Geotechnical Study of the Aptian Limestone of the Kef Region , Northwestern Tunisia : Evaluation for Industrial Use

This study aims to the initial characterization of Aptian sedimentary limestones in the Kef region located in the North-West of Tunisia in order to use in industrial fields. The limestone samples were collected from three outcrops respectively named Jebel Jerissa, Jebel Hmeima and Jebel Harraba. A geochemical characterization highlights a variation of the weight percentage (wt%) as follows: CaO (53 55), MgO (0.04 0.28), Al2O3 (0.07 0.51), Fe2O3 (0.41 2.87), and a loss on ignition (41.62 43.35). The other oxides (K2O, SO3, Na2O) are in trace amounts. Mineralogical analysis revealed that limestones contain more than 95% of calcite and the clay impurities are the minor phases detected. Petrographic study showed that these limestones are packestone-wakestone type. The hardness of Aptian limestones crosses the upper limit of the hard domain. Geotechnical tests reveal a Dry Micro Deval (MDS) coefficient varying from 23% to 33%, a Wet Micro Deval (MDH) coefficient with values oscillating around 26% to 36%, a Los Angeles coefficient (LA) about 25% against a value of the compressive strength ranging from 593 Kg/cm to 866 Kg/cm. The gravimetric tests highlighted a flexural strength value from 106 Kg/cm at 208 Kg/cm, while the ultrasonic coefficient oscillates from 4876 m/s to 5233 m/s, indicating the low porosity of these limestone (0.5% to 1%). The density recorded an average value of 2.50 g/cm. The various properties studied have proved that the limestone studied can be used in various industrial fields such steel industry, aggregate, cement industry and marble.


Introduction
Since the works of [1] and his successors, mainly most of them [2] [3] and [4], particular attention has been paid to the series of central and northern Tunisia of the Algerian-Tunisian borders.These series show impressive sedimentary accumulations during the Aptian-Albian periods.[2] describes the Aptian succession exceeding 2200 m thick at the Algerian-Tunisian borders.Impressive calcareous series [5] appears similar throughout the area, such as the "Limestones of Serdj" which have been deposited in certain sectors.These carbonate series belong to a vast platform that extended throughout Central Tunisia [6] and a large part of Northern Tunisia (Slata, Djerissa, Hameïma, Harraba, Boulahnèche...).
We selected three study sites in the Kef area: the Hameïma, Djerissa and Harraba deposits, which will be the subject of a petrographic and geotechnical study.This area are located between 35˚15' to the south and 36˚8' to the north and meridians 8˚47' to the east and 8˚18' to the west (Figure 1), belongs to the topographic set of Upper Tell [7] marked by a limestone and marl-limestone geological substratum.Despite the number of studies launched in the extreme north Western Tunisia [8] [9], physicochemical and geotechnical characterization of Aptian limestones and their behavior remain unknown.The Aptian limestones Figure 1.Location of the study area.
of the Kef area have been studied for possible use in the industrial field.The study was carried out on forty-five samples taken from the blackish gray limestone deposit of Hmeima, the deposit of Jebel Harraba and the massif of Jerissa (Figure 2).

Materials and Methods
The available methods for sustainability study are described in Figure 3.
The chemical analysis of the major elements of the useful materials was assayed using the Atomic Absorption Spectrometry technique, which applied to the determination of the content of a sample in CaO, MgO, Al 2 O 3 , MgO, Fe 2 O 3 , Na 2 O and K 2 O. Sulfates were determined by conventional dosage and the gravimetric method for evaluating the weight loss of material after firing at 1000˚C.The mineralogical analysis was performed using an X-ray diffraction device based on the diffraction of a monochromatic X-ray beam according to Bragg's     The compression strength test was carried out according to [10].It's consists of the measurement of the resistance of the rock to crushing by progressively applying the pressure up to the break of the specimen.The test was carried out by a hydraulic press.The bending test was carried out according to [11] and consists of the measurement of the resistance of the rock to loads when it is placed above a vacuum when we applied load with an effort of 0.2 N/mm 2 per second.The real density determines the degree of compactness of the rock.The impact strength was determined according to the standard [12] and consisted in dropping a ball that weighs 1 kg attached to a wire.This mass will be released at different heights until the specimen breaks.The resistance of abrasion was achieved according to standard [13] and consists in determining the length of the print produced on the specimen by the edge of a metal disc rotating under specified conditions in the presence of abrasive material.The porosity test was carried out according to the standard [14] and aims to know the ratio of the voids in a rock.The Apparent and real densities was carried out according to standard [14].The test samples used are dried before use at a temperature of 80 ˚C to a constant weight.The ultrasonic test is carried out in accordance with the requirements of [15].The result defines the propagation velocity of a sonic wave across the rock.
For aggregate tests, sampling was carried out according to [16], which applies to all aggregates used for civil engineering (concrete, asphalt, surface coatings, etc.).To comply with the rules of sampling a corridor divider was used.The Los Angeles test was carried out in accordance with standard [17] and aims to determine the resistance to fragmentation of a sample of aggregate.It consists on measuring the amount of element less than 1.6 mm produced by subjecting the material to a series of friction shocks in the Los Angeles apparatus which consist of a cylinder measured inside (508 ± 5) mm and has a diameter of (711 ± 5 mm) and is manufactured with a 12 mm thick sheet.The Micro Deval test defines the wear resistance of a granulate sample according to [18].The Micro-Deval abrasion test is a test of fine aggregate to determine abrasion loss in the presence of water and an abrasive charge.The Micro Deval apparatus consists of a number of test cylinders having a diameter of (200 ± 1) mm and an inside length of (154 ± 1) mm, watertight and laid on two horizontal supports driven by a motor rotating (100 ± 5) rpm.The stainless steel balls used have a diameter of 10 ± 0.5 mm.The tests can be carried out dry or wet.The density and absorption coefficient are determined by the pycnometer method for aggregates in accordance with [19].The petrographic study of limestones was based on the two facies description nomenclatures, combining the nature of the constituents of the rock: cement, matrix and porous space [20] with the percentage of elements represented by (Mudstone: < 5% allochems, wackestone: >5% allochems, packstone and grainstone: Allochems joined) [21].This study is carried out at laboratory and consists essentially of the observation by means of a Zeiss Axiosskop 40 microscope using polarized light.The interpretation of the micro facies identified was done through thin sections.

Chemical Analysis of Deposits in the Kef Region
Chemical analysis of Aptian limestones in the Kef area is presented in Table 2.
Chemical analysis of Aptian limestones (J.Harraba, J.Hmeima and J.Jerissa) showed a similarity in geochemical distribution by recording a percentage of CaO varying from 41% to 43% for all outcrops, a low content of Fe 2 O 3 with the exception of Jebel Jerissa (2%), infinitesimal contents for other oxides such as MgO, Na 2 O and K 2 O.The loss on ignition was 42%, indicating a chemical purity of these limestones.These results are confirmed by the mineralogical analysis (Figure 4), where the XRD patterns show a very high content of CaCO 3 (with an average of 95.80%) with low impurity contents.

Gravimetric Characterization of the Aptian Limestones of the Kef Region
The results of the gravimetric tests of Aptian limestones are presented in Table 3.
Gravimetric tests of Aptian limestones showed an acceptable flexural strength of 200 Kg/cm 2 compared to a compressive strength of around 600 Kg/cm 2 and sometimes greater than 850 Kg/cm 2 (J.Jerissa).The impact wear values were greater than 28.44 mm, while the ultrasonic coefficients oscillate around 5000 m/s, indicating the low porosity of this limestone (0.5%).All samples showed a reduction in strength, probably caused by the cementing material, which in this case is calcite [22].Other possible explanation is the reduction of surface particle energy [23], or a modification of particle binding due to interstitial pressure in poorly drained samples [24].Analysis of the whiteness of limestones revealed a whiteness index of 83.22% and a chromatic tendency towards yellow (J.Harraba) or gray (J.Hmeima) or brown (J.Jerissa).

Mechanical Characterization of Aptian Limestones of the Kef Region
The results of the mechanical tests of Aptian limestones are presented in Table 4.

Aptian limestones in the Kef region have a variable Dry Micro Deval (MDS)
coefficient about 32% for the outcrops of Harraba and Hmeima compared to a value of 23% for that of Jerissa.The Wet Micro Deval (MDH) coefficient was around 33% for the Harraba and Hmeima deposits against a lower value for the Jerissa deposit.This is due to the presence of a ferruginous matrix acting as cement.The Los Angeles coefficient (LA) was about 25%.The values of compressive strength have an interesting value for Jerissa limestone (866 Kg/cm 2 ) compared to the acceptable values for the two others deposits.All limestones studied had an apparent density (MVA) and a Real density (MVR), varying from 2.66 g/cm 3 to 2.67 g/cm 3 .The study of the limestone hardness in the Kef area (Figure 5) showed that all Aptian limestone deposits are able to cross the limit of hard field according to [25].These results were confirmed by [26] who reported a hardness value rating of 7 to 8 and a compressive strength of 662 bars and a specific gravity of 2.54 g/cm 3 .

Petrographic Study
The petrographic examination of thin section representing the facies of the Aptian limestones (Figure 6) highlighted ferruginous inclusions in the cement and revealed the existence at least of two distinct phases of filling in karst.The karst affects the last calcareous bed of the Formation Serdj [27].This bench is a wackestone-packstone limestone with orbitolina type (Mesorbitolina texana, Paracoskinolina tunisiana and Archaeoalveolina reicheili), milioles and rudists ac- cording to [28] [29].The uniformity of these facies reveals a homogeneous and sedimentation character.The karstic surface was found in our three study sites: Hameïma, Harraba and Jerissa.Unlike in the last 50 meters of the Serdj Formation of the Harraba deposit, we found ammonites Mellegueicerasechihaouiae, as well as poorly preserved Douvilleiceratidae.The presence of phosphate forms suggested that they are reworked and highlight an Aptian-Albian line [30].Angeles and Micro-Deval [31].The specifications (Table 5) of the aggregates take into account the different fields of use depending on the association with hydraulic hydrocarbon binder [32].
The characteristics of aggregates used in concrete (Table 6), as defined either by [33] [34], rely mainly on their mechanical characteristics such as the Los Angeles, Micro-Deval and the water absorption coefficient.
The cement is generally made from a mixture of limestone and marl fired at a temperature close to 1450˚ C. The product thus formed is in the form of a module called Clinker, which, after fine grinding, will be added with a little addition (gypsum) to provide Portland cement.The quality criteria and permissible limits of the different cement components are shown in Table 6.Aptian Limestones of the Kef region can be used as a basis for the manufacture of cement CPA according Tunisian [35], but a restriction relative to their use for the production of hydraulic lime when their use is conditioned by chemicals corrections.In spite of their lithology, limestones have acceptable brightness index, however, its chromatic tendency towards yellow can play as a limiting factor for industrial use.The effect of oxidation by iron oxides is always felt.The calculation of the silica modulus (MS) and Alumino-ferric (MAF) modulus with the addition of Table 5. Specifications for road aggregates.the marls of the region give satisfactory results.For the field of concrete the carbonate outcrops find their place despite their inter-variability.

Criteria for Chemical and Agricultural Use of Limestones
Calcium carbonates and lime, derived from limestone, are widely used in agriculture, both as an amendment or soil corrector, as well as in the processing of agricultural products (sugar manufacture), animal, and human feed.The selecthe use of limestone are presented in Table 7.For certain uses other criteria are required such as the whiteness at least equal to 85% for the fillers and the compressive strength > 400 Kg/cm 2 for the rocks dedicated to lime.
All the carbonate deposits studied are favorable for use in the field of chemistry.
Their calcium carbonate content and the chemical composition of all the calcareous deposits reveal an interesting mineralogical purity and homogeneity.The CaCO 3 content greatly exceeds 95%.This use is strongly conditioned by the variability of the values recorded which is due to the degree of recrystallization and the limestone porosity in relation to the Grain which form the carbonated cement.
Table 7.Chemical criteria required according to the use of limestone [32].8.
The Aptian limestone of the Kef can used in various industrial fields such as the marble quarry sector.Since all deposits are favorable for use as a marble stone, a deposit study has objectified the estimation of the volume and dimensions of the blocks (Figure 7) that could be extracted according to the Table 8.Industrial parameters for use in marble [36].

Figure 4 .
Figure 4. XRD patterns of the Aptian limestone of the Kef region (J.Hmeima).

Figure 5 .
Figure 5. Hardness diagram of the Aptian limestone of the Kef area.

3. 5 . Industrial Use of Limestone 3 . 5 . 1 .
Technological Characterization Parameters for AggregatesThe specifications of the aggregates are based on their mechanical strength: Los

3. 5 . 3 .
Possibilities of Industrial Use of the Aptian Limestone Deposits of the Kef AreaThe use of limestone in marble industry depends on degree of importance relative to each technical parameter of the marble stones studied in relation to the various use in the field of construction was presented in Table

Figure 7 .
Figure 7. Block Diagram of the dimensions of the marble blocks extracted from the Aptian limestone.

Table 1 .
Dimensions of test specimens for marble stones.

Table 2 .
Chemical results of the Aptian limestone of the Kef area.

Table 3 .
Gravimetric result of the Aptian limestone of the Kef region.

Table 4 .
Geotechnical test results of limestone from the Kef region.

Table 6 .
Criteria for the use of aggregates in ordinary concrete and cement.