The Study of the Preparation of Catalysts for Carbonyl Sulfide Hydrolysis under Moderate Temperature

Multifunctional composite catalyst for carbonyl sulfide hydrolysis under moderate temperature was prepared by impregnation method. The hydrolysis and deoxidization ability of the prepared catalyst was investigated in a fixed bed reactor. It was found that deoxidization ability of the prepared catalyst was raised by the increase of the content of potassium loading catalyst and reaction temperature. And the concentration of H2S had no effect on deoxidization while COS improved the deoxidization ratio. And deoxidization rates were nearly scaled up with concentration of H2. The hydrolysis ability was decreased by the decrease of the surface basicity.


Introduction
In the process of coal coking, through a series of complex physical and chemical reactions, coal was generated into the coke oven gas eventually.Coke oven gas contains a lot of sulfide, hydrogen chloride, hydrogen fluoride and other gases, and trace amount of these compounds can result in the deactivation of the following catalysts and lead to corrosion of the following reaction equipment [1]- [6].The amount of sulfur in the gas must be decreased to a standardized scope.So the sulfide in coke oven gas must be removed before used.Coke oven gas contains not only hydrogen sulfide (H 2 S) but also other sulfurous gases including carbonyl sulfide (COS).In comparison to H 2 S, COS is more difficult to remove due to its low reactivity in many desulfurizers.Therefore, the formation Journal of Materials Science and Chemical Engineering of COS in coke oven gas will reduce the coke oven gas desulfurization efficiency.
Many studies of COS removal by sorption, catalytic hydrolysis and hydrogenation conversion have been reported in order to overcome this limitation [7] [8] [9] [10].An alternative technology has been used for the removal of COS, and this is based on the formation of H 2 S by hydrolysis: COS + H 2 O = H 2 S + CO 2 .
Liu et al. [11] studied the heterogeneous reaction of COS on metal oxides.The results showed that the activity series for heterogeneous hydrolysis of COS decreased in the following sequence: The specific surface area and surface basicity of these oxides have great effect on the catalytic activity.Shangguan et al. [12] prepared the catalyst containing Al 2 O 3 and K 2 CO 3 at low temperature and an improved desulfurization performance was reported.Loading K 2 CO 3 can increase the basicity of catalyst, which increases the COS hydrolysis ability.However, some desulfurization process must be carried out under intermediate temperatures, and in this temperature, Al 2 O 3 is easy to be sulfated which will decrease the catalytic activity.
Liujun et al. [13] thought reduce catalytic activity was due to oxygen existed in gas.The oxygen can make H 2 S transform into SO 42 -on the surface of catalyst and this reaction can sulfate the Al 2 O 3 , thereby decreasing the basicity of catalysts.
To overcome the pernicious effect of Al 2 O 3 that oxygen brings in, something that can remove oxygen must be introduced into catalyzer.Hydrodeoxygenation has been reported as a feasible way to remove the oxygen.Hydrodeoxygenation refers to the reaction of O 2 and H 2 generate into H 2 O to remove oxygen under the influence of deoxidizers.Cu-based deoxidizer has been widely used, but it has low deoxidization accuracy and oxygen capacity.Pd-based deoxidizer has wide operating temperature range and high deoxidization accuracy, but it is expensive and needs strict impurity in the raw material gas.Mn-based deoxidizer cannot be used in sulfur-containing atmosphere while coke oven gas contains a lot of sulfur.Ni-based deoxidizer has very high hydrodeoxygenation catalytic activity, however Ni can react with CO and coke oven gas has some CO.Mo-based deoxidizer has high hydrodeoxygenation catalytic activity, and it still work even in high temperature.In sulfur-containing atmosphere, Mo can generate MoS 2 which has better hydrodeoxygenation catalytic activity, so Mo-based deoxidizer can add into middle temperature hydrolysis catalysts to avoid oxygen poisoning.
By considering the deoxidization ability of middle temperature COS hydrolysis catalysts added MoO 3 and the change law of the deoxidization ability in different reaction conditions, some researches were investigated in this paper.

Preparation and Pre-Sulfidation of Catalysts
The COS hydrolysis catalysts doped with MoO 3 were prepared using impregnation method.Different mass ration of (NH 4 )6Mo 7 O 24 •6H 2 O and K 2 CO 3 were dissolved in some distilled water that accorded with the water absorption of

Pre-Sulfidation
Catalyst was heated to 200˚C in a N 2 atmosphere, and then H 2 and H 2 S was inlet.

Hydrodeoxygenation Tests
Hydrodeoxygenation tests were performed in a fixed-bed micro-reactor.The experimental apparatus consists of gas inlet unit, reaction unit and detecting unit.Gases were controlled by rotameter and then introduced into a vertically quartz tube that was placed in a tube furnace.The inner diameter of the reaction quartz tube was 15 mm. 10 ml of sample was packed in the tube to a height of about 4.5 cm, and then heated to the reaction temperature in a mixed gas flow.
The mixed gas contains H 2 , N 2 , O 2 and H 2 S or COS.The reaction temperature was range from 200˚C to 300˚C.

Determination of the Deoxidization Ability
The concentration of O 2 in inlet and outlet were determined through CG7900.
The changes in the concentration of O 2 in inlet and outlet indicate the deoxidization ability of the catalysts.

The Pre-Sulfidation of Catalysts
At the time of preparing catalysts, Mo was the form of ionic state in the impregnating solution firstly, then transformed into oxidation state when the catalysts were roasting and activating.However, only if molybdenum oxides were transformed into MoS 2 can catalysts get more deoxidization ability.The reaction that occurs during the pre-sulfidation process is MoO When the H 2 S was at a low concentration, the time of pre-sulfidation would be grown.This will take more time for pre-sulfidation process in practical application.When the temperature of pre-sulfidation was too high, H 2 would transform Mo oxides into Mo simple substance which could make the active component of hydrodeoxygenation loss.So, the concentration of H 2 S in sulfidation gas was 2000 -2500 mgS/m 3 and the temperature was 200˚C.

The Pre-Experiment of Catalysts Hydrodeoxygenation
The change of the ratio of deoxidization for catalyst without Mo was shown in Figure 1 with the increase of time.As shown in Figure 1, the deoxidization ratio of the catalysts without Mo was nearly zero, and it could be proved that the catalysts without Mo did not have the ability of deoxidization and the oxidation of H 2 S could not have effect on the determination of deoxidization ratio.

The Effect of the Molybdenum Content on the Hydrolysis Ability of the Catalysts
The change of the COS hydrolysis conversion for the catalysts was shown in

The Effect of Temperature and the Potassium Content on the Deoxidization Ability of the Catalysts
Influences of temperature and the content of potassium on the ratio of deoxidization of catalyst were shown in Table 1.
As shown in the Table 1, it can be concluded that the deoxidization ability raised with the increase of reaction temperature and the potassium content.
From the thermodynamics, the hydrodeoxygenation reaction is an exothermic  process, so deoxidization ability should be decreased with the increase of the reaction temperature.However, the actual deoxidization ratio showed the opposite tendency, this may be because that the hydrodeoxygenation reaction is away from the chemical equilibrium, catalyst improves the chemical reaction rate and the reaction rate increase with the temperature raising.As for potassium content, the H + in surface hydroxyl was replaced by K + with the potassium added in which could reduce the phase change of Al 2 O 3 and accelerate electron transfer of activated oxygen and activated hydrogen.And K + not only could prompt Mo 4+ into stable Mo 5+ but also was the active center of oxidation-reduction reaction.

The Effect of Sulfur-Containing Atmosphere the Deoxidization Ability of the Catalysts
The change of the ratio of deoxidization for catalyst in different sulfur containing atmosphere was shown in Figure 3 with the increase of time.As shown in

The Effect of the Concentration of H2 on the Deoxidization Ability of the Catalysts
The change of the ratio of deoxidization for catalyst in different concentration of H 2 was shown in Figure 4 with the increase of time.As shown in Figure 4, the ratio of deoxidization of catalyst were raised with the increase of the concentration of H 2 .The ratio of deoxidization were nearly scaled up with concentration Y. K. Xu et al.
of H 2 , so it can be concluded that the controlling process of hydrodeoxygenation reaction was connected with H 2 and that process might be a second order reaction.

Conclusion
At the process of catalyst deoxidization, the potassium can improve the deoxidization ability of the catalysts, and the improvement raised with the increase of potassium contents while at the process of hydrolysis the surface basicity decrease make the hydrolysis ability decrease.Catalyst improves the deoxidization rate and the deoxidization rate increase with the temperature raising.In the H 2 S containing atmosphere the ratio of deoxidization did not change with the change of the concentration of H 2 S, however in the COS atmosphere the ratio of deoxidization raised a lot.The ratio of deoxidization scaled up with the increased of the concentration of H 2 and that may be a second order reaction.

Y
. K. Xu et al.Journal of Materials Science and Chemical Engineering supports.Then the corresponding mass of Al 2 O 3 supports was added into the above solution.The mixture was maintained for 12 h at room temperature.Then put the mixture into the dying oven for 4 h at 120˚C.Finally put them into muffle furnace for calcination activation at 550˚C for 5 h.

Figure 1 .
Figure 1.The change of the ratio of deoxidization for catalysts without Mo with the time increasing.

Figure 2
Figure2with the increase of time.As shown in Figure2, A referred to the catalyst without Mo doped, and B referred to the catalyst with 10 wt.% Mo doped, and C was the catalyst that doped with 10 wt.% Mo after pre-sulfurized.The temperature of reactions were 300˚C, and the concentration of H 2 was 20%.The hydrolysis ability of the catalyst was decreased with the Mo doped in and this phenomenon was more significant when the catalyst was pre-sulfurized.Because the COS hydrolysis reaction was a base-catalysis, while the Mo doped in made the surface basicity decrease and decreased the hydrolysis ability eventually.And the pre-sulfidation made the surface basicity decrease further.It might be that after the pre-sulfidation the S 2 -occupied lots of surface space and made the COS difficult to combine with surface basic sites.Though the hydrolysis ability decreased with addition of Mo, it can make the catalyst have the ability of deoxidization to avoid the pernicious effect of Al 2 O 3 that oxygen brought in.

Figure 2 .
Figure 2. The change of the COS hydrolysis conversion ratio for catalysts in different forms of Mo-based with the time increasing.

Figure 3 ,Figure 3 .
Figure3, the 80, 200, 700, 1100 referred to the concentration of H 2 S, and that were 80 mgS/m 3 , 200 mgS/m 3 , 700 mgS/m3, 1100 mgS/m 3 .And the concentration of COS was 700 mgS/m 3 .The temperature of reactions were 300˚C, and the concentration of H 2 was 20%.The ratio of deoxidization did not significantly changed with the increased of the concentration of H 2 S, however in COS

Figure 4 . 2 O
Figure 4.The ratio of deoxidization of catalysts in different concentration of H 2 .

Table 1 .
Influences of different Temperature and different potassium content on the ratio of deoxidization of catalyst.
Content of potassium (%)Ratio of deoxidization in different temperature (%)