Effect of Zn Substitution on the Magnetic and Magnetocapacitance Properties of Nanosized Multiferroic GaFeO 3 Ceramics

This article aims to investigate the possibility to turn the multiferroic orders and magnetocapacitance effect close to/above room temperature in nanosized GaFeO3 ceramics by a sol-gel preparation method and substitution with non-magnetic Zn atoms. Therefore, in this work, we have synthesized a series of nanocrystalline Ga1−xZnxFeO3 (GZFO, x = 0, 0.01, 0.05 and 0.1) ceramic samples and study the effect of Zn substitution on their structural, magnetic, and electric properties. All the GZFO samples have an orthorhombic structure with Pc21n space group and the value of lattice parameters increase systematically with increasing Zn concentration. Interestingly, it shows that magnetic and electric properties are strongly dependent on the Zn substitution concentration. Based on the results of temperature-dependent magnetizations, M(T), it is observed that with increasing Zn-content up to 0.10, the ferrimagnetic transition temperature (TC) increases from 306 to 320 K. It is also found that the nanocrystalline Zn-doped GaFeO3 (GFO) samples exhibit the characteristics of ferroelectricity at room temperature. Furthermore, the magnetization, ferroelectric polarization and magnetocapacitance of Zn-doped GFO nanosized ceramics are enhanced compared to those of the pristine sample of GFO ferrite. These results open wide perspectives for the applications of room temperature multiferroic devices.


Introduction
Recently, multiferroic and magnetoelectric (ME) materials opened new avenues for the development of novel devices based on new functionalities such as con-New Journal of Glass and Ceramics trol of the magnetic properties by means of electrical fields and vice versa [1] [2].Among these materials, gallium ferrite, GaFeO 3 (GFO), has been reported to exhibit ferrimagnetic (FM) and piezoelectric orderings and has been intensively studied for its practical application as a ME ferrimagnet [3] [4].GFO crystallizes in non-centrosymmetric orthorhombic structure with a space group Pc2 1 n and with four different cation sites, that is, labeled Fe1 and Fe2, which are predominantly occupied by Fe 3+ and other two labeled as Ga1 and Ga2, which are mostly occupied by Ga 3+ [4] [5].The Fe1, Fe2, and Ga2 sites are octahedral surrounded by oxygen, while Ga1 site is tetrahedral coordinated by oxygen.In general, bulk GFO exhibits room temperature (RT) spontaneous polarization along the crystallographic b-axis and a FM structure below RT along the c-axis [4].As such, GFO is a quite interesting material due to simultaneous exhibit magnetic and electric orderings [6].In the past few years, several attempts have been directed towards the syntheses of new gallium ferrite compounds and studies of their related properties [7] [8].Moreover, the substitution of trivalent or divalent metal ion in GFO is a pronounced way to control various physical properties [9] [10] [11].However, the effect of the substitution of a non-magnetic cation on the net magnetization of a ferrimagnet is difficult to predict.It is depend on the site occupation of the non-magnetic cation with respect to the two opposing sublattices.The magnetization increase is possible, as in the case of the non-magnetic Zn 2+ -ions substitution into NiFe 2 O 4 [12].In addition, up to now, the Zn substitution effect on T C is not yet explored in literature.Accordingly, we aim to study the impact of substituting GFO with non-magnetic Zn 2+ for Ga 3+ -ion on the multiferroism.In this work, therefore, we synthesized a series of nanocrystalline Ga 1−x Zn x FeO 3 (GZFO, x = 0, 0.01, 0.05 and 0.1) ceramic samples by a sol-gel method to systematically study the effect of Zn substitution on their magnetic and multiferroic properties.

Sample Preparation
The nanosized ceramic samples of Ga 1−x Zn x FeO 3 (GZFO, x = 0, 0.01, 0.05 and 0.1) were prepared through a sol-gel method using nitrates as metal precursors.
First, gallium nitrate [Ga(NO 3 ) 3 ⋅xH 2 O], iron nitrate [Fe(NO 3 ) 3 ⋅9H 2 O] and zinc nitrate [Zn(NO 3 ) 2 ⋅6H 2 O] in stoichiometric proportions were dissolved in distilled water.Citric acid (C 6 H 8 O 7 ) in 1:1 molar ratio with respect to the metal nitrates was added to the solution as a complexant.The clear solution was dried at 120˚C to form a gel, and then the obtain gel was burned until the combustion process was completed.After that, the precursory powders were reground and sintered at 800˚C for 12 h.

Characterization
The crystalline structure and the phase purity of the obtained samples were characterized with a typical X-ray diffraction (XRD), acquired by a Bruker D8 Ad-vance X-ray diffractometer Cu K α1 radiation.The XRD data were fit using the General Structure Analysis System (GSAS) Rietveld refinement program.Micrographs of the samples were analyzed using a field emission transmission electron microscope (TEM) operated at 120 kV.The temperature-and field-dependent magnetizations were measured with a Quantum Design superconducting quantum interference device (SQUID) magnetometer.For the magnetocapacitance (MC) measurements, the powders were pressed into the disk (5 mm in diameter and 0.5 mm in thickness) under a pressure of 1.5 GPa and then coated with 100 nm thick silver layers on both the top and the bottom sides of the disk as electrodes.A capacitance bridge (Agilent E4980A Precision LCR meter) hooked to a probe station with a closed-cycle low temperature system was used.Room temperature ferroelectric measurements were performed using a Sawyer-Tower circuit and a commercial FE test system (TF Analyzer, aixACCT Co.).

Crystal Structure
The RT XRD patterns of the Ga 1−x Zn x FeO 3 samples with x = 0, 0.01, 0.05, and 0.1 are given in Figure 1.Based on the standard reference (JCPDS Files No.26-0673), all the observed peaks of the GZFO samples can be indexed on the basis of an orthorhombic unit cell of space group, Pc2 1 n, suggesting that all samples without any secondary phase.The GZFO samples of various Zn-content, namely, 0, 1, 5, and 10 at % designated as GZFO1, GZFO2, GZFO3, and GZFO4, respectively.
The lattice parameters were determined by Rietveld refinement method and listed in Table 1.As an example, the profile fitting of GZFO2 sample using GSAS Rietveld refinement program is shown in Figure 2. The fact that the value of the unit cell volume and the lattice parameters a, b, and c of GZFO increase systematically with increasing Zn-content (x) implies that the Zn-ions do replace the Ga-ions.This could be attributed to the larger ionic radius of Zn 2+ ion (~0.74 Å) than that of Ga 3+ ion (~0.62 Å), which clearly confirms that the zinc is successfully doped in the lattice of GFO.According to the calculation using a Debye-Scherrer equation [13], the average grain size of the GZFO samples are about 30 nm.The grain sizes were also confirmed by TEM.As an example, the TEM image of the GZFO2 sample is shown in the inset of Figure 2. In order to measure the orthorhombic distortion [14], we have calculated the values of c/a and 2 c/b of each GZFO samples (shown in Table 1).It is evident that the Zn substitution affects the structure of the pristine sample by increasing of the orthorhombic distortion of the perovskite lattice parameters of nanocrystalline GFO.

Magnetic Properties
The temperature dependence of magnetization, M(T), was measured in a magnetic field of 1000 Oe under the condition of field-cooled (FC).228 K in bulk GFO [4].The results could be explained on the basis of variation of Ga/Fe occupancy due to the disorder effects, which in turn alters the bond parameters of Fe-O-Fe and hence the strength of the magnetic interactions [4] [7].
The field-dependent magnetization M(H) curves of all the GZFO samples measured at 5 K are presented in Figure 4.And also, the M(H) loops for all the GZFO samples observed at RT are shown in the inset of Figure 4. On can observe from the M(H) data that all the samples exhibit pinched-like hysteresis loop behavior of two phase systems as indicated by the fact that the loops could be decomposed in two additive loops with different coercivities.A similar type of M-H loop is reported by Kim et al. [5], in GFO and AlFeO 3 , and explained it in terms of the existence of hard and soft magnetic phases.Because of the fact that the four cation sites have different magnetic anisotropy energies in GFO, namely, the octahedral sites (F1, F2, and G2) have strong anisotropy, whereas the tetrahedral site (Ga1) is weak anisotropic, and hence these act as hard and soft magnetic phases, respectively [15].In addition, the magnetization has been enhanced due to doping of Zn 2+ in GFO compared to that of the pristine sample.The cause of magnetic enhancement could be explained from the modification exchange interaction due to the substitution of larger size cations of Zn 2+ in place of relatively smaller size cations of Ga 3+ .Therefore, it is expected that with the variation of Zn-content in GZFO samples, there is a substantial change in cation distribution and hence in the magnetic properties.

Electric Properties
To investigate the presence of spontaneous polarization, the ferroelectric polarization-electric field (P-E) loops for the Zn-doped GFO samples were measured at RT are shown in Figure 5(a).Here, the P-E loops taken at an applied maximum electric field of 30 kV/cm for each samples.It is found that all three samples show clear hysteresis loop behaviors that confirms the existence of ferroelectricity.Figure 5(a) also shows that maximum polarization and the tendency  In order to know the coupling between the magnetic and ferroelectric orderings, we have measured the dielectric constant of the GZFO samples in presence of an externally applied magnetic field.The change in dielectric constant with the applied magnetic field is one of the important ways to study the coupling effect [16] [17].Figure 5(b) shows the variation of MC which is calculated by the expression [17], MC = [ε′(H, T) − ε′(0, T)]/ε′(0, T).Here, ε′(H, T) and ε′(0, T) represents the dielectric constants in presence and absence of external magnetic field (H), respectively.In such GZFO sample, the dielectric constant is strongly perturbed by the external magnetic field.It is confirmed the presence of FM and ferroelectric coupling, that is, the multiferroic state in all the GZFO samples at RT.It is to be noted that the value of MC increases in the doped samples for different applied magnetic fields.And also, the values of MC for nanosized GZFO ceramic samples are higher than that observed for bulk GFO [6].To further probe the electrical leakage effect, the leakage current densities (J) were measured for all the GZFO samples at RT as shown in Figure 6.It shows that the Zn substitution in GFO allows decreasing the leakage current density by two orders of magnitude, as shown in the inset of Figure 6.We attribute the decrease of the leakage currents to the substitution of Fe 2+ with Zn 2+ , decreasing the hopping possibilities between Fe 2+ and Fe 3+ within the structure; a similar behavior has been reported by Lefevre et al. [18].

Conclusion
In summary, we have studied the effect of Zn doping on the multiferroic properties of nanocrystalline GZFO samples prepared by a sol-gel method.It shows that magnetic and electric properties are strongly dependent on the Zn-doping.
The magnetic characterization indicates that with an increase in the Zn-content, the FM transition temperature increases from 306 to 320 K.It is also found that Figure 6.Leakage current density (J) as function of applied electric field (E) measured at RT for the GZFO samples.Inset shows an enlarged view of the raw data for the GZFO samples at negative electric field.

Figure 2 .
Figure 2. XRD patterns of the GZFO2 sample along with the Rietveld refinement.Inset shows the TEM image for the GZFO2 sample.

Figure 3 .
Figure 3. Temperature-dependent FC magnetization for the GZFO samples.Inset shows temperature dependence of the derivative of the FC curves for GZFO1 and GZFO4 samples.

Figure 4 .
Figure 4. Magnetic hysteresis loops M(H) measured at 5 K for all the GZFO samples.Inset shows M(H) loops of GZFO samples measured at RT.

Figure 5 .
Figure 5. (a) P-E curves for GZFO2, GZFO3 and GZFO4 samples measured at RT with 1 kHz frequency; (b) The variation of MC with magnetic field for all the GZFO samples observed at RT.

Table 1 .
Rietveld refinement data of GZFO samples with different Zn-content.