Shear-Controlled Gold Mineralization of G . R . Halli Area of Chitradurga Schist Belt , Dharwar Craton : Insights from Fluid Inclusion Study

Gold mineralization at G. R. Halli is located along the Central shear zone of Chitradurga schist belt, extending from west of Gonur, through east of G. R. Halli and C. K. Halli to east of Honnemardi, roughly parallel to stratigraphic units. The NNW-SSE trending shear zone has a width of 0.5 to 1.5 km shows extensive carbonatization of metabasalts and the associated lithologies confined to NNW-WNW trending arcuate brittle-ductile zone. The sheared and silicified contact zones between carbonaceous argillite and schistose metabasalt form the potential sites for localization of mineralization. The gold is associated with sulphides mainly pyrite, arsenopyrite, galena, sphalerite, minor chalcopyrite. Textural relationship indicates two stage sulphide mineral assemblages co-relatable with two stage fluid ascents having temperature of homogenization between 125 ̊C and 256 ̊C. It is a typical epigenetic lode gold system, which got affected by later deformation.

as 4.1 to 10 ppm and 5 to 44 ppm respectively.The work was further carried out by Rajendran [4] and Rajendran and Khan [5].They delineated two parallel to sub-parallel arcuate zones for gold mineralization.The mineralization is mainly shear controlled, epigenetic in nature, and has fluids that circulated at 2.5 km depth at temperature and pressure conditions of 241.27˚C and 0.6 Kb respectively [6].These fluid characteristics of G. R. Halli gold deposit indicate their Archaean lode gold deposit nature.In any Precambrian mineral deposit role of multiple deformation and fluid ascent cannot be ruled out.The study area has also witnessed intense carbonatization, resulting in culmination of primary features and overprinting of later activities.In view of this an attempt has been made in this paper to understand the role of deformation and nature of mineralization fluid through fluid inclusion signatures.

Geological Setting and Mineralization
Chitradurga schist belt (CSB) is an important greenstone belt of Dharwar craton and host number of gold occurrences along three major crustal scale shear zones viz., 1) Chitradurga Eastern Margin Shear Zone (CEMSZ), 2) Chitradurga Central Shear Zone (CCSZ) and 3) Chitradurga Western Margin Shear zone (CWMSZ).G. R. Halli deposit is a part of CCSZ (Figure 1) and exposes rocks belonging to Ingaldhal and Hiriyur Formation composed of schistose metabasalt and argillite-greywacke suite of rocks, intruded by irregular carbonated metabasic dykes and minor incidence of ferro-dolomite and lenses of quartz-goethite breccia (Figures 2-5        are further classified depending on proximal to distal alteration by [9].The gold mineralization occurs in the form of disseminations, stringers and fracture filling sulphides mainly pyrite, arsenopyrite, galena, sphalerite, minor chalcopyrite and rare stibnite associated with quartz-carbonate veins.Titano-magnetite is the main oxide facies minerals in the ore zones.Based on textural relationship between the sulphide minerals during the ore petrographic studies two-stage evo-lution is envisaged, where chalcopyrite, sphalerite and pyrrhotite association showing mutual boundary and exsolution textures define the first stage followed by arsenopyrite, pyrite, galena replacing the early sulphides (Figure 9).

Fluid Inclusion Study
Quartz veins samples traversing the metabasalt were selected for fluid inclusion study.These veins are invariably associated with mineralization.Quartz veins traversing the metabasalts vary from approximately 3 to 20 cm.Mixed trails of aqueous-carbonic rich, bi-phase and carbonic monophase inclusions are observed predominantly within the undeformed quartz grains.These inclusions are of smaller size and show less equilibrated shapes in comparison to the primary fluid inclusions.
The shapes of the aqueous rich inclusions show a greater degree of equilibration than the corresponding monophase inclusions within single trails.A generalized picture of the disposition of the fluid inclusions is given.Both primary and secondary fluid inclusions were studied in order to understand the nature of fluids and role of subsequent deformation.

Carbonic Monophase Inclusion
Carbonic inclusions are filled with near pure liquid CO 2 .These mono-phase carbonic (CO 2 ) fluid inclusions are dark in colour.They are rounded and anhedral in nature.The size of these inclusions varies from 0.6 to 10 µm.Carbonic fluid inclusions are less abundant than aqueous carbonic inclusions in these samples.The melting temperature of CO 2 ranges from −56.7˚C to −59.1˚C indicating that the fluid is dominated by CO 2 only.The homogenization temperatures of CO 2 range from 5.7˚C to 22.1˚C.The density of the CO 2 varies from 0.75 to 0.89 g/cm 3 .

Biphase (H2O + CO2) Inclusions
These bi-phase H 2 O + CO 2 inclusions are the earliest inclusions and are primary with respect to the quartz formation.The fluid inclusion data recorded are presented in the Table 1.These inclusions are of various shapes from negative crystals to irregular and oval shape.In many cases, the H 2 O-CO 2 inclusions are coexisting with monophase CO 2 inclusions.At places they exhibit necking and stretching probably indicating they have been affected by deformation (Figure 10).Co-existing vapor rich and liquid rich fluid inclusions are present indicating boiling condition of mineralizing environment (Figure 11).
The melting temperature of CO 2 ranges from −56.6˚C to −59.2˚C.The range of homogenization temperature varies from 125˚C to 256˚C (Figure 12), which corresponds to a salinity range of 1.97 to 11.93 wt.% NaCl equivalent (Figure 13) as calculated using Linksys software (version 1.8) following the equations [10] [11] and [12].Major component in aqueous phase is NaCl ± KCl in the fluid system.Depreciation in Tm CO 2 indicates the presence of minor amount CH 4      in the CO 2 bearing inclusions [13].The CO 2 density varies from 0.86 to 0.99 gms/cm 3 .Pressure calculated from the Isochores of CO 2 indicates a change in fluid pressure between 1200 and 2000 bars (Figure 14).

Discussion and Conclusions
Shear systems in Chitradurga schist belt have a distinct role as many of the known gold occurrences are situated along the three major shear zones viz., CEMSZ, CCSZ and CWMSZ.Litho units show evidences of shearing with overprinting carbonatization, sericitization and sericitization are seen in all the mineralized zones.Some of the earlier workers have opined two general associations of gold mineralization in CSB i.e., vein associated deposits mainly in metavolcanic rocks and stratiform-strata bound deposits in banded iron formation or Fe-rich cherts.In both the cases there is a distinct role of shear zone, which served as important conduits for the transfer of fluids and melts in the lithosphere.The occurrence of gold associated with vein systems and the localisation of the veins within faults/shear zones in G. R. halli area strongly suggest that structurally-focussed fluid flow was fundamental to the formation of this deposit.
Recently, based upon carbon and oxygen isotope data of carbonates from auriferous quartz carbonate veins magmatic/mantle source is proposed for the G.
R. Halli gold deposits [14].[9] indicated two events of hydrothermal activity by correlating the core and rim of the tourmaline with 1) the regional D 1 deformational event associated with the emplacement of the adjoining ca.2.61 Ga Chitradurga granite and 2) juvenile magmatic accretion (2.56 to 2.50 Ga) associated with gold mineralization respectively.The two-event theory of [9] is clear-cut evidence that, the G. R. Halli area has been affected by multiple deformation and fluid ascent.This is further supported by present work on ore petrography with two distinct sulphide assemblages, i.e. early chalcopyrite, sphalerite and pyrrhotite association and later arsenopyrite, pyrite and galena association.
Fluid inclusion characteristics are also supportive of this where T h vs Salinity diagram clearly suggests that the second event has affected the early fluids resulting in re-equilibration (Figure 15).This is also supported by the clustering of two T h and the later is related to deformation in this case shearing.These fluid characteristics and co-relatable sulphide phases suggest that, there are two distinct fluid systems operated in the area where the early fluids having low saline   host lithologies, the common manifestations include metamorphic retrogression and carbonatization.
).The area exhibits easterly younging succession with metabasalt of Ingaldhal Formation in the west and metasediments of Hiriyur Formation in the east.Metabasalts the dominant litho unit in the area and are fine grained, massive to schistose in nature, relatively more altered.Relict intergranular texture is defined by altered laths of plagioclase showing v-junction development and chloritized pyroxene filling intergranular spaces.Very fine dissemination of magnetite, pyrite, pyrrhotite and chalcopyrite are noticed in metabasalt.Intense carbonatization of metabasalt has resulted in development of layering or banding in these rocks.Tension gashes are profusely developed in the area indicating role of shearing.Quartz-carbonate-sulphide veins are also seen traversing these litho units.Meta-argillites are very fine grained, dark grey laminated, carbonaceous rock.It shows alternating siliceous and carbonaceous layers.The siliceous layer is characterized mainly by presence of sericite with minor chlorite and quartz.The felsic volcanic is noticed in the northern and north eastern part of G. R. Halli village showing creamish grey colour, very fine grained, thinly foliated, friable and at places with variegated colour rock.The pervasive deformation fabrics (S 1 and sub-parallel S 2 cleavages, trending NNW-SSE to NW-SE with sub-vertical dips) and mineral re-crystallization events (under greenschist facies conditions) are related to the late D1 and early D2 events.The latter D2 event also facilitated extensive granite plutonism in the regions around Chitraduraga, Jampannanaikanakote and Honnemaradi areas.
mesothermal system were affected by later low temperature low to moderate saline fluid regime.Remobilization of gold and association of Ag with the second event cannot be ruled out with the given fluid system.Overall the G. R. Halli gold deposit is a typical epigenetic lode gold system, which got affected by later deformation.Epigenetic mineralisation is structurally controlled and normally sited in shear zones/fault, contact of contrasting lithologies and fold hinges.Alteration due to hydrothermal fluid interaction is characteristic of epigenetic type of mineralisation.Though alteration characteristics differ depending upon the G. Gopalakrishna et al.DOI: 10.4236/ojg.2018.87039671 Open Journal of Geology

Figure 14 .
Figure 14.The isochors of carbonic inclusions is approximated by a CO 2 system, revealing there was change in fluid pressures from 1200 to 2000 bars.

Figure 15 .
Figure 15.Salinity vs temperature of homogenization (T h ) of samples from G. R. Halli area shows re-equilibration of early fluids later event.

Table 1 .
Fluid inclusion characteristics of H 2 O-CO 2 inclusions from the G. R. Halli area.