Author(s)

Ndoye Mouhamed¹, Kane Cheikhou¹, Gadji Elhadji Momar Rokhy¹, Diédhiou Moussa Bagha¹, Mar-Diop Codou Guèye¹, Theo Tzedakis^2*

¹Ecole Supérieure Polytechnique, Université Cheikh Anta Diop, Dakar, Senegal.
²Laboratoire de Génie Chimique, UMR CNRS 5503, Université de Toulouse III-Paul Sabatier, Toulouse, France.

This study presents the elaboration of a simple and cheap electrode made by carbon paste introduced into a cavity of electrode body, and used for the lead traces determination in tap water. A potentiostatic pre-electrolysis at constant voltage enables the reduction of the lead (Pb²⁺) and the accumulation of the metallic lead at and into the carbon paste; the reoxidation of the Pb (Linear sweep voltammetry) leads to the anodic striping peak. The effect of the main operating parameters on the shape of the peak and the magnitude of the current was examined and their optimal values were determined. Then calibration was achieved and the method was successfully applied (using all the optimized parameters) to the determination of lead in water, with a detection limit of 0.138 μg·L^-1. Compared to other methods (ICP-AES for example), the proposed method offers a satisfactory detection limit of the Pb²⁺ (0.138 μg·L^-1) because of the important specific area of the carbon paste electrode, for a significantly lower cost. Besides, there is no observed loss in the electrode answer in terms of peak current, which means that there is no any irreversible steps nor deactivation of the electrode, even after ten successive measurements; only reduction of the lead followed by the deposit oxidation was observed at the electrode.

Carbon Paste Electrode, Lead, Linear Sweep Anodic Stripping Voltammetry, Water

Mouhamed, N. , Cheikhou, K. , Rokhy, G. , Bagha, D. , Guèye, M. and Tzedakis, T. (2018) Determination of Lead in Water by Linear Sweep Anodic Stripping Voltammetry (LSASV) at Unmodified Carbon Paste Electrode: Optimization of Operating Parameters. American Journal of Analytical Chemistry, 9, 171-186. doi: 10.4236/ajac.2018.93015.