Petrology of Metaluminous A-Type Rhyolite Discovered from Hadjer el Hamis Volcanoes (Lake Chad Basin)

Metaluminous (P.I. > 1) rhyolite from Hadjer el Hamis consisted of quartz, alkali feldspar, clinopyroxene (hedenbergite), amphibole (F-arfvedsonite) and oxides-hydroxides (ilmenite, magnetite, limonite) phenocrysts is characterized by the negative Eu, Ba, P, Sr and Ti anomalies. This metaluminous rhyolite and the early discovered peralkaline rhyolites in Hadjer el Hamis volcanoes derive likely from the same source, according to their coexistence on the same sector and their similar Zr/Nb ratios. The causes of magma heterogeneity are likely linked to varying amounts of extraction of an earlier melt phase or tectonic juxtaposition or a sudden increasing of fO 2 in silicic magmas, triggered from a hydrothermal process, associated with F- and alka-li-bearing fluids influx, which promoted the enrichment of Na in the hedenbergite rims and the crystallization of arfvedsonite.


Introduction
Metaluminous A-type rocks frequently occur in post-orogenic, extensional settings [1]. The rhyolitic outcrops of Hadjer el Hamis overhang the sedimentary units of the SE Lake Chad [2] (Figure 1). These rhyolites can be related to a tectonomagmatic stage, of the western central Africa rift system, which may constitute the NNE extension of a N50˚E to N30˚E elongated succession of small alkaline complexes, from the Gulf of Guinea to the Lake Chad [3].
The metaluminous A-type rocks were discovered from the Lake Chad basin.
This paper adds to an earlier paper on the petrology of peralkaline rhyolites from the SE Lake Chad [4] which presents a fieldwork, petrographical study, mineralogical and geochemical data of the metaluminous rhyolites from Hadjer el Hamis (Lake Chad basin). Furthermore, we present the relationship between these peralkaline and metaluminous rhyolites.

Geological Background and Fieldwork
The metaluminous rhyolitic rocks, which are the focus of this paper, are mostly welded lavas. At the Late Cretaceous times, tectonic events would have led to the occurrence of the eruptive rocks in southeastern edge of Lake Chad [4]. The volcanic eruptions, which consisted mainly of rhyolites, were probably triggered after the reactivation of Precambrian basement faults [5].
The previous petrological studies of the rhyolites from the SE Lake Chad have mainly been concentrated on peralkaline-type, which are the predominant silicic volcanic rocks; and not to the coexisting aluminous and peralkaline rhyolites.
Nowadays, the coexistence in the same domain of peralkaline and mertaluminous rocks is strongly debated in order to determine their genetic relationship [6].
Metaluminous rhyolites from the SE Lake Chad were sampled on rocky slopes and/or in working quarries at the flanks of Hadjer el Hamis volcanoes. Hadjer el Hamis (418 m a.s.l) are five domes or necks composed of both, dark green and grey rhyolites, showing vertical columnar jointing [4]. The rhyolitic fragments split from the flanks are scattered around the foothills.

Analytical Methods
The petrography of samples was determined by optical microscopy (OM) using an Olympus BX60 binocular microscope at the "Instituto de Geociências, Universidade de Brasília (Brazil)". The superprobe JEOL JXA-8230, Electron Probe Microanalyser of the same University was used for back-scattered electron (BSE) and 20 s for the other selected elements. The diameter of the electron beam was 10 µm. All data were corrected with standard ZAF correction procedures. Natural minerals and synthetic glasses were used as standards.
Whole-rock samples were crushed to fine powder in a "Siebtechnik" mill equipped with two agate jars at the "Instituto de Geociências

Nomenclature and Petrography
The  This groundmass is very finely crystallized. Quartz phenocrysts are euhedral to subhedral, with corrosion gulfs. Euhedral and subhedral feldspar phenocrysts are irregular, colourless to yellow brown, with spongy structure. In the interstices left by these phenocrysts occur microlites of feldspar and Fe-Ti oxides. The dark greenish amphibole phenocrysts are sometimes pseudomorphosed or enclosed with fine-grained Fe-Ti oxides. Apatite microcrysts are included in amphibole. Clinopyroxene phenocrysts are green or brown, with anhedral to subhedral shape, overgrown and partly replaced by Fe-Ti oxides.

Clinopyroxene
The compositions of clinopyroxene (Table 1) fall in the fields of the hedenbergite (Wo 45−46 En 3−3 ). These compositions (Table 1) are similar in peralkaline and metaluminous rhyolites, with relatively high CaO contents (up to 18.8 wt%).

Geochemistry
Major-elements compositions of metaluminous rhyolite from Hadjer el Hamis are more or less similar to those of the peralkaline rhyolites (see Table 5   The total REE concentrations ranging from 359 -387 ppm to 345 ppm, respectively from peralkaline to metaluminous rhyolites. Overall, peralkaline and metaluminous rhyolites from the Lake Chad basin exhibit the similar Zr/Nb ratios (see Table 5), just below 7 (Zr/Nb: 6.5 -6.9).
Primitive mantle-normalized [9] REE (Rare Earth Elements) patterns for all samples are subparallel (Figure 4). The rhyolites from the Lake Chad basin exhibit high enrichment in LREE and display fractionated REE pattern with (La/Yb) N ratios ranging from 9.1 to 10.4.
The REE patterns (Figure 4)  multi-element patterns ( Figure 5) show negative Ba, P, Sr and Ti anomalies.

Petrological Implications
The peralkaline and metaluminous rhyolitic magmas from Lake Chad basin derive likely from the same source, according to their coexistence in the same dome (Hadjer el Hamis) and their similar Zr/Nb ratios. According to the Y vs Nb diagram ( Figure 6), the silicic rocks of the Lake Chad are from within plate domain and likely the product of the intraplate magmatism [2]. The values of K/Rb, Rb/Sr, Rb/Ba and Ga/Al ratios (see Table 5; Figure 6) for the Lake Chad rhyolites are similar to those exhibited for the A-type granite [10]. A-type granites ( [11] [12] [13]) are generated in association with uplift and major strike-slip faulting.
Primary diversity in source rocks, varying amounts of extraction of an earlier melt phase, or tectonic juxtaposition can be suggested as causes of magma heterogeneity [6].   However, other processes such as different degrees of partial melting or removal of successive batches of magma from a suitable source might also produce ranges of subalkaline to peralkaline magmas. Indeed, the trace-element variations of the Lake Chad rhyolites suite, such as subparallel primitive mantle-normalized REE and multi-element patterns, indicate that they are likely the cogenetic products.

Crystallization Process
The occurrence of nearly pure albite and sanidine are regarded as reflecting alkali exchange during sub-solidus hydrothermal reactions or as corresponding to late-stage recrystallization at hydrothermal conditions [4]. Quartz phenocrysts with corrosion gulfs were probably generated during ascent to the surface upon eruption, during decompression of the rhyolitic magmas.

Conclusion
The metaluminous rhyolites from Hadjer el Hamis are characterized by the occurrence of phases such as arfvedsonite, hedenbergite, ilmenite and alkali feldspar consistent with the well-developed negative Ba, P, Sr, Ti and Eu anomalies. The occurrence of nearly pure albite and sanidine is regarded as reflecting alkali exchange during sub-solidus hydrothermal reactions or as corresponding to late-stage recrystallization at hydrothermal conditions. Indeed, the studied metaluminous rhyolites are from within plate domain and likely the product of the intraplate magmatism. According to their coexistence in the same dome with peralkaline rhyolites and their similar Zr/Nb ratios these rocks are from the same source (cogenetic). The heterogeneity of the rhyolitic lavas (metaluminous and peralkaline) from Hadjer el Hamis could be linked to the destabilization of hedenbergite phenocrysts core, breaking down into limonite and ilmenite, which involved a sudden increasing of fO 2 in silicic magmas and promoted the enrichment of Na in the hedenbergite rims; and the crystallization of arfvedsonite and the Na-rich phases such as pure albite. These therefore cause the decreasing of Na 2 O contents in the magma source and the generation of metalu-