Synthesis and Surface Activity of Cashew-Based Anion-Nonionic Surfactants

Abstract

Four novel anion-nonionic surfactants were synthesized using cashew phenol as raw material. The four structures were characterized by IR and elemental analysis. Their surface activities were investigated. Their critical micelle concentrations (CMC) are 9.30 × 10 –3 mol/L, 8.50 × 10–3 mol/L, 8.10 × 10–3 mol/L and 7.71 ×–3 mol/L respectively, and the corresponding surface tensions at CMC are 28.38 mN/m, 28.60 mN/m, 30.40 mN/m and 30.00 mN/m respectively. The contact angles of the solutions on sheet galsses were measured to observe their surface wettabilities. The effects of their concentrations, the concentrations of NaCl and temperature on their foaming capacity and foam stability were studied.

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H. Li, J. Wang, C. Liu, J. Han, C. Li and M. Ning, "Synthesis and Surface Activity of Cashew-Based Anion-Nonionic Surfactants," Open Journal of Applied Sciences, Vol. 2 No. 2, 2012, pp. 93-97. doi: 10.4236/ojapps.2012.22012.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] A. M. Al-Ghamdi and H. A. Nasr-El-Din, “Effect of Oilfield Chemicals on the cloud Point of Nonionic Surfactants,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 125, No.1, 1997, pp. 5-18. doi:10.1080/028418501127346846
[2] Y. F. Wang, L. S. Wang, J. Y. Li and F. L. Zhao, “Surfactants Oil Displacement System in High Salinity Formations: Research and Application,” Society of Petroleum Engineers (SPE), Allen, 2001, pp. 330-336.
[3] H. J. Liu, L. H. Lin and K. M. Chen, “Reparation and Properties of water-Soluble Polyester Surfactants. II. Preparation and Surface Activity of Silicone-Modified Polyester Surfactants,” Journal Applied Polymer Science, Vol. 86, No. 12, 2002, pp. 3005-3012. doi:10.1002/app.11290
[4] Y. Fujita and M. Reinhard, “Identification of Metabolites from the Biologoval Transformation of the Nonionic Surfactant Residue Octyphenoxyacetic Acid and Its Brominated Analog,” International Journal of Environmental Science and Technology, Vol. 31, No. 5, 1997, pp. 15181524. doi:10.1021/es9607852
[5] X. Xu, H. Chen and X. R. Cai, “Synthesis and Properties of Polyfluorene Copolymers Bearing Thiophene and Porphyrin,” Journal of Chinese Chemical Letters, Vol. 18, No. 7, 2007, pp. 879-882. doi:10.1016/j.cclet.2007.05.040
[6] C. C. Lai and K. M. Chen, “Preparation and surface Activity of Polyoxyethylene-Carboxylated Modified Gemini Surfactants,” Journal of Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 320, No.1-3, 2008, pp. 6-10. doi:10.1016/j.colsurfa.2007.12.056
[7] L. G. Qiu, A. J. Xie and Y. H. Shen, “Synthesis and Surface Activity of Novel Triazole-Based Cationic Gemini Surfactants,” Journal of Chinese Chemical Letters, Vol. 14, No. 6, 2003, pp. 653-656.
[8] M. J. Rosen, “Wetting and Its Modification by Surfactants,” Surfactants and Interfacial Phenomena, 3rd Edition, WileyInterscience, New York, 1978, p. 174.
[9] S. Paria and K. C. Khilar, “A Review on Experimental Studies of Surfactant Adsorption at the Hydrophilic SolidWater Interface,” Advances in Colloid and Interface Science, Vol. 110, No. 3, 2004, pp. 75-95. doi:10.1016/j.cis.2004.03.001
[10] K. M. Chen and H. J. Liu, “Preparation and Surface Activity of Water-Soluble Polyesters,” Journal Applied Polymer Science, Vol. 34, No. 5, 1987, pp. 1879-1888. doi:10.1002/app.1987.070340507
[11] Y. Li, P. Zhang, G. Q. Zhao, X. L. Cao, Q. W. Wang and H. Y. Wang. “Effect of Equilibrium and Dynamic Surface Activity of Surfactant on Foam Transport in Porous Medium,” Journal of Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 272, No. 1-2, 2006, pp.124-129. doi:10.1016/j.colsurfa.2005.07.037
[12] D. Beneventi, B. Carre and A. Gandini, “Role of Surfactant Structure on Surface and foaming Properties,” Journal of Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 189, No. 1-3, 2001, pp. 65-73. doi:10.1016/S0927-7757(01)00602-1

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