CdHgTe Quantum Dots Sensitized Solar Cell with Using of Titanium Dioxide Nanotubes

Abstract

The sensitization of TiO2 nanotubes with CdHgTe quantum dots (QDs) was applied by using the direct dispersion technique. The CdHgTe-QDs were fabricated with different Hg% ratio in organic medium for controlling their particle size. While TiO2 nanotubes (NTs) were fabricated by anodization technique. The QDs and NTs were characterized using SEM, TEM and UV-VIS spectrophotometer. In this work, the photovoltaic parameters of the quantum dots sensitized solar cell (QDSSC) depend mainly on the Hg% ratio in the QDs. The most efficient QDSSC was obtained at 25% of Hg ratio with Jsc of 4 mA/cm2, Voc of 0.63 V, FF of 0.32 and efficiency of 0.81%.

Share and Cite:

Feteha, M. and Ameen, M. (2013) CdHgTe Quantum Dots Sensitized Solar Cell with Using of Titanium Dioxide Nanotubes. Journal of Power and Energy Engineering, 1, 67-72. doi: 10.4236/jpee.2013.15011.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] A. G. Pattantyus Abraham, I. J. Kramer, A. R. Barkhouse, X. Wang, G. Konstantatos, R. Debnath, L. Levina, I. Raabe, M. K. Nazeeruddin, M. Grätzel and E. H. Sargent, “Depleted Heterojunction Colloidal Quantum Dot Solar Cells,” ACS Nano, Vol. 4, No. 6, 2010, pp. 3374-3380. http://dx.doi.org/10.1021/nn100335g
[2] Z. Yang and H. Chang,“CdHgTe and CdTe Quantum Dot Solar Cells Displaying an Energy Conversion Efficiency Exceeding 2%,”Solar Energy Materials and Solar Cells, Vol. 94, No. 12, 2010, pp. 2046-2051. http://dx.doi.org/10.1016/j.solmat.2010.06.013
[3] A. J. Nozik, “Quantum Dot Solar Cells,” Physica E: Low Dimensional Systems and Nanostructures, Vol. 14, No. 1-2, 2002, pp. 115-120. http://dx.doi.org/10.1016/S1386-9477(02)00374-0
[4] A. J. Nozik, “Fundamental and Applications of Quantum Confined Structures,” NERL Publication, Vol. 3, 2007.
[5] B. E. Mccandless and J. R. Sites, “Cadmium Telluride Solar Cells,” Handbook of Photovoltaic Science and Engineering, John Wiley & Sons Ltd., 2003, pp. 617-662.
[6] L. Tsakalakos, “Nanostructures for Photovoltaics,” Materials Science and Engineering: R: Reports, Vol. 62, No. 6, 2008, pp. 175-189. http://dx.doi.org/10.1016/j.mser.2008.06.002
[7] C. Grimes, “Titanium Dioxide Nanotube Arrays Improved Solar Cells,” SPIE Newsroom, 2008. http://dx.doi.org/10.1117/2.1200806.1148
[8] D. R. Baker and P. V. Kamat, “Photosensitization of TiO2 Nanostructures with CdS Quantum Dots: Particulate versus Tubular Support Architectures,” Advanced Functional Materials, Vol. 19, No. 5, 2009, pp. 805-811. http://dx.doi.org/10.1002/adfm.200801173
[9] D. Regonini, “Anodised TiO2 Nanotubes: Synthesis, Growth Mechanism and Thermal Stability,” Ph.D. Thesis, University of Bath, UK, 2008.
[10] G. K. Mor, O. K. Varghese, M. Paulose, K. Shankar and C. A. Grimes, “A Review on Highly Ordered, Vertically Oriented TiO2 Nanotube Arrays: Fabrication, Material Properties, and Solar Energy Applications,” Solar Energy Materials and Solar Cells, Vol. 90, No. 14, 2006, pp. 2011-2075. http://dx.doi.org/10.1016/j.solmat.2006.04.007
[11] M. Feteha, S. Ebrahim, M. Soliman, W. Ramdan and M. Raoof, “Effects of Mercaptopropionic Acid as a Stabilizing Agent and Cd:Te Ion Ratio on CdTe and CdHgTe Quantum Dots Properties,” Journal of Materials Science: Materials in Electronics, Vol. 23, 2012, pp.1938-1943. http://dx.doi.org/10.1007/s10854-012-0684-y
[12] M. T. Harrison, S. V. Kershaw, M. G. Burt and A. Eychmu, “Wet Chemical Synthesis and Spectroscopic Study of CdHgTe Nanocrystals with Strong Near Infrared Luminescence,” Materials Science and Engineering, Vol. 70, 2000, pp. 355-360. http://dx.doi.org/10.1016/S0921-5107(99)00254-8

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.