Comparative Physico Mechanical Study of Cements CEM II 42.5R in Cameroon: Case of DANGOTE and CIMENCAM

The present work deals with a comparative study of the physical-mechanical characteristics of different types of cement CEM II 42.5R produced and used in Cameroon. Indeed, the recent policy of integration and promotion of products in the sub-region has allowed some manufacturers (04) to settle in Cameroon and propose their products that characteristics are most often ignored by consumers. In order to handle this work correctly, we have conducted several tests on cements CEM II 42.5R of CIMENCAM and DANGOTE. These trials were carried out on fresh concrete, mortar, and also on a normalized cement paste. The present study mainly shows the specificities and the characteristics of CEM II 42.5R cement from other brands.


Introduction
Cements are hydraulic binders made of fine powders which, if they are added to water, they form a paste that is able to hydrate and gradually harden after a longer or shorter time [1].They are in fact composed of anhydrous, crystalline or vitreous constituents, essentially containing silica, alumina and lime.Moreover, the hardening is due to the hydration of certain components, mainly silicates and calcium aluminates; the proportion of lime and reactive silica to be at least 50% of the cement mass [1]  Cement has been used for millennia: in ancient Egypt, it was a plaster mortar that bounded the stones.Chinese or the Mayas also use to build using limebased mortars, obtained by baking limestone rocks: this is the basis of the cement still manufactured today.Over the centuries, cement has been perfected.
The Romans used lime which is reinforced by volcanic ash (pozzolana) to make their mortar this was then able to take under water.The empirical methods were perfected later on with the theory of hydraulicity and described the necessary proportions of lime and clay to produce cement by baking.From this, the industrial production of cement can start [4] [5] [6].In 1824, Joseph Aspdin, a Scottish, improved the "recipe" and created Portland Cement.But it is in France that the Polytechnic Pavin de Lafarge settled his first lime kilns at Teil, in Ardèche, in 1833 [4].
The cement industry now is available to the user with large numbers of brands and specific areas of employment.The wide range of compositions, strengths, setting velocity and hardening combine with the requirements for the construction of buildings or civil engineering structures [6] [7] [8].However in Cameroon, the cement plant has grown exponentially.So in addition to CIMENCAM, we have seen the establishment of DANGOTE, MEDCEM, and CIMAF.Each cement plant has a specificity in the mineralogical and chemical composition of the cements manufactured according to the geological context, the atmospheric conditions and the need for performance [4].
Cameroon cement plants produce, several types of cements including CEM II 42.5 R.So the composition varies from one cement plant to another.There are advantages solicited following the significant demand of the builders for the realization of works of civil engineering and real estate.The success of a structure depends on the mastery of the characteristics of the cement, the inputs (aggregates and water) and the atmospheric conditions [1]- [9].However, it has been found that manufacturers sometimes neglect these parameters during the construction of structures, particularly the characteristics of cements [7]- [13].Fig- ure 1 shows the cement manufacturing process.
The purpose of this study is to present the specificities of CEM II 42.5 R cement from each cement plant (Case of CIMENCAM and DANGOTE) and the areas of use that arise from these properties.The first part will be devoted to the generality of the cements, as well as to the materials and methods used.And the second part will be dedicated to the experimental study, namely a comparative study of CEM II 42.5 R cement produced by CIMENCAM and DANGOTE, followed by an analysis of the results and by the recommendations.

Materials and Methods
This part is devoted to materials and methods.We will begin by presenting the characterization of materials that will be summarized in the presentation of the general properties and the mechanical and physical characteristics of the materials used.Finally we will present the experimental devices that allowed us to test Granulometric analysis makes it possible to characterize the aggregates by determining the size of the grains which constitute them, and the percentages of the grains of each size.It is carried out with sieves (Figure 2) according to standard NF P 18-560 [14].In addition, it will be necessary to avoid confusing grain size, which is the science that determines grain size and granularity, which is a dimensional distribution of grains of a granulate [5].
The studied material is placed at the top of the sieves and the classification of the grains is obtained by vibration of the sieve column.At the end of the test, we draw the particle size curve which gives the respective weight percentages of   2) and (3).Finally, the fineness module (Mdf) for sand [15]- [20] is calculated.
( ) D 10 , D 30 , D 60 represent the diameters of the elements corresponding to 10%, 30% and 60% of cumulative sieve, respectively.When we have: Cu < 2, the particle size is said to be uniform Cu > 2, the particle size is said to be spread A sand is well graduated when one has: 1 ≤ Cc ≤ 3 [27] ( ) { }

Sand Equivalent to 10% Fines
The equivalent of sand is used to measure the cleanliness of the sand and to detect the presence of fine elements in this sand.It is carried out according to the standard NFP 18 -598 [15]- [21].It is the ratio multiplied by 100 of the height of the sedimented sandy part, at the total height of the flocculate and the sandy part [15].The test is to flocculate the fine elements of sand suspended in a washing solution and then, after a time of rest, to measure the height of the sedimented elements.
Figure 3 shows the device used to perform the aforementioned test.

Resistance to Fragmentation
In order to verify the resistance to fragmentation, the Los Angeles test was carried out according to the NF EN 1097-2 standard and is intended to measure the resistance to shock fragmentation of a sample of aggregates.Indeed, it is expressed by the coefficient Los Angeles (L) which is the ratio between the mass of the refusal to sieve 1.6 mm of the sample after passage in the apparatus (Figure 4) intended for the test on mass initial [7] [18].The coefficient L is determined as follows:  With.P: mass of sieve passing 1.6 mm (g), M: mass of materials collected (g), m: mass of dry refusal (g).

Wear Resistance: Micro-Deval Test
The purpose of the micro-Deval test is to verify under standard conditions the input of the aggregates produced by mutual friction in the presence of water and an abrasive load in a rotating cylinder.This test is carried out according to standard NF EN 1097-1.Indeed, after abrasion and depoits in a rotating cylinder arranged on a device as shown in photo 4 (12,000 revolutions in 2 hours), the mass m of the elements less than 1.6 mm produced, in the presence of water and expressed by the micro-Deval coefficient (M DE ) [7] [19]-[24].The M DE coefficient is determined as follows: 100 With P: passing mass of sieve 1.6 mm (g), M: mass of materials collected (g), m: mass of dry refusal (g).

Specific Density
The specific density is the mass of the unit of absolute volume of the body, that is to say, the material that constitutes the body, without taking into account the volume of the voids [2].It varies from 2900 to 3150 kg/m 3 depending on the type of cement [10].It is measured in two ways: using the graduated cylinder or using the pycnometer.Indeed, the test specimen method is very simple, fast and uses standard laboratory equipment (graduated test tube) except that it is of low precision [7].In addition, the pycnometer test is carried out according to the EN 1097-6 standard.The density of the aggregates (sand and gravel) used was measured using the graduated cylinder (Figure 5(a)) and the cement using the glass pycnometer (Figure 5(b)) [7] [20]- [27].

Measurement of Finesse
The fineness of cement is generally expressed by its mass area.This is the total area of the grains contained in a unit of powder.The objective of the test is to assess the surface area of the cement grains per gram of powder [7].This surface is expressed in cm 2 /g.The test for the determination of the fineness of the cement is carried out according to the EN 196-1 standard.The mass surface of the cements studied is measured by comparison with a reference cement that surface area is known [8] [14]- [25].The equipment used to carry out the test is called the "Blaine Permeabilimeter".Indeed it will be to pass a known volume of air through cement powder.The larger is the surface of this powder, the longer it takes for the air to pass through the powder.

Consistency Measurement
The consistency test of the dough makes it possible to characterize its greater or lesser fluidity.The following standardized tests make it possible to appreciate Figure 5. Graduated cylinder and pycnometer for the measurement of specific gravity.
this consistency: • Consistency test carried out with the Vicat apparatus according to EN 196-3 • The cone flow test according to standard NF P 15-358 [25].
As part of our work, we evaluated this consistency from the Vicat consistency.
Indeed it consists in measuring the depression of a cylindrical rod under the effect of a constant load in the dough.Indeed, it is the distance "d" between the end of the probe and the bottom of the mold that characterizes the consistency.

Measurement of Setting Time
The test is carried out on a paste of standardized consistency and is made according to the EN 196-3 standard.The objective of the test is to define for given cement a time that is significant for the speed of setting.It is the evolution of the consistency of a paste of standardized consistency that will be followed by the test.The apparatus used is that of Vicat equipped with a 1.13 mm diameter needle as shown in Figure 7.It is said that the "setting start time" is reached when under the effect of a load of 300 g, the needle stops at a distance "d = 4 mm ± 1 mm" from the bottom of the mold.In addition, the "end of setting time" is the one at the end of which the needle is no more than 0.

Slump cone of Abrams or Slump Test
Abrams cone collapse is carried out according to standard NF EN 12350-2 and is very often used because it is quite easy to implement [7] [8] [23].It consists of molding in a truncated cone whose diameter of the base is 20 cm, the top is 10 cm and height 30 cm of the concrete.The cone is filled in three layers each poked 25 times with a metal rod 16 mm in diameter with rounded ends.Then gently lift the mold and measure the slump immediately after.
The mold is then gently raised and the slump or slump measured immediately afterwards (Figure 8(a)).

Making Concrete Specimens
The concrete is first kneaded in a concrete mixer or kneader, and then molded in molds 16 cm in diameter and 32 cm in height (Figure 9

Measurement of Finesse
The fineness of a cement is generally expressed by its mass area.Table 1 presents the results obtained following the fineness test on the two different cements studied.
Figure 11 shows the results obtained following the fineness test on the two different studied cements The finer the value of a cement, the finer the grinding.We can see that CIMENCAM has a greater grinding fineness.Note that the finer the milling of a cement, the higher the speed of hydration reactions and the higher the mechanical resistance at young ages (2 to 7 days).On the other hand, cement is sensitive to ventilation and large shrinkage [7].

Consistency Tests
Table 2 shows the consistency in % of the various cements studied.
Table 1.Blaine fineness of the cements studied.From the results obtained, we find that CIMENCAM needs a large quantity of water to reach the consistency required by the EN 196-3 standard.

Setting Time
We talk about the setting of cement when the paste of cement, mortar or concrete loses its plasticity.In the course of our work, we have determined these different times on the various cements used (see Figure 13).
It was on the standardized cement paste made during the consistency test that  any.Thus, the setting time is faster for cement when it has great fineness [7] [8] [18]- [27].In view of the results obtained, we can see that CIMENCAM has a setting start time lower than that of DANGOTE is ground more finely.In addition, the results we obtained are consistent with those of Blaine finesse.Indeed, the finer a cement is, the greater its specific surface is, the shorter is its setting time and the faster it flows.However, since DANGOTE has a more advanced setting time than CIMENCAM, it also has the advantage of less cracking and less shrinkage [1].

Abrams Cone Settlement of Fresh Concrete
The histogram presented in Figure 14 shows the value of the slump measured on concretes made from the various cements studied.

Density of Fresh Concrete
The fresh density is measured in order to be able to verify the density calculated theoretically.The fresh densities of the different types of cement studied are shown in Figure 15.
The density theoretically calculated following the formulation that we made, allowed us to obtain 2.99 t/m 3 .Thus we can see that the fresh concrete densities obtained are different and below the theoretical.The characteristics of the studied cements and the mechanism of hydration can explain this difference.It should also be noted that the phenomenon of contraction of materials may have an influence on this difference.Indeed, this measure should make it possible to make corrections on the proportions of the constituents of the concrete.

Semi-Wet Density
Mass volume is defined as the mass of a body per unit volume.During the cooking period, we measured the density of the test specimens at different ages, as shown in Figure 16.
During our study, we observed that the concretes studied have densities ranging from 2 t/m 3 to 2.5 t/m 3 .Indeed, the more the maturation evolves, the more the density increases.This is due to the fact that immersed in the maturation pond, concretes become saturated as and when they mature.

Compressive Strength
The compressive strength on the concrete specimens makes it possible to determine   sand and gravel with the cement paste) of the concrete and the class resistance of cement [7].Note that between the 3 rd day and 7 th day, we notice that the resistance has hardly changed and then from the 14 th day begins again to grow until 28 th days.Indeed, it is 35.3MPa (increase of 32 MPa of 15% taking into account the environment and the quality of the aggregates used to make the concrete) that we hoped to have at least at the outcome of our calculations.

Recommendations
At the end of this analysis, it was discussed to make a comparative study between the characteristics of DANGOTE and CIMENCAM CEM II 42.5R cements.We remember that both have good characteristics (meeting the standards).Nevertheless, each of them presents a specificity in the face of a specific task: • CIMENCAM has a fine particle size and a good resistance in short and long run young and long term, so it is recommended to use this cement for work requiring high strength such as beams, poles.• On the other hand, DANGOTE, has a slightly coarser grain size, it is less exposed to shrinkage and venting, so it is recommended to use it for finishing work such as wall and floor covering, prefabrications.Filling element (cinder block, Urdis), the realization of the decorative elements.

Conclusion
Determining the physico-mechanical characteristics of the CEM II 42.5 R cements used in Cameroon was the main objective of our study.For this purpose, we have carried out various tests on fresh and cured concrete, standard mortar and standard cementitious paste.Examples include cement setting tests, bending and compression tests on hardened concrete.The study was carried out from two cements encountered in Cameroon namely: CIMENCAM and DANGOTE.We stopped at 28 days which is the number of days at which the reference resistance to compression of concretes or mortars is determined.Hence the values of the 28-day compressive strengths on the mortar specimens are as follows: CIMENCAM (54 MPa) and DANGOTE (45 MPa).Thus we have been able to determine that CEM II 42.5 R cements can be used in masonry for reinforced and stressed concrete that is to say for standard structures requiring high resistance.The results shown in our paper present in a non-exhaustive way, a general idea about the different types of CEM II 42.5 R cements used in Cameroon.

Figure 2 .
Figure 2. Series of sieves used for sieve size analysis.

Figure 4 .
Figure 4. Apparatus for los angeles trial.

Figure 7 .
Figure 7. Vicat apparatus equipped with a 1.13 mm needle for the setting test.
(a)).Finally the molds are put on a vibrating table for tightening the concrete.Moreover, the tightening time depends on the consistency of the concrete.The standard NF EN 12390-1 is the one that regulates the dimensions of molds.The test pieces must remain in the mold and be protected against shocks, vibrations and desiccation for at least 16 hours and up to 3 days at a temperature of 25˚C ± 5˚C in hot countries and 20˚C ± 5˚C[22].After demolding, the concretes are kept in a maturation basin (Figure9(b)) until the expected day of crushing[22] [23]  [24][25].

Figure 8 .
Figure 8. Measurement of subsidence and cone of Abrams and its accessories.

Figure 11 .
Figure 11.Graph showing the fineness of Blaine of the cements studied.

Figure 12 presents
Figure 12 presents the results obtained following the consistency test on the two different cements studied.

Figure 12 .
Figure 12.Graph showing the consistency of the cements studied.

Figure 13 .
Figure 13.Graph showing the setting time of the studied cements.

10 Figure 14 .
Figure 14.Graph showing the slump of fresh concrete of the studied cements.

Figure 15 .
Figure 15.Graph presenting the density values of fresh concrete of the studied cements.

Figure 16 .
Figure 16.Semi-wet density of hardened concrete as a function of aging age.

Figure 17 .
Figure 17.Resistance to compression at different days of maturation.

Table 2 .
Consistencies of the cements studied.