Experimental Study on the Radiative Properties of Fly Ash in the Radiant Syngas Cooler of Gasifier

Radiant syngas cooler (RSC) is the key heat recovery equipment in coal gasification system. The syngas from gasifier carries large amount of slags in which the mass fraction of fly ash less than 100 μm is about 20%. Studying the optical properties of fly ash has high significance for the optimization of heat transfer calculation in RSC. A new experimental method was proposed to inversely calculate the radiative parameters of particles—“KBr transmittance-reflectance method”. By measuring the “directional-hemispherical” reflectance and transmittance of fly ash particles by FTIR under the wavelength range of 0.55 1.65 μm, using the four-flux model to solve the radiative transfer equation and combing with Mie theory, the absorption and scattering efficiency of 22.7 μm fly ash and optical constant (also known as complex refractive index, m = n + ik) of fly ash were inversely calculated. The results indicated that for fly ash with large size parameter, there was no obvious change of the absorption and scattering efficiency when the mass fraction of Fe2O3 was between 5.65% and 16.53%, which was well explained by Mie theory; The obtained optical constant was close to the results of KBr transmittance method.


Introduction
The syngas produced by various gasifiers contains about 10% to 20% calorific value which exists in the form of sensible heat.Usually, this part of the energy is not effectively used.For example, the high-temperature syngas in coal-water Z. F. Fu  by 4 -5 percents [1].
The syngas flowing into RSC carries a large amount of high-temperature slags, in which the mass fraction of particles less than 100 μm is about 20%.Because of its small size and large number density, this part of fly ash has a significant effect of light scattering on the radiation transfer in RSC [2].Therefore, the study of the optical properties of fly ash, including its absorption efficiency, scattering efficiency and optical constant, is important to the optimization of heat transfer in RSC.
The optical properties of fly ash are determined by chemical composition, size ), surface condition and geometry [3].In view of the radiative properties of fly ash, a lot of researches have been carried out mainly through the combination of calculation and experiment.Goodwin examined the optical constant of slags in the wavelength of 0.19 -13 μm by measuring the the near normal reflectance and transmittance, which is widely accepted [4] [5].Self and Ruan determined the optical constant by measuring KBr slabs that contain fly ash particles and then combining with Mie theory and K-K relation, but the extrapolation formula of the K-K relation will cause some deviations [6] [7] [8].
Meanwhile, the result of extinction coefficient k through this method is 10 -100 times larger than that given by Goodwin.This is because particles have larger surface areas than bulk [9].Yin and Liu obtained effective optical constant of fly ash based on the effective medium theory (EMT) of mean electromagnetic field [10].Self compared the optical constant of slag from 300 K to 1900 K.It was found that the k value of some wavelength increased by nearly three times [6].
Mengüc and Wall used light scattering method to measure the optical constant of coal and fly ash respectively, but this method was difficult to apply [11] [12].
In order to eliminate the errors from the extrapolation formula of the K-K relation and reduce the effects of forward scattering in KBr transmittance method, a "KBr transmittance-reflectance method" was proposed in this paper based on [13] [14] [15] to obtain the optical constant of 3.21 μm fly ash particles and the absorption and scattering efficiency of 24.8 μm fly ash particles.

Lorenz-Mie Theory
Lorenz-Mie theory is a classical algorithm used to solve the interaction between spherical particles and plane electromagnetic waves.It gives an exact solution to the scattering problem of spherical particles with any size.When a light with wavelength of λ is incident on an isotropic homogeneous spherical particle, the extinction, scattering and absorption efficiency of the particle can be expressed by the following formula [16] [17]: ) where x is size parameter; r is particle radius; a n and b n are called Mie scattering coefficients, which are calculated as follows: where m = n + ik represents the optical constant; are the Bessel functions which follow the recurrence relation: where, For dispersed particle system that satisfies the independent scattering condition, the scattering of particles has no effect on each other.The absorption and scattering coefficients of the particle system are the integral of the absorption and scattering efficiency by the particle size distribution, as follows: where λ µ represents the absorption coefficient scattering λ κ , scattering coef- ficient λ σ , extinction coefficient λ σ ; Q µ represents the corresponding ab- sorption, scattering and extinction efficiency; N denotes the number of particles per unit volume; f(D) is the normalized size distribution.For particles with same size, the relation is simplified as: Therefore, when the particle absorption, scattering coefficients and the size distribution are obtained from experiments, the absorption, scattering efficiency and optical constants of particles can be inversely calculated.

Four-Flux Model
The four-flux model is an approximate solution of radiative transfer equation to determine the absorption and scattering coefficients of materials.In four-flux model, it is assumed that 1) there is no emission of the sample at room temperature; 2) only a collimated radiative flux is incident onto the front surface of the sample; 3) at any position z inside of the sample, there are four parts of energy: a collimated beam I c (z) propagating to positive z, a collimated beam J c (z) propagating to negative z, a diffuse beam I d (z) propagating to positive z, a diffuse beam J d (z) propagating to negative z [18] [19].
As shown in Figure 1, 0~L denotes the KBr slab that contains fly ash particles; .
According to energy balance, the differential equations and boundary conditions can be established, see [20].In this paper, the total reflectance R and transmittance T at two planes of 0 and L are derived under diffuse reflection boundary condition.The formulas are as follows: (1 The constants in the formulas are found to be: where, where, a and s are the absorption and scattering coefficient respectively, and because KBr has no absorption in the infrared and partial visible spectrum, a and s are approximately treated as the absorption and scattering coefficient of the fly ash particles; L is the thickness of sample; ζ is the forward scattering ratio, which equals the energy scattered by a particle in the forward hemisphere over the total energy; ε is the average crossing parameter, which is defined by say- ing that, when the radiation light travels a length dz , the average path length is dz ε

Sample Preparation
The preparation of samples plays a crucial role in the experimental results.In the experiment, fully ground KBr was mixed with fly ash particles and then compressed into slab.The procedures of sample preparation are as follows: 1) Spectrum pure KBr pellets are ground into powder; 2) Fly ash and KBr are mixed with mass ratio 1:100; 3) The mixture was compressed using a tablet pressing machine under pressure 7 t/cm 2 ; 4) Because KBr is deliquescent, infrared heating was used to ensure that the preparation of sample was in a dry environment.    .According to the reversibility of light, the hemispherical-directional reflectance R and transmittance T were equal to directional-hemispherical reflectance and transmittance that are required in the four-flux model.Based on the experiment data, the absorption, scattering coefficients of the fly ash system can be calculated and then the absorption, scattering efficiency and optical constant of single particle can be further retrieved.

Optical Constant of 3.21 μm Fly Ash Particle
There is multiple value problem when calculating optical constant of particles with large size parameter, which means a group of testing data (R, T) will get multiple values of (n, k).Thus, the optical constant of fly ash was retrieved from particles 43 3.21μm D = .The reflectance and transmittance spectra are displayed in Figure 4.The calculated optical constant is shown in Figure 5.
As shown in Figure 5, n value is essentially in agreement with the reference data which is between 1.5 and 1.6.The k value is similar to the results of KBr transmission method in reference [21], and is quite different from the result of slag in reference [4].This is because particles have larger surface area than bulk materials, so that the measured k value of fly ash is larger than that of slag.
In the calculation of the heat transfer in RSC, the absorption, scattering coefficient and phase function of the fly ash particle system can be obtained according to the optical constant combining with suitable particle scattering model and particle size distribution, and the radiative transfer equation can be further solved.

Absorption, Scattering Efficiency of 22.7 μm Fly Ash Particle
In the experiment, the density of fly ash was    It can be seen from Figure 6 that when the mass fraction of Fe 2 O 3 was between 5.65% and 16.53%, the change of Q a and Q s was not obvious and they concentrated around 0.9 and 1.1 respectively.Only when the mass fraction of Fe 2 O 3 was reduced to 0.85%, Q a and Q s changed significantly: Q a decreased to 0.3 -0.4,while Q s increased to 1.7 -1.8.
Since Fe 2 O 3 has strong absorption characteristic when the incident wavelength is less than 4 μm [4], k is mainly influenced by the content of Fe 2 O 3 and increases with the increase of Fe 2 O 3 , while the n value remains stable.Thus it is worth analyzing the results in Figure 6 by comparing the change of Q a and Q s under different size parameter x and k values through Mie scattering theory, see Figure 7.
As shown in Figure 7, with the increase of size parameter x, the influence of k value on particle scattering and absorption efficiency gradually decreases; when k grows larger, the values of Q a and Q s coincide.In the experiment, when the mass fraction of Fe 2 O 3 was relatively high, the k value became larger, so the change of Q a and Q s was not obvious as shown in Figure 6.In addition, it is found that with the increase of the size parameter x, the scattering and absorption efficiency of the particles approach a constant respectively.And for materials with larger k value, the size parameter x is smaller when the absorption and scattering efficiency tends to be stable.
In the calculation of heat transfer in RSC, the absorption and scattering efficiency of large size parameter fly ash can be approximately determined as fixed values which are not affected by the variation of Fe 2 O 3 .
in ρ and out ρ represent the internal and external reflectivity respectively which can be calculated by Fresnel equation[19]:

[ 20 ]
. For collimated light, 1 c ε = and diffuse light is indicated by d ε .In order to make sure the accuracy of the four-flux model, the selection of d ε and ζ is particularly important.Since the size distribution of particles can be controlled in experiment, d ε and ζ are calculated under different size para- meter x and k by Mie scattering theory, see Figure 2. As shown in Figure 2, d ε and ζ change little under different k values at the size parameter x < 1.However, at the size parameter 1 < x < 10, there is significant enhancement of forwarding scattering of particles, thus d ε and ζ have sharp changes with different k values.As size parameter x increases larger than 10, d ε and ζ reaches constants respectively, which are 1.05% and 95%.Because the particle sizes in experiments are 22.7 μm and 3.21 μm and the measuring wavelength is 0.55 -1.65 μm, the size parameters are larger than 6.Thus in calculation, d ε and ζ are chosen to be 1

Figure 2 .
Figure 2. Forward scattering ratio and average crossing parameter calculated by Mie theory.
Measurement of the hemispherical-directional reflectance and transmittance spectra of free-standing KBr sample was performed at room temperature, which means the emission of the sample can be neglected.The experiments examined the wavelength range of 0.55 -1.65 μm using Fourier Transform Infrared Spectroscopy (FTIR).The experiment equipment illuminated hemispherical radiation onto sample slab.Then the effective radiation intensity of upper surface ,1 eff I and lower surface ,2 eff I were separately received by two FTIRs, see Figure 3. Since the radiation intensity from the hemispherical radiation source ,source I λ was known, the reflectance R and transmittance T were readily calculated as Z. F. Fu et al.DOI: 10.4236/jpee.2018.6900215 Journal of Power and Energy Engineering

Figure 6 .
Figure 6.Absorption efficiency Q a and scattering efficiency Q s of 22.7 μm fly ash.

Figure 7 .
Figure 7. Direct calculation of absorption efficiency Q a and scattering efficiency Q s by et al. is directly cooled by chilling.The syngas temperature decreases from about 1400˚C to less than 300˚C, which causes huge energy loss.Radiant Syngas Cooler (RSC) is installed at the outlet of gasifier and plays a significant role in recovering this part of energy.The utilization of RSC can increase the power generation efficiency of Integrated Gasification Combined Cycle (IGCC) DOI: 10.4236/jpee.2018.69002 10 Journal of Power and Energy Engineering slurry gasifier