Effects of Electrode Types on the Microstructure , Tensile and Hardness Properties of 304 L Austenitic Stainless Steel Heat-Affected Zone ( HAZ )

Submerged arc welding (SAW) has been well utilised for the production of weld joints in 304 L ASS for various industrial application. However, effective performance of the material in service has been hampered by improper choice of electrode. Therefore, in this study, effects of different types of electrode on the microstructure and tensile property of type 304 L austenitic stainless steel heat-affected zone (HAZ) were studied. Chemical composition of the as-received sample was determined. A number of samples were cut from the as-received sample. Afterwards, two half were joined together with 308 L, 312 L and 316 electrodes at a controlled welding speed, current and voltage of 4.6 mm/s, 160 A and 30 V to produce a constant heat input of 626.09 J/mm. An automatic SAW machine with Model Type: DX3-301, and Frequency: 50 Hz was used. And based on ASTM standard, tensile and hardness samples were prepared from the as-received and HAZs. Tensile and hardness measurements were made. Also, specimens for microscopy studies were prepared from the HAZ and as-received samples. From the results, microstructures of the HAZs revealed varied volume fraction of austenite and ferrite phases and grain sizes, and at austenite and ferrite grain boundaries, chromium carbide formation and precipitation were observed. The weld joint produced with 308 L electrode revealed optimum UTS value and YS value of 475 and 325 respectively. While weld joint produced with 316 L electrode has superior ductility of value 41%. Irrespective of the types of electrode used, the as-received sample revealed superior tensile properties over the weld joints. Also, optimum hardness value of 45.7 HRA was obtained with 308 L. Hardness value of the as-received sample was higher than that of HAZ samples. How to cite this paper: Kutelu, B.J., Adubi, E.G. and Seidu, S.O. (2018) Effects of Electrode Types on the Microstructure, Tensile and Hardness Properties of 304 L Austenitic Stainless Steel Heat-Affected Zone (HAZ). Journal of Minerals and Materials Characterization and Engineering, 6, 531-540. https://doi.org/10.4236/jmmce.2018.65038 Received: November 30, 2017 Accepted: August 28, 2018 Published: August 31, 2018 Copyright © 2018 by authors and Scientific Research Publishing Inc. This work is licensed under the Creative Commons Attribution International License (CC BY 4.0). http://creativecommons.org/licenses/by/4.0/ Open Access


Introduction
The Type 304 L Austenitic Stainless Steel (ASS) has featured prominently in different areas of engineering applications, including metallurgical, mechanical, chemical, automobile and nuclear industries.One major factor for its wide acceptance in these areas is its good welding characteristics [1].Although, different arc welding techniques, which include shielded metal arc welding (SMAW), gas tungsten arc welding (GTAW), submerged arc welding (SAW), and plasma arc welding (PAW) have been used to join the type 304 L ASS [2] [3] and [4].And due to ease of process control, high deposition rate, time savings, reduced cost, excellent surface appearance, invisible arc, lower welder skill requirement, improved repair procedure and increased efficiency and productivity, the SAW process has been widely utilized relative to the other techniques in these various areas of applications for the production of weld joints [5] [6].
The weld joint is comprised of base metal (BM), heat-affected zone (HAZ) and fusion zone (FZ), and in service, performance of the weld joint is determined by the microstructural characteristics of these zones.However, due to differently feature microstructures in the HAZ, resulting from thermal cycles, which correspond to different mechanical properties, the HAZ becomes more critical than BM and FZ.Microstructural characteristics of the weld joint can be influenced by electrode composition [7] [8].In SAW, weld joints are produced by chemical and physical reaction of the weld electrode, the base metal and the flux and the alloying elements coming from them [9].The chemical compositions of the weld electrode can influence strength and toughness of weld metal; during the solidification of weld joint, volume fraction of acicular ferrite and δ-ferrite have been influenced by electrode composition [10].Hence, in this study, 312 L ASS, 308 L ASS and 316 L ASS electrodes were used to produce 304 L butt joint SAW welded samples, with particular emphasis on HAZ; this is with a view to determining the best match for optimum service performance.

Materials
The materials employed for the work included type 304 L austenitic stainless steel plate sheet of 8 mm thickness and welding electrodes with the following specifications: AWS 308 L, AWS E312L and AWS E316 and diameter φ = 2.5 mm.

Spectrometric Analysis of the As-Received Sample
Chemical analysis of the as-received 304 L austenitic stainless steel plate was done by optical emission spectrometry using AR 4 30 metal analyzer and the result is depicted in Table 1.While the composition of the different electrode used such as 308 L, 312 L and 316 L are shown in Tables 2-4 respectively.

Weld Preparation and Design
Samples with length 50 mm, breadth 3.5 mm and thickness 4.5 mm were cut from the plate with hacksaw; the use of hacksaw was informed by the need for avoidance of distortion and thermal damage from thermal cutting [11].To allow for sufficient root penetration single bevel-butt joint design configuration with 60˚ within the edges and root opening (air gaps) of 2.5 mm was adopted Care was taken not to allow the root opening to exceed twice the specified gap [12] [13].Before welding all the edges were thoroughly cleaned in order to avoid any source of contamination like rust, scale, dust, oil, moisture that could creep into the weld metal and later on could result possibly into a weld defect [14] and depicted in Figure 1 is the experimental sample with single V geometry.

Gas Tungsten Arc Welding Process
An automatic SAW machine with Model Type: DX3-301, and Frequency: 50 Hz SAW was used for the welding.Prior welding, edges and area adjoining the samples were cleaned of dust using wire brush.Afterwards, the samples were then positioned with respect to each other, aligned accurately, tacked sparingly and welded using 308 L, 312 L and 316 L, electrodes selection was based on American Society of Mechanical Engineers (ASME) standard, and it was metal

Tensile Samples Preparation and Testing
The preparation of the HAZs tensile samples were done in accordance with ASTM E 8-04.Wire-cut electric discharge machining was used to remove flashing and other surface irregularities from the top and bottom surfaces of the tensile specimens.Cross-sectional area and pre-determined gauge length of the samples were measured, and to ensure that the samples undergo deformation, they were placed in the proper grippers.The test was carried out in x-direction with INSTRON tensile testing machine; load was applied at the rate of 0.5 mm/min.

Samples Preparation for Hardness Testing
Figure 2 is a sample of the SAW weldment.Prior to testing, sides and ends of the samples (base metal and weldment) were properly ground, this is necessary to ensure dimensional accuracy; their surfaces were also ground, to maintain flatness and stability.Hand grinder was used for the grinding.Thereafter, the samples were mounted in bakelite, polished and etched by Vilella's reagent.
Preparation of the samples was in accordance with ASTM E 8-04 standard.Micro-hardness test was carried out on all the weldment samples using Vickers micro hardness tester LECO 700AT with diamond pyramid.Tests were performed on the transverse cross-section of the base metal (BM), heat affected zone

Hardness Sample Preparation and Measurement
Surfaces of the (as-received and HAZ) samples with dimensions 20 mm length, 20 mm breadth and 8 mm thickness (Figure 3) were properly ground to give it flat and stable surface using a hand grinder.Thereafter, hardness measurement was made using Digital Rockwell hardness (H RA ) Tester with 16 inches indenter and 60 gf indenting load with a dwell time of 10 s.Hardness measurements were made in three different locations, and the average value was taken [11].

Metallography
Samples for metallographic examination were prepared from the weldments.In order to make the sample convenient for handling, transverse sections were prepared by mounting on thermosetting material known as Bakelite, their surfaces flattened by filing and grinding using laboratory grinding and polishing machines, a set of emery papers of 100, 240, 320, 600, 800 1000 and 1200 p were used.Grinding was done in order of coarseness of the papers, and as each specimen was change from one emery papers to the other, it was turned through an angle of 90˚ so as to remove the scratches sustained from the previous grinding.
After grinding, the specimens were polished using rotary polishing machine, a polishing cloth was also introduced to give it mirror like surface [8] [11].Thereafter, the specimens were then etched in a solution of 1 ml HCL + 3 ml HNO 3 + 1 ml glycerol and the microstructures examined at a magnification of 400× × using metallurgical microscope.volume fraction of ferrite observed may be due to difference in cooling rates that resulted from heat inputs of the electrodes [15].It is well known that, electrode heat input varies, and can be classified into high and low heat inputs [5].The observed sensitised regions may be chromium carbide precipitates.The precipitates, which may have been formed at high temperature, may be due to the welding heat.Also, the inclusions may have resulted from reaction of oxidation with some elements at the high temperature of welding to form intermetallic compounds, which may include oxide of chromium and nickel, and the precipitates may be accounted for by the present of impurities in the weld metal and contaminants within the welding atmosphere.

Results and Discussion
In SAW, the use of low heat electrode remains one effective approach for reducing welding heat input, and hence improving HAZs mechanical properties [5].For ASS, as the welding heat input decreases, more volume fraction of ferrite is produced, and since ferrite grains are stronger than austenite grains, with more ferrite phase, the mechanical properties of HAZs are improved.Also, with low heat input, the austenite grain size decreases, leading to improvement in HAZ mechanical properties [6].Hence, the improved tensile properties (UTS and YS) of weld joints produced with 308 L, whose values are 475 MPa and 325 MPa respectively, as seen in stress strain curve in Figure 5 may be attributed to low heat input of the electrode relative to the 312 L and 316 L electrodes.Past research findings have shown that the use of low heat input electrodes increases the amount of weld metal deposition, weld penetration depth increases and sharpens weld metal tip shape [15].Hence, enhancing the mechanical properties, and thus the service performance of the weld joints.The same justification for strength may be applicable for the observed relative superior hardness property of the weld joint produced by 308 L with value of as seen in Figure 6.As heat input decreases, smaller grains are produced, which allows for greater interactions between dislocations, the grain size and the available room for their gliding through the lattice is reduced.
Nearness in mechanical properties of the base plate and HAZ is dependent on similarity in their chemical compositions.Hence, for the production of high quality weld joints, chemical composition of the electrode becomes a critical parameter.And this may be contributory to the observed variation in tensile and hardness properties of the HAZs.From the chemical compositions presented in Tables 1-4, it can be seen that unlike electrodes 312 L and 316 L, most alloying elements for the base metal (Table 1) are replicated for 308 L electrode thereby making it more compatible for this application than the other ones.For instance Figure 5. Tensile stress-strain curves of the HAZ samples at a range of electrode types, and as-received sample.effects of Cr and Mo, (as alloying elements in BM and 308 L electrode) on the final HAZ microstructure after solidification promotes hardness by formation of acicular ferrite and fine carbides in the weld [10] [16].The presence of Ti 316 L may have accounted for reduction in ultimate tensile strengths and elongation percentages of the HAZ [17] (Figure 7).Welding low carbon steel with low carbon filler metal and martensitic and semi austenitic precipitation hardening stainless steel with type 630 filler metal have given optimum weld joint performance in different applications; provide the weld joint is devoid of defects including discontinuities, entrained contaminants or porosity [18] [19].Also, the observed variation in mechanical properties may have been informed by differences in electrode extension.It is well known, that the amount of resistant heating which occurring in the electrode is governed by electrode extension, if the electrode extension is short, heating effect will be small and pe-

Conclusions
Based on the results of the findings, the following conclusions were drawn: 1) The microstructures of the 316 L, 312 L and 308 L HAZs are comprised of austenite matrix with varied volume fraction of ferrite.
2) Inclusions, chromium carbide formation (white patches) and precipitates (dark tiny spots) are seen in the HAZs microstructures.
3) Optimum tensile properties (UTS, YS and %E) were obtained with 308 L electrode, and tensile properties of the HAZs samples were found to be relatively lower when compared with the as-received sample.
4) Optimum hardness value was obtained with 308 L as compared to 316 and 312 electrodes respectively.
Hardness value of the as-received sample was high relative to HAZs produced with 308 L, 316 L and 312 L respectively.
maintenance of welding is a very important step for achieving the desired results.The two major factors, which basically control the selection of electrodes, are: 1) Types of base material.2) Service condition.Though there are other factors, which can influence the choice on welding electrodes, the above two factors primarily decide the welding electrodes.The different types of base materials that are normally encountered in any industry are (a) carbon and low alloy steels, (b) stainless steels, (c) austenitic Mn steels and (d) cast iron.A number of investigations on the microstructural and mechanical behavior of SAW welded 304 L ASS have appeared in learned journal; however the desired attention required by the HAZ has not been adequately addressed.

Figure 1 .
Figure 1.Experimental sample with single V configuration.

Figure 2 .
Figure 2. A sample of the SAW weldment.

Figures 4 (Figure 3 .
Figures 4(a)-(c) are HAZs microstructures of SAW weld joints produced with 302 L, 316 L and 308 L respectively.The HAZs microstructures are comprised majorly of austenite matrix with varied volume fraction of ferrite grains, sensitized regions in form of white patches and precipitates in form of dark tiny particles in varied amounts are dispersed within the austenite matrix.The varied

Figure 6 .
Figure 6.Hardness characteristics of as-received sample and HAZs produced with 308 L, 312 L and 316 L electrodes.

Figure 7 .
Figure 7. Elongation behaviour of as-received and the HAZs produced with 308 L, 312 L and 316 L electrodes.
Minerals and Materials Characterization and Engineering netration will be deep, if on the other hand, the extension is increased, heating effects and penetration rate are increased and deposition reduced[8].

Table 1 .
Chemical composition of the as-received 304 L austenitic stainless steel plate.

Table 2 .
Chemical composition of 308 L electrode.

Table 3 .
Chemical composition of 312 L electrode.

Table 4 .
Chemical composition of 316 L electrode.