Share This Article:

Metal-organic frameworks derived from divalent metals and 4-(1H-1, 2, 4-triazol-1-yl)benzoic acid

Full-Text HTML Download Download as PDF (Size:1448KB) PP. 58-66
DOI: 10.4236/ojic.2012.23009    5,051 Downloads   9,604 Views   Citations

ABSTRACT

Two inorganic-organic coordination polymers, [Cd(TBA)2]·3H2O (1) and [Cu(TBA)2]·2H2O (2) have been synthesized by reaction of the metal ions of Cd(II) and Cu(II) with the ligand HTBA [HTBA = 4- (1H-1, 2, 4-triazol-1-yl)benzoic acid] under solvothermal condition. The compounds were characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy, X-ray powder diffraction (XRPD), and thermo gravimetric analysis (TGA). The structural analyses reveal the two independent polymers exhibit different structures. Complex 1 exhibits a 3D framework with 1D channels, and complex 2 shows a 2-fold interpenetrating 3D diamond net.

Cite this paper

Li, J. , Zhang, G. , Li, Y. , Wang, X. , Zhu, J. and Tian, Y. (2012) Metal-organic frameworks derived from divalent metals and 4-(1H-1, 2, 4-triazol-1-yl)benzoic acid. Open Journal of Inorganic Chemistry, 2, 58-66. doi: 10.4236/ojic.2012.23009.

References

[1] Xiao, D.R., Wang, E.B., An, H.Y., Li, Y.G., Su, Z.M. and Sun, C.Y. (2006) A bridge between pillared-layer and helical structures: A series of three-dimensional pillared coordination polymers with multiform helical chains. Chemistry—A European Journal, 12, 6528-6541. doi:10.1002/chem.200501308
[2] Lee, H.Y., Park, J., Lah, M.S. and Hong, J.I. (2008) One-dimensional double helical structure and 4-fold type [2 + 2] interpenetration of diamondoid networks with helical fashion. Crystal Growth & Design, 8, 587-591. doi:10.1021/cg7007232
[3] Wang, X.L., Qin, C., Wang, E.B., Xu, L., Su, Z.M and Hu, C.W. (2004) Interlocked and interdigitated architectures from self-assembly of long flexible ligands and cadmium salts. Angewandte Chemie International Edition, 43, 5036-5040. doi:10.1002/anie.200460758
[4] Fan, J., Yee, G.T., Wang, G. and Hanson, B.E. (2006) Syntheses, structures, and magnetic properties of inorganic-organic hybrid cobalt(II) phosphites containing bifunctional ligands. Inorganic Chemistry, 45, 599-608. doi:10.1021/ic051286h
[5] Fan, J., Slebodnick, C., Angel, R. and Hanson, B.E. (2005) New zinc phosphates decorated by imidazolecontaining ligands. Inorganic Chemistry, 44, 552-558. doi:10.1021/ic0487528
[6] Wu, T., Yi, B.H. and Li, D. (2005) Two novel nanoporous supramo-lecular architectures based on copper(I) coordination polymers with uniform (8, 3) and (8210) nets: In situ formation of tetrazolate ligands. Inorganic Chemistry, 44, 4130-4132. doi:10.1021/ic050063o
[7] Choi, H.J., Dinca, M. and Long, J.R. (2008) Broadly hysteretic H2 adsorption in the microporous metal-organic framework Co (1, 4-benzenedipyrazolate). Journal of the American Chemical Society, 130, 7848-7850. doi:10.1021/ja8024092
[8] Kaye, S.S., Dailly, A., Yaghi, O.M. and Long, J.R. (2007) Impact of preparation and handling on the hydrogen storage properties of Zn4O (1,4-benzenedicarboxylate)3 (MOF-5). Journal of the American Chemical Society, 129, 14176-14177. doi:10.1021/ja076877g
[9] Dinca, M. and Long, J.R. (2007) High-enthalpy hydrogen adsorption in cation-exchanged variants of the microporous metal-organic framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2. Journal of the American Chemical Society, 129, 11172-11176. doi:10.1021/ja072871f
[10] Han, S.S., Furukawa H., Yaghi O.M. and William A.G. III (2008) Covalent organic frameworks as exceptional hydrogen storage materials. Journal of the American Chemical Society, 130, 11580-11581. doi:10.1021/ja803247y
[11] Wang, Z.X., Shen, X.F., Wang, J., Zhang, P., Li, Y.Z., Nfor E.N., et al. (2006) A sodalite-like framework based on octacyanomolybdate and neodymium with guest methanol molecules and neodymium octahydrate ions. Angewandte Chemie International Edition, 45, 32873291. doi:10.1002/anie.200600455
[12] Kajiwara, T., Nakano, M., Kaneko, Y., Takaishi, S., Ito, T., Yamashita M., et al. (2005) A single-chain magnet formed by a twisted arrangement of ions with easy-plane magnetic anisotropy. Journal of the American Chemical Society, 127, 1015010151. doi:10.1021/ja052653r
[13] Liu, T.F., Fu, D., Gao, S., Zhang, Z.Y., Sun, H.L., Su, G. and Liu, Y.J. (2003) An azide-bridged homospin singlechain magnet: [Co(2, 2'-bithiazoline)(N3)2]n. Journal of the American Chemical Society, 125, 13976-13977. doi:10.1021/ja0380751
[14] Freeman, D.E., Jenkins, D.M., Lavarone, A.T., Freedman, D.E., Jenkins, D.M., Iavarone, A.T. and Long, J.R. (2008) A redox-switchable single-molecule magnet incorporating [Re(CN)7]3–. Journal of the American Chemical Society, 130, 2884-2885. doi:10.1021/ja077527x
[15] Ohba, M., Kaneko, W., Kitagawa, S. Maeda, T. and Mito, M. (2008) Pressure response of three-dimensional cyanide-bridged bimetallic magnets. Journal of the American Chemical Society, 130, 4475-4484. doi:10.1021/ja7110509
[16] Kou, H.Z., Jiang, Y.B. and Cui, A.L. (2005) Two-dimensional coordination polymers exhibiting antiferromagnetic Gd(III)-Cu(II) coupling. Crystal Growth & Design, 5, 77-79. doi:10.1021/cg049897s
[17] Wang, X.F., Lv, Y., Okamura, T.-A., Kawaguchi, H., Wu, G., Sun, W.Y. and Ueyama, N. (2007) Structure variation of mercury(II) halide complexes with different imidazole-containing ligands. Crystal Growth & Design, 7, 1125-1133. doi:10.1021/cg060814c
[18] Wu, G., Wang, X.F., Okamura, T., Sun, W.Y. and Ueyama, N. (2006) Syntheses, structures, and photoluminescence properties of metal(II) halide complexes with pyridine-containing flexible tripodal ligands. Inorganic Chemistry, 45, 8523-8532. doi:10.1021/ic060493u
[19] Zhao, X.X., Ma, J.P., Dong, Y.B., Huang, R.Q. and Lai, T.S. (2007) Construction of metal-organic frame-works (M = Cd(II), Co(II), Zn(II), and Cu(II)) based on semirigid oxadiazole bridging ligands by solution and hydrothermal reactions. Crystal Growth & Design, 7, 10581068. doi:10.1021/cg060583+
[20] Qin, J., Ma, J.P. and Liu, L.L. (2009) A novel two-dimensional frame-work based on unprecedented cadmium(II) chains. Acta crystallographica, 65, 66-68. doi:10.1107/S0108270109000341
[21] Cui, K.H., Yao, S.Y., Li, H.Q., Li, Y.T., Zhao, H.P., Jiang, C.J. and Tian, Y.Q. (2011) Acentric and chiral four-connected metal-organic frameworks based on the racemic binaphthol-like chiral ligand of 4-(1-H(or methyl)-imidaozol-1-yl) benzoic acid. Crystal Engineering Communication, 13, 3432-3437. doi:10.1039/C0CE00789G
[22] Zhang, J.Z., Cao, W.R., Pan, J.X. and Chen, Q.W. (2007) A novel two-dimensional square grid cobalt complex: Synthesis, structure, luminescent and magnetic properties. Inorganic Chemistry Communication, 10, 1360-1364. doi:10.1016/j.inoche.2007.08.016
[23] Sheldrick, G.M. (1996) SADABS. Program for empirical absorption correction for area detector data. University of G?ttingen, G?ttingen.
[24] Sheldrick, G.M. (1997) SHELXS 97. Program for crystal structure refinement. University of G?ttingen, G?ttingen.
[25] Seidel, R.W., Goddard, R., Zibrowius, B. and Oppel, I.M. (2011) A molecular antenna coordination polymer from cadmium(II) and 4,4’-bipyridine featuring three distinct polymer strands in the crystal. Polymers Chemistry Journal, 3, 1458-1474. doi:10.3390/polym3031458

  
comments powered by Disqus

Copyright © 2018 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.