Share This Article:

Adsorption of 5.5’-Disulfonicindigotin (5.5’-DI) onto Green Coconut Fiber (Cocos nucifera L.): Kinetic and Isotherms

Full-Text HTML Download Download as PDF (Size:1357KB) PP. 37-52
DOI: 10.4236/jeas.2014.42005    2,276 Downloads   3,142 Views   Citations

ABSTRACT

Green coconut fiber (Cocos nucifera L.) has been largely used in solid-phase extraction. The effect of the initial dye concentration (1.91, 3.02 and 4.02) × 10-5 mol·L-1 and solid phase contact (SPE) time were evaluated at different temperatures (283, 298 and 313) K at pH 2. Kinetic experimental data were applied to three simplified kinetic models: pseudo-first order, pseudo-second order, and intraparticle diffusion. The adsorption of 5.5’-DI onto the solid phase showed excellent fit to the pseudo-second order model. At 283, 298 and 313 K the maximum sorption, qmax,exp, for the lowest initial concentration (Co = 1.91 × 10-5 mol·L-1) of 5.5’-DI were (5.01, 5.24 and 6.14) × 10-4 g·g-1; for Co = 3.02 × 10-5 mol·L-1 (0.93, 1.01 and 1.03) × 10-3 g·g

Cite this paper

F. Zeferino, L. , Gaubeur, I. , E. V. Suárez-Iha, M. and A. M. Freitas, P. (2014) Adsorption of 5.5’-Disulfonicindigotin (5.5’-DI) onto Green Coconut Fiber (Cocos nucifera L.): Kinetic and Isotherms. Journal of Encapsulation and Adsorption Sciences, 4, 37-52. doi: 10.4236/jeas.2014.42005.

References

[1] Santana, I.A., Ribeiro, E.P. and Iguti, A.M. (2011) Evaluation of Green Coconut (Cocos nucifera L.) Pulp for Use as Milk, Fat and Emulsifier Replacer in Ice Cream. Procedia Food Science, 1, 1447-1553.
http://dx.doi.org/10.1016/j.profoo.2011.09.214
[2] Faostat Production Crops. Coconut. (2011).
http://faostat.fao.org
[3] de Lima, A.C.A., Nascimento, R.F., de Sousa, F.F., Filho, J.M. and Oliveira, A.C. (2012) Modified Coconut Shell Fibers: A Green and Economical Sorbent for Removal of Anions from Aqueous Solution. Chemical Engineering Journal, 185-186, 274-284.
http://dx.doi.org/10.1016/j.cej.2012.01.037
[4] Silva, E.T., Souza, D.A., Machado, J.C. and Hourston, D.J. (2000) Mechanical and Thermal Characterization of Native Brazilian Coir Fiber. Journal of Applied Polymer Science, 76, 1197-1206.
[5] Rosa, M.F., Bezerra, F.C., Correia, D., Santos, F.J.S., Abreu, F.A.P. and Furtado, A.A.L. (2002) Utilizacao da Casca de Coco como Substrato Agrícola. Embrapa Agroindústria Tropical, 52, 22-26.
[6] John, M.J. and Thomas, S. (2008) Biofibres and Biocomposites. Carbohydrate Polymers, 71, 343-364.
http://dx.doi.org/10.1016/j.carbpol.2007.05.040
[7] Sriccia, N., Hawley, M.C. and Misra, M. (2008) Characterization of Natural Fiber Surfaces and Natural Fiber Composites. Composites Part A: Applied Science and Manufacturing, 39, 1632-1637.
http://dx.doi.org/10.1016/j.compositesa.2008.07.007
[8] Sousa, F.W., Moreira, S.A., Oliveira, A.G., Ribeiro, J.P., Rosa, M.F., Keukelereire, D. and Nascimento, R.F. (2010) Green Coconut Shells Applied as Adsorbent for Removal of Toxic Metal Ions Using Fixed-Bed Column Technology. Journal of Environmental Management, 91, 1634-1640.
http://dx.doi.org/10.1016/j.jenvman.2010.02.011
[9] Sousa, F.W., Moreira, S.A., Oliveira, A.G., Cavalcante, R.M., Nascimento, R.F. and Rosa, M.F. (2007) Uso da casca de coco verde como adsorbente na remocao de metais tóxicos. Química Nova, 30, 1153-1157.
http://dx.doi.org/10.1590/S0100-40422007000500019
[10] Dallago, R.M., Smaniotto, A. and de Oliveira, L.C.A. (2005) Resíduos sólidos de curtumes como adsorventes para a remocao de corantes em meio aquoso. Química Nova, 28, 433-437.
http://dx.doi.org/10.1590/S0100-40422005000300013
[11] Sequin-Frey, M. (1981) The Chemistry of Plant and Animal Dyes. Journal of Chemical Education, 58, 301-307.
http://dx.doi.org/10.1021/ed058p301
[12] Bayer, A. and Drewson, V. (1982) Darstellung von Indigblauaus Orthonitrobenzaldehyd. Berichte der Deutschen Chemischen Gesellschaft, 15, 2856-2864.
http://dx.doi.org/10.1002/cber.188201502274
[13] Kyzas, G.Z., Fu, J. and Matis, K.A. (2013) The Change from Past to Future for Adsorbent Materials in Treatment of Dyeing Wastewaters. Materials, 6, 5131-5158.
http://dx.doi.org/10.3390/ma6115131
[14] Langergren, S. (1898) Zurtheorie der sogenannten adsorption geloesterstoffe. Veternskapsakad Handlingar, 24, 1-9.
[15] Yener, J., Kopac, T., Dogu, G. and Dogu, T. (2006) Adsorption of Basic Yellow 28 from Aqueous Solutions with Clinoptilolite and Amberlite. Journal of Colloid and Interface Science, 294, 255-264.
http://dx.doi.org/10.1016/j.jcis.2005.07.040
[16] Blanchard, G., Maunaye, M. and Martim, G. (1984) Removal of Heavy Metals from Waters by Means of Natural Zeolites. Water Research, 18, 1501-1507.
http://dx.doi.org/10.1016/0043-1354(84)90124-6
[17] Annadurai, G., Juang, R.S. and Lee, D.J. (2002) Use of Cellulose-Base Wastes for Adsorption of Dyes from Aqueous Solutions. Journal of Hazardous Materials, 92, 263-274.
http://dx.doi.org/10.1016/S0304-3894(02)00017-1
[18] Langmuir, I. (1918) The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Journal of the American Chemical Society, 40, 1361-1403.
http://dx.doi.org/10.1021/ja02242a004
[19] Freundlich, H.Z. (1906) Concerning Adsorption in Solutions. Zeitschrift für Physikalische Chemie, 57, 444-448.
[20] Dubinin, M.M. and Radushkevich, L.V. (1947) Equation of the Characteristic Curve of Activated Charcoal. Proceedings of the Academy of Sciences of the USSR, Physical Chemistry Section, 55, 331-333.
[21] Brigida, A.I.S., Calado, V.M.A., Goncalves, L.R.B. and Coelho M.A.Z. (2010) Effect of Chemical Treatments on Properties of Green Coconut Fiber. Carbohydrate Polymers, 79, 832-838.
http://dx.doi.org/10.1016/j.carbpol.2009.10.005
[22] Aragao, W.M., Cruz, E.M.O. and Helvécio, J.S. (2001) Caracterizacao morfológica do fruto e química da água de coco em cultivares de coqueiro-anao. Agrotrópica, Ilhéus, 13, 49-58.
[23] Freitas, P.A.M., Iha, K., Felinto, M.C.F.C. and Suárez-Iha, M.E.V. (2008) Adsorption of di-2-pyridyl Ketone Salicyloylhydrazone on Amberlite XAD-2 and XAD-7 Resins: Characteristics and Isotherms. Journal of Colloid and Interface Science, 323, 1-5.
http://dx.doi.org/10.1016/j.jcis.2008.04.001
[24] Kavitha, D. and Namasivayam, C. (2007) Experimental and Kinetic Studies on Methylene Blue Adsorption by Coir Pith Carbon. Bioresource Technology, 98, 14-21.
http://dx.doi.org/10.1016/j.biortech.2005.12.008
[25] Zhong, Q.Q., Yue, Q.Y., Li, Q., Xu, X. and Gao, B.Y. (2011) Preparation, Characterization of Modified Wheat Residue and Its Utilization for the Anionic Dye Removal. Desalination, 267, 193-200.
http://dx.doi.org/10.1016/j.desal.2010.09.025
[26] Messina, P.V. and Schulz, P.C. (2006) Adsorption of Reactive Dyes on Titania-Silica Mesoporous Materials. Journal of Colloid and Interface Science, 299, 305-320.
http://dx.doi.org/10.1016/j.jcis.2006.01.039
[27] Dotto, G.L.,Vieira, M.L.G., Goncalves, J.O. and Pinto, L.A.A. (2011) Remocao dos corantes azul brilhante, amarelo crepúsculo e amarelo tartrazina de solucoes aquosas utilizando carvao ativado, terra ativada, terra diatomácea, quitina e quitosana: Estudos de equilíbrio e termodinamica. Química Nova, 34, 1193-1199.
http://dx.doi.org/10.1590/S0100-40422011000700017
[28] Cai, W.Q., Yu, J.G., Cheng, B., Su, B.L. and Janoriec, M. (2009) Synthesis of Boehmite Hollow Core/Shell and Hollow Microspheres via Sodium Tartrate-Mediated Phase Transformation and Their Enhanced Adsorption Performance in Water Treatment. Journal of Physical Chemistry C, 113, 14739-14746.
http://dx.doi.org/10.1021/jp904570z
[29] Antonio, P., Iha, K. and Suárez-Iha, M.E.V. (2004) Adsorption of di-2-pyridyl Ketone Salicyloylhydrazone on Silica Gel: Characteristics and Isotherms. Talanta, 64, 484-490.
http://dx.doi.org/10.1016/j.talanta.2004.03.014
[30] Ho, Y.S. and McKay, G. (1999) Pseudo-Second Order Model for Sorption Processes. Process Biochemistry, 34, 451-465.
http://dx.doi.org/10.1016/S0032-9592(98)00112-5
[31] Weber Jr., W.J., Morris, J.C. and Sanit, J. (1963) Kinetics of Adsorption on Carbon from Solution. Journal of the Sanitary Engineering Division, American Society of Civil Engineers, 89, 31-38.
[32] Bilgili, M.S. (2006) Adsorption of 4-Chlorophenol from Aqueous Solutions by XAD-4 Resin: Isotherm, Kinetic and Thermodynamic Analysis. Journal of Hazardous Materials, 137, 157-164.
http://dx.doi.org/10.1016/j.jhazmat.2006.01.005
[33] Katal, R., Baei, M.S., Rahmati, H.T. and Esfadian, H. (2012) Kinetic Isotherm and Thermodynamic Study of Nitrate Adsorption from Aqueous Solution Using Modifies Rice Husk. Journal of Industrial and Engineering Chemistry, 18, 295-302.
http://dx.doi.org/10.1016/j.jiec.2011.11.035
[34] Al-Ghout, M.A., Khraisheh, M.A., Ahmad, M.N. and Allen, S. (2009) Adsorption Behavior of Methylene Blue onto Jordanian Diatomite: A Kinetic Study. Journal of Hazardous Materials, 165, 589-598.
[35] Etim, U.J., Umoren, S.A. and Eduok, U.M. (2012) Coconut Coir Dust as a Low Cost Adsorbent for the Removal of Cationic Dye from Aqueous Solution. Journal of Saudi Chemical Society, in Press.
http://dx.doi.org/10.1016/j.jscs.2012.09.014
[36] Oguz, E. (2005) Thermodynamic and Kinetic Investigations of PO3-4 Adsorption on Blast Furnace Slag. Journal of Colloid and Interface Science, 281, 62-67.
http://dx.doi.org/10.1016/j.jcis.2004.08.074
[37] Antonio, P., Iha, K. and Suárez-Iha, M.E.V. (2007) Kinetic Modeling of Adsorption of di-2-Pyridylketone Salicyloylhydrazone on Silica Gel. Journal of Colloid and Interface Science, 307, 24-28.
http://dx.doi.org/10.1016/j.jcis.2006.11.031
[38] Klug, M., Sanches, M.N.M., Laranjeira, M.C.M. and Favere, V.T. (1998) Análise das isotermas de adsorcao de Cu(II), Cd(II), Ni(II) e Zn(II) pela n-(3,4-dihidroxibenzil) quitosana empregando o método da regressao nao linear. Química Nova, 21, 410-413.
http://dx.doi.org/10.1590/S0100-40421998000400006
[39] Singh, S., Barick, K.C. and Bahadur, D. (2013) Functional Oxide Nanomaterials and Nanocomposites for the Removal of Heavy Metals and Dyes. Nanomaterials and Nanotechnology, 3, 1-19.
http://dx.doi.org/10.5772/57237
[40] Sari, A., Mendil, D., Tuzen, M. and Soylak, M. (2009) Biosorption of Palladium(II) from Aqueous Solution by Moss (Racomitrium lanuginosum) Biomass: Equilibrium, Kinetic and Thermodynamic Studies. Journal of Hazardous Materials, 162, 874-879.
http://dx.doi.org/10.1016/j.jhazmat.2008.05.112
[41] Mastral, A.M., Garcia, T., Murillo, R., Callen, M.S., Lopez, J.M. and Navarro, M.V. (2003) Measurements of Polycyclic Aromatic Hydrocarbon Adsorption on Activated Carbons at Very Low Concentrations. Industrial & Engineering Chemistry Research, 42, 155-161.
http://dx.doi.org/10.1021/ie020189i
[42] Peric, J., Trgo, M. and Medvidovic, N.V. (2004) Removal of Zinc, Copper and Lead by Natural Zeolite—A Comparison of Adsorption Isotherms. Water Research, 38, 1893-1899.
http://dx.doi.org/10.1016/j.watres.2003.12.035
[43] Dabrowski, A. (2001) Adsorption—From Theory to Practice. Advances in Colloid and Interface Science, 93, 135-224.
http://dx.doi.org/10.1016/S0001-8686(00)00082-8
[44] Messina, P.V. and Schulz, P.C. (2006) Adsorption of Reactive Dyes on Titania-Silica Mesoporous Materials. Journal of Colloid and Interface Science, 299, 305-320.
http://dx.doi.org/10.1016/j.jcis.2006.01.039
[45] Foo, K.Y. and Hameed, B.H. (2010) Insights into the Modeling of Adsorption Isotherm Systems. Chemical Engineering Journal, 156, 2-10.
http://dx.doi.org/10.1016/j.cej.2009.09.013
[46] Hamdaoui, O., Naffrechoux, E., Suptil, J. and Fachinger, C. (2005) Ultrasonic Desorption of pchlorophenol from Granular Activated Carbon. Chemical Engineering Journal, 106, 153-161.
http://dx.doi.org/10.1016/j.cej.2004.10.010
[47] Gaubeur, I., Coutinho-Neto, M.D., Homen-de-Mello, P., Cafer, L.D.F. and Gomes, A.C.R. (2012) The Interaction of an Azo Compound with a Surfactant and Ion Pair Adsorption to Solid Phases. Journal of Colloid and Interface Science, 367, 370-377.
http://dx.doi.org/10.1016/j.jcis.2011.10.032
[48] Garcia, S. and Gaubeur, I. (2011) An Anionic Resin Modified by di-2-pyridyl Ketone Salicyloylhydrazone as a New Solid Preconcentration Phase for Copper Determination in Ethanol Fuel Samples. Journal of the Brazilian Chemical Society, 22, 501-510.
http://dx.doi.org/10.1590/S0103-50532011000300013

  
comments powered by Disqus

Copyright © 2018 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.