Synthesis and characterization of a ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide

Jing Chen, You-Juan Zhang, Kun-Tao Huang, Qiang Huang

College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, China.
College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, China;School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China.
School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China.

DOI: 10.4236/ojic.2013.33008                

Abstract

A ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide,

[Cd₂(NITpBA)₄(H₂O)₄] (where NITpBA = 2-(4-carboxyphenyl)4,4,5,5-tetramethyl-4,5-dihydro-imidazol-1-oxyl-3-oxide), has been synthesized and characterized. X-ray analysis reveals that the compound 1 crystallizes in the monoclinic P2₁/c (No. 14) space group, and [Cd₂(NITpBA)₄(H₂O)₄] units are linked into infinite chains by radical bridging ligands.

Keywords

Nitronyl Nitroxide; Anionic Radical;Ladder-Like Structure; Cd (II) Complex

Conflicts of Interest

The authors declare no conflicts of interest.

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