A. K. Mohanty and M. Misra, “Influence of Processing Methods and Fiber Length on Physicalproperties of Kenaf Fiber Reinforced Soy Based Biocomposites,” Composites Part: B, Vol. 38, No. 3, 2007, pp. 352-359.
http://dx.doi.org/10.1016/j.compositesb.2006.05.003
[12] Z. Liu and S. Z. Erhan, “‘Green’ Composites and Nanocomposites from Soybean Oil,” Material Science and Engineering A, Vol. 483-484, No. 1, 2008, pp. 708-711.
http://dx.doi.org/10.1016/j.msea.2006.12.186
[13] J. Müssig, “Cotton Fibre Reinforced Thermosets versus Ramie Composites: A Comparative Study Using Petrochemicaland Agro-Based Resins,” Journal of Polymer and the Environment, Vol. 16, No. 2, 2008, pp. 94-102.
http://dx.doi.org/10.1007/s10924-008-0089-4
[14] K. Adekunle, D. Åkesson and M. Skrifvars, “Biobased Composites Prepared by Compression Molding with a Novel Thermoset Resin from Soybean Oil and a NaturalFiber Reinforcement,” Journal of Applied Polymer Sciences, Vol. 116, No. 3, 2010, pp. 1759-1765.
[15] J. T. Kim and A. N. Netravali, “Mechanical and Thermal Properties of Sisal Fiber-Reinforced Green Composites with Soy Protein/Gelatin Resins,” Journal of Biobased Materials and Bioenergy, Vol. 4, No. 4, 2010, pp. 338-345. http://dx.doi.org/10.1166/jbmb.2010.1098
[16] G. Mehta, A. K. Mohanty, K. Thayer, M. Misra and L. T. Drzal, “Novel Biocomposites Sheet Molding Compounds for Low Cost Housing Panel Applications,” Journal of Polymer and the Environment, Vol.13, No. 2, 2005, pp. 169-175. http://dx.doi.org/10.1007/s10924-005-3211-x
[17] M. A. Dweib, B. Hu, H. W. Shenton III and R. P. Wool, “Bio-Based Composite Roof Structure: Manufacturing and Processing Issues,” Composite Structures, Vol. 74, No. 4, 2006, pp. 379-388.
http://dx.doi.org/10.1016/j.compstruct.2005.04.018
[18] J. Müssig, “Karosserie aus Naturfasern und Pflanzenöl,” Kunststoffe, Vol. 97, No. 3, 2007, pp. 78-83.
[19] K. Satyanarayana and F. Wypych, “Characterization of Natural Fibers,” In: S. Fakirov and D. Bhattacharrya, Eds., Handbook of Engineering Biopolymers: Homopolymers, Blends and Composites, Hanser Gardner Publications, 2007, p. 34.
[20] T. Reußmann, “Entwicklung eines Verfahrens zur Herstellung von Langfasergranulat mit Naturfaserverstärkung,” Ph.D. Dissertation, Technische Universität Chemnitz, Chemnitz, 2003, p. 22.
[21] S. Chabba, G. F. Matthews and A. N. Netravali, “‘Green Composites Using Cross-Linked Soy Flour and Flax Yarns,” Green Chemistry, Vol. 7, No. 8, 2005, pp. 576-581. http://dx.doi.org/10.1039/b410817e
[22] S. Alix, S. Marais, C. Morvan and L. Lebrun, “Biocomposite Materials Fromflax Plants: Preparation and Properties,” Composites Part: A, Vol. 39, No. 12, 2008, pp. 1793-1801.
http://dx.doi.org/10.1016/j.compositesa.2008.08.008
[23] M. A. Dweib, B. Hu, A. O’Donnell, H. W. Shenton and R. P. Wool, “All Natural Composite Sandwich Beams for Structural Applications,” Composite Structures, Vol. 63, No. 2, 2004, pp. 147-157.
http://dx.doi.org/10.1016/S0263-8223(03)00143-0
[24] J. Schuster, M. Duhovic and D. Bhattacharyya, “Manufacturing and Processing of Polymer Composite Materials,” In: S. Fakirov and D. Bhattacharrya, Eds., Synthetic Polymer-Polymer Composites, Hanser Gardner Publications, 2012, pp. 18-24.
http://dx.doi.org/10.3139/9781569905258.001
[25] Q. Govignon, S. Bickerton, J. Morris and P.A. Kelly, “Full Field Monitoring of the Resin Flow and Laminate Properties during the Infusion Process,” Composites Part: A, Vol. 39, No. 9, 2008, pp. 1412-1426.
http://dx.doi.org/10.1016/j.compositesa.2008.05.005
[26] P. Simacek, D. Heider, J. W. Gillespie Jr. and S. Advani, “Post-Filling Flow in Vacuum Assisted Resin Transfer Molding Processes: Theoretical Analysis,” Composite Part: A, Vol. 40, No. 6-7, 2009, pp. 913-924.
http://dx.doi.org/10.1016/j.compositesa.2009.04.018
[27] S. Mekic, C. A. Ulven, I. S. Akhatov, E. Jerke and E. Kerr-Anderson, “Evaluation of In-Plane and Transverse Permeability of Flax Preformsfor Biocomposite Materials,” Journal of Biobased Materials and Bioenergy, Vol. 3, No. 2, 2009, pp. 156-164.
http://dx.doi.org/10.1166/jbmb.2009.1020
[28] K. Van de Velde and E. Baetens, “Thermal and Mechanical Properties of Flax Fibres as Potential Composite Reinforcements,” Macromoleculare Materials and Engineering, Vol. 286, No. 6, 2001, pp. 342-349.
http://dx.doi.org/10.1002/1439-2054(20010601)286:6<342::AID-MAME342>3.0.CO;2-P
[29] B. Lauke, W. Beckert and K. Schneider, “Interlaminar Shear Strength Evaluation of Curved Composite Samples,” Applied Composite Materials, Vol. 1, No. 1, 1994, pp. 267-271.
http://dx.doi.org/10.1007/BF00568283
[30] Q. Lui, T. Stuart, M. Hughes, H. H. Sharma and G. Lyons, “Structural Biocomposites from Flax-Part II: The Use of PEG and PVA as Interfacial Compatibilising Agents,” Composites: Part A, Vol. 38, No. 5, 2007, pp. 1403-1413.
http://dx.doi.org/10.1016/j.compositesa.2006.08.009
[31] J. Gassan, T. Dietz and A. Bledzki, “Effect of Silicone Interphase on the Mechanical Properties of Flax-Polyurethane Composites,” Composites Interfaces, Vol. 2, No. 7, 2000, pp. 103-115.
http://dx.doi.org/10.1163/156855400300184262

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