Structural and electrical characterization of Bi2VO5.5 / Bi4Ti3O12 bilayer thin films deposited by pulsed laser ablation technique

Abstract

The pulsed laser ablation technique has been employed to fabricate bilayer thin films con-sisting of layered structure ferroelectric bismuth vanadate (Bi2VO5.5) and bismuth titanate (Bi4Ti3O12) on platinized silicon substrate. The phase formation of these films was confirmed by X-ray diffraction (XRD) studies and the crystallites in these bilayers were randomly oriented as indicated by diffraction pattern consisting of the peaks corresponding to both the materials. The homogeneous distribution of grains (~300 nm) in these films was confirmed by atomic force microscopy. The cross-sectional scanning electron microscopy indicated the thickness of these films to be around 350 nm. The film exhi-bited P-E hysteresis loops with Pr ~ 11 ?C/cm2 and Ec ~ 115 kV/cm at room temperature. The dielectric constant of the bilayer was ~ 225 at 100 kHz which was higher than that of homogeneous Bi2VO5.5 film.

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Kumari, N. , Krupanidhi, S. and Varma, K. (2010) Structural and electrical characterization of Bi2VO5.5 / Bi4Ti3O12 bilayer thin films deposited by pulsed laser ablation technique. Natural Science, 2, 1073-1078. doi: 10.4236/ns.2010.210133.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] Rijnders, G. and Blank, D.H.A. (2005) Materials science: Build your own superlattice. Nature, 433, 369-370.
[2] Shimuta, T., Nakagawara, O., Makino, T., Arai, S., Tabata, H. and Kawai, T. (2002) Enhancement of remanent polarization in epitaxial BaTiO3 / SrTiO3 superlattices with “asymmetric” structure. Journal of Applied Physics, 91, 2290-2294.
[3] Pontes, F.M., Longo, E., Leite, E.R. and Varela, J.A. (2004) Improvement of the dielectric and ferroelectric properties in superlattice structure of Pb(Zr,Ti)O3 thin films grown by a chemical solution route. Applied Physic Letters, 84, 5470-5472.
[4] Lee, H.N., Christen, H.M., Chisholm, M.F., Rouleau, C. M. and Lowndes, D.H., (2005) Strong polarization en- hancement in asymmetric three-component ferroelectric superlattices, Nature, 433, 395-399.
[5] Neaton, J.B. and Rabe, K.M. (2003) Theory of polariza-tion enhancement in epitaxial BaTiO3 / SrTiO3 superlat-tices, Applied Physic Letters, 82, 1586-1588.
[6] Aurivillius, B. (1949) Mixed bismuth oxides with layer lattices. II. Structure of Bi4Ti3O12. Arkiv for Kemi, 1(54) 463-480.
[7] Araujo, C.A.P. de, Cuchiaro, J.D., McMillan, L.D., Scott, M.C. and Scott, J.F. (1995) Fatigue-free ferroelectric ca-pacitors with platinum electrodes, Nature, 374, 627-629.
[8] Park, B.H., Kang, B.S., Bu, S.D., Noh, T.W., Lee, J. and Jo, W., (1999) Lanthanum-substituted bismuth titanate for use in non-volatile memories, Nature, 401, 682-684.
[9] Maiwa, H., Lizawa, N., Togawa, D., Hayashi, T., Saka- moto, W., Yamada, M. and Hirano, S. (2003) Electrome-chanical properties of Nd-doped Bi4Ti3O12 films: A candidate for lead-free thin-film piezoelectrics. Applied Physic Letters, 82, 1760-1762.
[10] Watanabe, T., Funakubo, H., Osada, M., Noguchiand, Y. and Miyayama, M. (2002) Preparation and characteriza-tion of a- and b-axis-oriented epitaxially grown Bi4Ti 3O12-based thin films with long-range lattice matching, Applied Physic Letters, 81, 1660-1662.
[11] Rae, A.D., Thompson, J.G., Withers, R.L. and Willis, A. C. (1990) Structure refinement of commensurately mo- dulated bismuth titanate, Bi4Ti3O12. Acta Crystallogr, 46, 474-487.
[12] Borisov, V.N., Poplavko, Y.M, Avakyan, P.B. and Osi-pyan, V.G. (1988) Phase transition in bismuth vanadate, Soviet Physics - Solid State, 30, 904-905.
[13] Osipian, V.G., Savchenk, L.M., Elbakyan, V.L. and Avak- yan, P.B. (1987) Layered boismuth vanadate ferroelctrics, Inorganic Materials, 23, 467-469.
[14] Prasad, K.V.R. and Varma, K.B.R. (1994) Dielectric, thermal and pyroelectric properties of ferroelectric bismuth vanadate single crystals, Materials Chemistry and Physics, 38, 406-410.
[15] Prasad, K.V.R. (1994) Investigations into the structural, dielectric and ferroelectric properties of ceramics and single crystal of parent and substituted bismuth vanadate. Ph. D. Thesis, Indian Institute of Science, Bangalore.
[16] Kumari, N., Krupanidhi, S.B. and Varma, K.B.R. (2007) Dielectric, impedance and ferroelectric characteristics of c-oriented Bismuth vanadate films grown by pulsed laser deposition. Materials Science and Engineering B, 138, 22-30.
[17] Kumari, N. (2009) Structural, optical and electrical studies on Aurivillius oxide thin films. Ph. D. Thesis, Indian Institute of Science, Bangalore.
[18] Lines, M.E. and Glass, A.M. (1979) Principles and ap-plications of ferroelectrics and related materials, Clare- don Press, Oxford.
[19] Dawber, M., Rabe, K.M. and Scott, J.F. (2005) Physics of thin-film ferroelectric oxides. Reviews of Modern Phy- sics, 77, 1083-1130.
[20] Richerson, D.W. (1992) Modern ceramic engineering: Properties, processing and use in design, Marcel Dekker Inc., New York.

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