The Synthesis and Characterization of Arc Melted Fe1-xAlx Alloys

Abstract

The paper presents correlation study on a series of Fe1-xAlx alloy samples prepared by arc melting. All the samples show crystalline structure, irrespective of the Al content and are textured mainly along (110) direction. The particle size decreases rapidly with x particularly after x > 0.3. The corresponding magnetic measurements were obtained at room temperature using a VSM, with a maximum applied field of 14 kOe. The results show that the ferromagnetic state of the samples disappears with x, and becomes paramagnetic for alloys with x ≥ 0.4. It is also found that coercivity (Hc) and resistivity increase with x. The results were interpreted in terms of continuous change in their electronic structure i.e. overlap of the electron wave functions of the magnetic atoms with the Al electron wave function.

Share and Cite:

Rajan, S. , Shukla, R. , Kumar, A. , Vyas, A. and Brajpuriya, R. (2013) The Synthesis and Characterization of Arc Melted Fe1-xAlx Alloys. Journal of Applied Mathematics and Physics, 1, 4-8. doi: 10.4236/jamp.2013.12002.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] G. Sauthoff, “State of Intermetallics Development,” Ma terials and Corrosion, Vol. 47, No. 11, 1996, pp. 589-594. doi:10.1002/maco.19960471103
[2] H. W. Sheng, Y. H. Zhao, Z. Q. Hu and K. Lu, “Lattice Instability in the Solid State Amorphization of Fe(Al) Solid Solution by Mechanical Alloying,” Physical Re view B, Vol. 56, No. 5, 1997, pp. 2302-2305. doi:10.1103/PhysRevB.56.2302
[3] Q. Zeng and I. Baker, “Magnetic Properties and Thermal Ordering of Mechanically Alloyed Fe-40 at.% Al,” In termetallics, Vol. 14, No. 4, 2006, pp. 396-405.
[4] M. Krasnowsky and T. Kulik, “Nanocrystalline FeAl In termetallic Produced by Mechanical Alloying Followed by Hot-Pressing Consolidation,” Intermetallics, Vol. 15 No. 2, 2007, pp. 201-205. doi:10.1016/j.intermet.2006.05.008
[5] P. Pochet, E. Tominez, L. Chaffron and G. Martin, “Or der-Disorder Transformation in Fe-Al under Ball Mill ing,” Physical Review B, Vol. 52, No. 6, 1995, pp. 4006 4016. doi:10.1103/PhysRevB.52.4006
[6] A. Hernando, X. Amils, J. Nogues, S. Surinach, M. D. Baro and M. R. Ibarra, “Influence of Magnetization on the Reordering of Nanostructured Ball-Milled Fe-40 at.% Al Powders,” Physical Review B: Condensed Matter and Materials Physics, Vol. 58, No. 18, 1998, pp. R11864 R11867. doi:10.1103/PhysRevB.58.R11864
[7] E. Apinaniz, F. Plazaola, J. S. Garitaonandia, D. Martin and J. A. Jimenez, “Study of the Enhancement of the Magnetic Properties of Fe70Al30 in the Order-Disorder Transition,” Journal of Applied Physics, Vol. 93, No. 10, 2003, pp. 7649-7651. doi:10.1063/1.1544504
[8] I. Baker and E. P. George, In: S. C. Deevi and V. Sikka, Eds., Aluminides: Processing Properties and the Me chanical Properties of FeAl, Proceedings of the Interna tional Symposium on Nickel and Iron Aluminides: Proc essing, Properties and Applications, The Metallurgical Society, Warrendale, 1997, pp. 145-156.
[9] P. F. Tortorelli and J. H. DeVan, “Behavior of Iron Alu minides in Oxidizing/Sulfidizing Environments,” Materi als Science and Engineering A, Vol. 153, No. 1-2, 1992, pp. 573-577. doi:10.1016/0921-5093(92)90253-W
[10] S. C. Deevi, V. K. Sikka and C. T. Liu, “Processing, Properties and Applications of Nickiel and Iron Alu minides,” Progress in Materials Science, Vol. 42, No. 1-4, 1997, pp. 177-192. doi:10.1016/S0079-6425(97)00014-5
[11] N. S. Stoloff, “Iron Aluminides: Present Status and Future Prospects,” Materials Science and Engineering A, Vol. 258, No. 1-2, 1998, pp. 1-14. doi:10.1016/S0921-5093(98)00909-5
[12] C. T. Liu, E. P. George, P. L. Maziasz and J. H. Schnef fiel, “Recent Advances in B2 Iron Aluminide Alloys: Deformation, Fracture and Alloy Design,” Materials Sci ence and Engineering A, Vol. 258, No. 1-2, 1998, pp. 84 98.
[13] Q. Zeng and I. Baker, “Magnetic Properties and Thermal Ordering of Mechanically Alloyed Fe-40 at% Al,” Inter metallics, Vol. 14, No. 4, 2006, pp. 396-405. doi:10.1016/j.intermet.2005.07.005
[14] L. F. Kiss, D. Kaptas, J. Balogh, L. Bujdoso, T. Kemeny and L. Vincze, “Rigid Magnetic Foam-Like Behavior in Ball-Milled FeAl,” Physical Review B, Vol. 70, 2004, Ar ticle ID: 012408. doi:10.1103/PhysRevB.70.012408
[15] J. Nogues and I. K. Schuller, “Exchange Bias,” Journal of Magnetism and Magnetic Materials, Vol. 192, No. 2, 1999, pp. 203-232. doi:10.1016/S0304-8853(98)00266-2

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.