Synthesis and Characterization of Novel Nano Derivatives of Graphene Oxide

Graphene oxide has many carboxylic groups within its molecular structure, which is perfect for esterification and imidation, the derivatives graphene oxide GAP, GSO when reaction grapheme oxide with 2-amino pyridine (GAP) and 2-hydroxy-5-sulfobenzoic acid (GSO). These derivatives have been characterized by FTIR, H1 NMR, XRD and FSEM. The patterns of XRD calculated particles size using two equations and compared between them.


Introduction
Graphene oxide is one of the carbon allotropes with a Nano size that gives a high surface area and the ample of oxygenic functional groups that gives the ability to react and join with active or catalysis material [1]. This modification on graphene oxide makes it able to save and generate energy; furthermore, these functional groups give it porous structure, so it could be used as current collector or doped material for electrodes in supercapacitor or lithium batteries [2]. This distinctive nano structure of graphene oxide enables us to use it in various applications like electronics, fuel cells, supercapacitor and sensors. In principle, we can't use graphene oxide in applications that require electric conductivity. This is due to poverty of graphene oxide to electrical conductivity [3]. Graphene oxide is similar to structure of graphite layer, but the plane of carbon atoms in graphene oxide is heavily decorated by oxygen-containing groups [4], GO has many exogenous functional groups such as epoxy (bridging oxygen atoms), hydroxy in the basal plane, carboxyl and carbonyl moieties lining the nanosheet edge [5].
In this study, new Nano compound derivative is synthesized from graphene oxide and can be used in several application corrosion inhibitors, solar cell, biological, electronics, etc.

Preparation of Graphene Oxide (GO)
Graphene oxide was prepared according to Hummers [6] method, 2 g of graphite was added to cool 50 ml concentrated H 2 SO 4 and stirred in an ice bath for 15 minutes. 1 g of sodium nitrate and 6 g of potassium permanganate were added to above solution and stirred in an ice bath for 2 hours. The ice-bath removed and the temperature of the mixture was kept at 35˚C in water path for 30 minutes. After that, the mixture became pasty (deep red-brown in color). 50 ml of deionized water was then added to above mixture. The temperature then raised to 90˚C -98˚C. The above mixture was diluted by addition 250 ml warm deionized water. Following this, 30% H 2 O 2 (~30 ml) was added till the solution turned bright yellow. The graphite oxide powder was dried at 40˚C for 24 h [7] [8] shown in Figure 1

Preparation of GAP
The GAP derived from GO, mix of grapheme oxide (0.5 g) with 2-amino pyridine (9.4 g, 9 mmole) dissolved in DMF 100 ml sonicated for 1 h to form homogeneous solution, then added DCC (2.06 g, 10 mmole), DMAP (1.22 g, 10 mmole). Then the mixture was stirred at 45˚C for 24 hours. To quench the reaction, an equimolar amount of HCl was added to the solution to neutralize DMAP, after the reaction finish, the product was filter, then black powder was dried [9] shown in Figure 2.

Preparation of GSO
The as-synthesized GO has many carboxylic groups within its molecular structure which is perfect for esterification, First, GO (0.5 g), with 7-hydroxy-5-sulfobenzoic acid were dissolved in DMF, 100 ml at the room temperature then DCC (2.06 g, 10 mmol) and DMAP (1.22 g, 10 mmol) sonicated for 1 h to form homogeneous solution. The mixture was stirred at 45˚C for 24 hours. To quench the reaction, an equimolar amount of HCl was added to the solution to neutralize DMAP the product was filter, then black powder was dried [9] shown in Figure 3.

X-Ray Diffraction (XDR) of GO, GAP and GSO
In Figure 6(a), the X-Ray Diffraction (XRD) of grapheme oxide shows a large interlayer spacing equal to 8.06 A˚ at the position (2θ = 10.97˚) disappearance of the peak at 26˚ due to completely oxidized after the chemical oxidation and exfoliation [6].     7-hydroxy-5-sulfobenzoic acid at graphene oxide also intermediate layer [13].
The Diffraction patterns of X-ray to prepared organic compound particles size is calculated using (Debye-Scherer) equation [14] cos where; D: Particles size, λ: X-ray wave length (nm), β: Half width at half maximum (HWHM), K: is s related hape factor, normally taken as 0.9. θ is X-ray angle. From this equation the particle size of grapheme oxide (GO) (16 nm) but to calculated average particle size to prepared organic compounds GAP (23.22 nm), GSO (40.74 nm). Also calculated particles size using (Williamson-Hall) (W-H) equation [15] [ ] where £ micro strain of particles, λ: X-ray wave length (nm), β: Half width at half maximum (HWHM), K: is s related hape factor, normally taken as 0.9. θ is X-ray angle where calculated to depend on XRD θ to compound in Figure 6(b) and  Table 1.

Field Emission Scanning Electron Microscopy (FESEM)
The FESEM of graphene oxide (GO) very sharp edges and flat surface the dark gray areas consist of several layers of sheets also kinked and wrinkled areas [6] ( Figure 8(a)), but GAP appeared relatively coarse very sharp edges and flat surface (Figure 8(b)), GSO the re-stacked layers and crumpling, kinked and wrinkled areas [16] [17] (Figure 8(c)).

Conclusion
Graphene oxide is synthesized by Hummer method and derivative GAP is prepared by reaction graphene oxide with 2-amino pyridine, GSO when graphene oxide reacts with 2-hydroxy-5-sulfobenzoic acid, graphene oxide and their derivatives characterization by FTIR, H1NMR and XRD. The patterns of XRD calculated particles size using two equations (Debye-Scherer) and (Williamson-Hall) compared between (Debye-Scherer) equation and (William-son-Hall), and the average particles size using (Debye-Scherer) equation high and (Williamson-Hall) to the attributed width peaks to particles size and Internal emotion, which is small when using powders. Also graphene oxide and their derivatives characterize by FESEM observed dark gray areas consist of several layers of sheets and light grey areas represent few layers.