Author(s)

Takeshi Kato^1*, Shukuro Igarashi², Osamu Ohno², Shotaro Saito², Ryo Ando¹

¹Industrial Technology Institute of Ibaraki Prefecture, Ibaraki, Japan.
²Department of Biomolecular Functional Engineering, Faculty of Engineering, Ibaraki University, Ibaraki, Japan.

On the basis of homogeneous liquid-liquid extraction (HoLLE) with Zonyl FSA to plating water containing 1 mg palladium, 96.6% of the palladium was extracted into the sedimented liquid phase. After phase separation, the volume ratio (Va/Vs) of the aqueous phase (Va) and the sedimented liquid phase (Vs) was 556 (50 mL → 0.09 mL). The assessment of the potential implementation of this procedure to wastewater treatment showed that HoLLE was satisfactorily achieved when the volume was scaled up to 1000 mL. Moreover, HoLLE was conducted to real palladium plating wastewater generated in the plating industry. 94.5% of the palladium was extracted into the sedimented liquid phase. After phase separation, the volume ratio (Va/Vs) of the aqueous phase (Va) and the sedimented liquid phase (Vs) was 500 (50 mL → 0.1 mL). In addition, HoLLE could separate palladium from coexisting metals in real plating wastewater. This knowledge is expected to lead to the development of new separation and concentration technologies of rare metals from real plating wastewater.

Homogeneous Liquid-Liquid Extraction, HoLLE, Zonyl FSA, Surfactant, Real Plating Wastewater

Kato, T. , Igarashi, S. , Ohno, O. , Saito, S. and Ando, R. (2016) Homogeneous Liquid-Liquid Extraction (HoLLE) of Palladium in Real Plating Wastewater for Recovery. Journal of Environmental Protection, 7, 277-286. doi: 10.4236/jep.2016.72024.