Advanced thermopile IR dual line sensor for smart home

This article presents all steps between the advanced design and the production of CMOS compatible thermoelectric effect infrared sensors dedicated to smart home applications. It will start by making a comparison between thermopile, bolometer and pyroelectric technologies. Although sensitivity performances available with bolometers appear to be better at first sight, it is found that thermopiles have non-negligible advantages that make them more suitable for this application field. Then the different steps necessary for the design will be described, starting from the thermoelectric model of the sensor (temperature gradient, electrical sensitivity, etc.) and considering all steps up to technological manufacturing in a clean room. The results obtained on the structures produced on a specific computer-controlled measurement bench (temperature regulation with an onboard preamplification card) will be presented. Finally, the results prove that the square structures have better performances (S = 82 V/W and NETD = 208 mK).


Introduction
Progress in micro technologies now makes it possible to combine monolithic integration of new multifunction detectors with massive collective production to give good reliability. This technological progress, including particularly the application of micro-machining techniques and deposition of CMOS compatible thin layers, accounts for a large share of the economic stakes involved in low cost components for both military and civil applications. In the field of smart home application, user safety and comfort functions must necessarily be based on definite detection of presence of a person. Our proposed solution is based on an uncooled system running at ambient temperature (300 K) and adapted to the 7 -14 µm spectral band. These detectors firstly need to be sensitive to the types of photons emitted, but must also be capable of discerning small radiation differences centered about an average value in a high ambient background level. Thus, we will justify the choice of this technology in this study. The scientific community usually mentions pyroelectric effects [1], thermoelectric effects [2], [3] bolometric effects [4] and also thermomechanical effects [5] as electrical phenomena involved in the measurement of IR thermal flux. Their common operating principle is based on the resultant of a temperature rise of the detector under the action of incident infrared radiation that modifies the physical properties of a chosen material after it has been absorbed. Usually the IR sensor arrays consist of one membrane by pixel [6], [7]. In this paper we present an original technology that permits obtaining a dual line sensor in one-off membrane for all pixels. We will restrict ourselves to a comparison of the thermopile and bolometric technologies in Section 2.
We then present the thermoelectric model necessary to evaluate and to theoretically size fundamental parameters of the sensor in Section 3. We will then describe the different technological steps essential to the production of sensors in Section 4, and Section 5 presents the specific characterization bench that we made so as to evaluate the performances of the different structures produced. Finally, we conclude this work by presenting the results obtained from the sensors as a function of their topology.

Advantages of the Thermopile Compared with the Pyroelectric and Bolometric Detection in a Smart Home Application
The detection capacity of pyroelectric sensors derived from the uncooled detectors line is differentiated from other sensors because it is restricted to detecting the dynamic behavior of a person rather than his intrinsic static presence. In other words, if there is no mechanical action to generate flux variations, the sensor can detect if a person is present and moving, but can never detect a person who is not moving. As a result, technologies making use of bolometric and thermoelectric detectors potentially offer the best solutions for satisfying new requirements, particularly for the static detection of persons. Table 1 summarizes the advantages and disadvantages of each technology so that we can study them and make a selection The information in the Table 1 are extracted from publications about microbolometer and thermopile sensors [8]- [13]. At first sight, the microbolometric sensor appears to be an attractive choice. Compared with the thermopile, its detectivity is higher; it has a high performance NETD and a significantly better response time. Obviously, these qualities are necessary, but they may not be sufficient. The specificity of the system to be designed is such that, above all, it must This is why, due to the maturity of silicon microsystems, prospects for collective production and low manufacturing costs, we have decided to design, make and characterize different thermopile topologies for the development of a presence detector within the LAAS-CNRS laboratory.

Single Pixel Thermoelectric Model
We thought it was important to model the thermopile first so as to obtain the best possible size for the adapted structure. The typical topology of the detector is shown in Figure 1, based on the association of thermojunctions connected in series to increase the output voltage. The thermoelectric properties of conducting materials cause the appearance of a potential difference due to the effect of differential temperature rise (K) between the two thermojunctions, where denotes the Seebeck voltage [14] [15]. This self-generated voltage is defined as a function of the total number N of thermocouples and their corresponding See- In Equation (1), R th (K/W) represents the thermal resistance of the thermopile, η represents the absorption coefficient and P 0 the radiative power (W) collected by the absorbent surface area of the sensor S a (m 2 ). The ratio of the generated voltage ΔV and the received power P 0 represents the electrical sensitivity of the thermopile, denoted v ℜ , ( Taking account of the symmetry properties of the structure, we modeled the entire sensor analytically along the x direction and we calculated the thermal gradient ΔT between the ends of the thermojunctions using the Fourier stationary heat equations Equation (2) considering the thermal conduction flows in the materials, and the heat fluxes exchanged by convection and radiation.
where λ is the thermal conductivity, d is the material thickness, h is the coefficient of convection, σ b is the Stefan-Boltzmann constant, ε is the coefficient of emissivity and T(x) is the temperature along the element x ∂ .
The temperature gradient between the hot and cold thermojunctions was determined by separating the global structure into 3 zones. We solved the heat transfer equation as a function of boundary conditions at the boundary of each of zone, respecting temperature continuity and conduction fluxes. Thus, the expression obtained for the temperature gradient ΔT between T c and T h is presented in Equation (3), in which the coefficients A 2 , 12 ξ , 23 ψ represent the total losses of heat exchanges per unit area and conduction flux shape factors [16], respectively.
The electrical sensitivity v ℜ is written as follows [16]: The model that we developed takes account of the influence of the size of the absorber, the membrane and the thermocouples. We performed a detailed study [16]  ber increases, it also shows that this reduces the sensitivity of the sensor ( Figure   3). Oversizing the absorber reduces the total thermal resistance of the thermopile.

Manufacturing of Micromachined Dual Line Thermopile Sensor and Package Assembly
The figures of the technology process ( Figure 4) consist of a cross section of the thermopile array, crossing the device in the middle of the pixels.   The silicon rim showed between pixels is connected to the silicon bulk to insure the cold junction reference at the edge of the membrane. This approach is applied to our dual line sensor (thermopile array: 2 × 8).
The initial substrate on which all technological steps of the thermopile are based has the following characteristics: diameter 4", crystalline orientation <100>, material type N, 4 -40 Ω•cm −1 , thickness 300 µm with polished faces.
Note that the manufacturing procedure is independent of the geometrical shape of the structures to be made (square, rectangular, etc.). We made the absorber after a first step dedicated to making alignment patterns etched in silicon by DRIE ( Figure 5). We did this by doping a strong concentration of boron using a solid source doping process. This boron layer is located at the center of the sensor to enable conversion of IR radiation into heat necessary for operation of the thermopile. We positioned the absorber area under the membrane because the high concentration of boron carriers becomes effective stop-layers during the chemical etching [21] of silicon when the membrane is released. Figure 6 shows the SIMS doping profiles on which we measured a concentration of 1 -1.5 × 10 20 cm −3 carriers over a depth of about 3 -5 µm.

Design and Manufacturing of a Specific Measurement Bench
We designed a specific measurement bench dedicated to thermopiles in order to evaluate the sensitivity to an infrared flow, temperature drifts and NETD. An  The temperature regulation system was designed so that it is possible to use it with a multifunction card controlled by a computer (automatic mode) or by an external control (manual and standalone mode). The choice of the element controlling the temperature variation is made on a Peltier effect thermoelectric cell (TEC). We added a temperature regulation to achieve optimum operation of the TEC (DT12-4). The temperature stabilization is based on the use of a PID corrector, a power amplifier (60 W) for control of the TEC, a type K thermocouple temperature measurement associated with a specific amplifier (AD595) and low noise operational amplifiers for the control (LT1124). The PID corrector is chosen so as to optimize the precision, stability and speed of the system (Mφ = 45˚ et 2 2 ζ = ). To do this, the size of the corrector requires knowledge about the system to be slaved, in other words the equations have to be identified in the Laplace domain of the complete system. Furthermore, the Peltier effect cell and the power amplifier were allowed for in the identification method (Broïda method [26]). In doing so, we modeled the complete thermal system using high level simulation tools such as the Matlab-Simulink software. Thus, the designed thermal system can be used to configure the sensors within a temperature range varying from −5˚C to +70˚C. Figure 11 and Figure 12 show a few experimental measurement examples to illustrate performances obtained by our systems. The average time response of the system with three successive temperature steps (5˚C, 10˚C and 15˚C) is obtained in about 15 s (Figure 12). For example, the temperature control system can maintain a constant temperature of 46˚C with a static error measured at ±0.05˚C over a period of 11 h (Figure 13), over a long usage cycle.
Knowing that the thermopile is a DC voltage generator outputting a very low amplitude signal (a few hundred nanovolts to several millivolts) with a frequency range not exceeding about ten Hertz, this type of signal must be processed by an amplifier combining high gain and high impedance inputs. The noise and offset must also be reduced to not disturb the measured signal. Therefore the choice of components that contain the amplification system is of fundamental importance for this type of sensor. Since the circuit is designed to be inserted on the temperature regulation card, it is probable that it is affected slightly by   temperature variations, particularly generated by the TEC. This is why the electronic architecture of the amplifier is such that it disturbs the measurements as little as possible. Furthermore, note that the electronics designed for this assembly are very similar to the assembly used for the final presence detection module that must also have a low temperature drift to not distort detection. The initially plan was to use a classical instrumentation amplifier with high gain and high CMRR. This type of component has a high performance differential amplification but has the disadvantage of the temperature drift of its offset (0.2 to 0.8 µV/˚C). This is why our choice has changed to chopper type amplifiers that have excellent performances for offset and temperature drifts. This amplifier range considerably reduces their own offset and noise level by a so-called auto-zero approach [27]. Thus, among components available on the market, op- found that the temperature drift of the circuit is 865 µV/˚C over a temperature range between 25˚C and 50˚C.
The measurement bench is automated using the LabVIEW software [29]. Different programs have been defined to perform temperature scans, constant temperature measurements and to adjust the offset. This enabled us to do a real time acquisition of the voltage output by the preamplification circuit, temperature and time. Finally, Figure 14 shows an overview of the regulation bench on which can be identified the temperature card, the preamplification card and the sensor housed in its machined aluminum support.

Evaluation of the Electrical Sensitivity
Performances of infrared flux thermopile sensors are evaluated at constant temperature. The sensor is positioned a few centimeters away from the black body.
The measurement bench keeps the sensor temperature constant in this situation.
The power P c of the radiation flux collected by the thermopiles has to be known so that the sensitivity of structures can be determined. This is evaluated using the following equation [30]: Since the two types of structures have the same number of thermocouples, square structures have significantly better sensitivities for the same arm length.
As we demonstrated in our model, these results clearly show that oversizing the absorber affects the sensitivity of the sensors.

Evaluation of the Electrical Sensitivity
It is useful to evaluate the influence of the temperature drift of a sensor on its own performances, to satisfy the needs of our target application. It can be compensated by determining the equation for variation of the sensor. Compensation can then be achieved by a simple measurement of the sensor temperature.
Therefore, we can use the measurement bench to configure the sensor temperature range. This is done by positioning the sensor a few centimeters from the black body (40 mm) and the temperature setting is 45˚C to submit it to a constant radiation flow. We use the measurement bench to emulate an equation for variation of the internal temperature of the sensor. The temperature range is between 10˚C and 45˚C with a time between each measurement point equal to 1mn. The black body has a temperature of 45˚C and is 40 mm from the sensor.
The results presented in Figures 15-18 show that the average drift of rectangular structures evaluated after amplification is 58 mV/˚C for 400 µm arms and 78 mV/˚C for 800 µm arms. The average drift for square structures is evaluated at 52 mV/˚C for 400 µm arm and 75 mV/˚C for 800 µm arms.
These results show that the topology of the structures is not preponderant for the drift of sensors because the differences measured between square and     rectangular structures for the same length of thermocouple arms are relatively small. This clearly shows the importance of the choice of materials, particularly in terms of the temperature coefficient of resistance (TCR) and not the simple thermal conductivity. During the design of a thermopile, it may be better to choose materials with lower thermal conductivities and implicitly a lower merit factor, but that minimizes the temperature drift of a sensor. It is then preferable to choose materials with a low TCR to achieve a better thermal stability of sensors.

Evaluation of the NETD
The measurement method is based on acquisition of the response of the sensor when it is subjected to two different homogenous temperature fluxes T 1 and T 2 .
Under the action of fluxes generated with a black body, the sensor outputs two consecutive voltages V T1 and V T2 at the temperature change [35]. The noise equivalent temperature difference (NETD) is evaluated using the following equation: with: The term V T ∂ ∂ represents the thermal sensitivity of the detector (V/K) where n V is the RMS noise voltage output from the sensor and the electronics of the preamplification circuit that we have described. Table 3 shows the experimental evaluation of the NETD for a few square and rectangular shaped thermopiles. Overall, we observe that the NETD of the thermopiles realized are between 222 mK and 395 mK. The results are significant. Structures with thermocouple arm lengths of 800 µm have a better quality NETD.

Conclusion
It is found that a thermopile has definite advantages over a bolometer for the development of a static presence detection system for smart home applications (no 1/f noise, linear response, self-generator, etc.). This work has enabled us to set up a methodology for modeling the temperature distribution along the structure by means of equations. We have presented its main characteristics in the form of analytic equations, to provide an aid to sizing of adapted structures.
We then presented all CMOS compatible technological steps necessary for manufacturing of the sensors. We designed and made a specific measurement bench and used it to evaluate performances in terms of electrical sensitivities, temperature drifts and NETD drifts, to characterize the different manufactured structures. Compared with the results in Table 3, it was found that the structures with optimal performances ( v ℜ = 82 V/W, R = 31 kΩ, NETD = 208 mK) are square in shape and have longer thermocouples (800 µm). We are now continuing this work, concentrating on two topics. Firstly, we are studying the potential physical influence of the contact surface between two component materials of a thermocouple on the global thermoelectric capacity of a thermopile. At the same time, we are developing wireless type electronics so as to integrate the matrix thermopiles produced into Wireless Sensor Network dedicated to smart home applications.