Bound State Solutions of the Schrödinger Equation for the More General Exponential Screened Coulomb Potential Plus Yukawa ( MGESCY ) Potential Using Nikiforov-Uvarov Method

The solutions of the Schrödinger with more general exponential screened coulomb (MGESC), Yukawa potential (YP) and the sum of the mixed potential (MGESCY) have been presented using the Parametric Nikiforov-Uvarov Method (pNUM). The bound state energy eigenvalues and the corresponding un-normalized eigenfunctions expressed in terms of hypergeometric functions were obtained. Some derived equations were used to calculate numerical values for MGESC, YP, and MGESCY potentials for diatomic molecules with different screening parameters (α) for l = 0 and l = 1 state with V0 = 2.75 MeV and V1 = 2.075 MeV. We observed an increase in l value; the particles behave more repulsive than attractive. The numerical values for different l-states at different screening parameters for CO molecules (r = 1.21282) and NO molecule (r = 1.1508) were obtained using the bound state energy eigenvalue of the Schrodinger equation for MGESC, YP and MGESCY potentials. Potential variation with intermolecular distance (r) for some of the particles moving under the influence of MGESC, Yukawa and the mixed potential (MGESCY) were also studied. We also observed the variation of the MGESC potential How to cite this paper: Ita, B.I., Louis, H., Akakuru, O.U., Magu, T.O., Joseph, I., Tchoua, P., Amos, P.I., Effiong, I. and Nzeata, N.A. (2018) Bound State Solutions of the Schrödinger Equation for the More General Exponential Screened Coulomb Potential Plus Yukawa (MGESCY) Potential using Nikiforov-Uvarov Method. Journal of Quantum Information Science, 8, 24-45. https://doi.org/10.4236/jqis.2018.81003 Received: February 2, 2018 Accepted: March 27, 2018 Published: March 30, 2018 Copyright © 2018 by authors and Scientific Research Publishing Inc. This work is licensed under the Creative Commons Attribution International License (CC BY 4.0). http://creativecommons.org/licenses/by/4.0/ Open Access


Introduction
The more general exponential screened coulomb (MGESC) potential expressed as is a potential of great interest which on expansion comprises of the sum of coulomb potential, modified screened coulomb or the Yukawa potential and a modified exponential potential given as ( ) This potential is known to describe adequately the effective potential of a many-body system of a variety of fields such as the atomic, solid state, plasma and quantum field theory [1].The problem arising from screened coulomb potential is of indubitable importance in physics and chemistry of atomic incidence.
To tackle this problem, various methods have been applied both numerically and analytically to obtain the energy spectrum of the particle under investigation.
This method includes the WKB method [2], and various types of perturbation method [3] [4] [5].The expansion of the MGESC Potential in Equation ( 1) gives ( ) ( ) The coefficient i V of Equation (3) can be obtained so that the perturbation method of [5] may be applied.Recently, a novel perturbative formalism which is based on decomposing the radial part of the Schrodinger equation into two having an Exact solvable part and approximate treatment depending on the nature of the perturbed potential [1] have been applied on the MGESC potential and bound state energies as well as wave functions to both bound and continuum region have been obtained.Hence, the Schrodinger equation for the MGESC Po-tential doesn't admit exact solution.For this reason, Sever and Tezcan [6] applied the large-N expansion following the method proposed by Mlodinow and Shatz [7] to obtain the energy eigenvalues for the ground state and the first excited state as well as their corresponding wavefunctions.Roy in 2013 [8] carried out extensive studies on some exponential screened coulomb potentials such as the Exponential Cosine Screened Coulomb (ECSC) and General Exponential Screened Coulomb (GESC) potential with special emphasis on higher states and stronger interactions.In his speculative studies, he obtained bound state solutions for both screened potentials via the Generalized Pseudospectral (GPS) method and computed reasonable results for the energy eigenvalues at different states compared with other results obtained in the literatures.Ita and Ekuri [9], carried out studies on the MGESC potential for diatomic molecules to obtain boundstate solutions of the Schrodinger equation using the Nikiforov-Uvarov (NU) Method.The Yukawa potential, in atomics and particle physics expressed in the form ( ) where g is the magnitude scaling constant, m is the mass of the affected particle, r is the radial distance to the particles, k is another scaling constant which was first proposed by Hideki Yukawa in 1935on the paper titled "On the interaction of Elementary Particles" a work in which, he explained the effect of heavy nuclei interaction on pions.According to Yukawa, the interactions of particles is not always accompanied by emission of light particles when heavy particles are transmitted from neutron state to proton state, but the liberated energy due to the transmission is taken up sometimes by another heavy particles, which will be transformed from proton state into neutron state [10].The Yukawa potential is a potential that decreases more rapidly with distance and can be expressed as the coulomb potential when 0 m → .Since then, numerous researches have been conducted by various scientists to obtain bound state of the potential by applying different scientific Methods.Gerry and Lamb in 1984 [11] studied the screened coulomb potential of the Yukawa type by using a scaling variational method based on the SO(2,1) Subgroup of the full SO(4.2) dynamic group of the point coulombic problem to obtain both energy eigenvalues for different states and Normalized wave functions.Gerry and Lamb, 1984 [11] applied the large-N phase Integral approximation based on the coherent states of SO (2, 1) (SU (1, 1)) to coulomb-like problems where they obtained energy eigenvalue for s-states of the Yukawa potential.Hamzavi and co-workers in 2012 [12] studied the Yukawa potential via a two body semi-relativistic (Spinless Salpeter) SS equation and obtained bound state energy values and their corresponding Normalized wavefunctions for short range Yukawa potential with arbitrary l-state using parametric NU Method.In their literature, it was spelt out that the known Static Screened Coulomb Potential (SSCP) yields reasonable results only for the innermost state when Z is Large while it gives a rather poor result for the outermost and middle atomic states.Dutt et al., in 1984 [13], carried out studies on a Journal of Quantum Information Science screened coulomb potential by using a Rayleigh-Schrodinger Perturbation theory and obtained energy eigen values for large values of screening parameters.Their calculations to the energy eigenvalue yielded reasonable result compared to other numerical and analytical methods.Hamzavi and his colleagues in 2012 [14], applied the NU Method to the Yukawa potential for any l-state and obtained bound state approximate analytical solutions.Computed values for the bound state energy for different states were obtained and compared with the (Asymptotic Iteration Method) AIM, Supersymmetric (SUSY) and Numerical method as stated in their literature.Gerry and Lamb [15] obtained the energy eigenvalues for the Yukawa potential by using the Generalized Scaling Variational method for a system with a spherically symmetric columbic potential at the origin.The energy eigenvalues for different states and different screening parameters for bound states were obtained and these values were in agreement with those obtained in the literature Dutt and Varshni [13] studied the energy levels of neutral atoms by applying the shifted large-N expansion to the Yukawa potential with a modified screening parameter.They obtained energy values for the k-shell over the range of atomic number Z up to 84 and compared with those obtained within the framework of hyper-viral-pad scheme they observed that the large-N techniques may also be applied in other areas of atomic physics.Sharma et al. [16] calculated bound state for all angular momenta for superposed two static screened coulomb potentials (SSCP) expressed as ( ) ( ) where 1 g and 2 g are coupling constants, α is the screening parameter and γ is the screening strength.By subjecting 1 0 g = , the modified screened coulomb potential as well as its numerical calculations for the bound state is obtained.
Pakdel et al. [17] studied the Dirac equation with scalar and vector potential for the Yukawa potential and obtained both bound and scattering states.In their calculations, the energy eigenvalues for different values of n and k were reported numerically as well as their corresponding eigenstates.Since the screened coulomb potential plays significant role in microscopic fields, this potential has been applied in different branches of atomic and molecular physics and chemistry.
For this reason, Roy [18] carried out studies on the critical parameters and spherical confinement of H atom in screened Coulomb potential using the GPS method.He extended his studies towards finding bound state energy eigenvalues for the screened coulomb potential ( ) ( ) and their corresponding wavefunctions as well as providing information regarding sample dipole polarizability.Onate and Ojunubah [19] applied the supersymmetric shape invariance approach and formalism on a class of YP expressed as Journal of Quantum Information Science From their calculations, they deduced three different potentials such as the Manning-Rosen, Yukawa and inversely quadratic Yukawa potential and obtained bound state energy eigenvalues as well as wave functions for different principal quantum number n for the s-state.In view of the relativistic quantum mechanics, a particle moving in a potential field is described particularly with the Klein-Gordon (KG) equation.Over the years numerous works have been reported concerning the Klein-Gordon equations for various kinds of potentials by using different Methods such as supersymmetry [21], supersymmetric WKB approach [22], Nikiforov-Uvarov Method [23]- [30].Ikhdair [31] obtained approximate analytical bound state solution of the Klein-Gordon equation with equal Scalar and Vector Eckart type potential given as via the NU Method.Both energy equation as well as the un-normalized wave functions expressed in terms of the Jacobi polynomial were obtained.Ikot et al. [32] obtained approximate analytic solutions of the Klein-Gordon in D-dimension for any l-state for a seven parameter type potential expressed as e e e e e e r r r r r r where A,B,C,F and G are potential parameters, q is the deformation parameter, as well as the wavefunction.Since then many literatures have reported different special case of potential such as, Poschl-Teller potential [34], Rosen-Morse [16] and many more by applying different methods.Moreover when arbitrary angular momentum quantum number l is present, one can only solve the SE and KGE approximately using suitable approximation scheme [35].Some of such approximations include convectional approximation scheme proposed by Greene and Aldrich [36], improved approximation scheme [37], an elegant approximation scheme [38].These approximations are used to deal with the cen-

Theoretical Approach
The Nikiforov-Uvarov method is based on the solutions to a second-order linear differential equation with special orthogonal function [23].The hyper-geometric type has been used to solve the Schrödinger, Klein-Gordon and Dirac equation for different kind of potentials [25]- [30].

The More Generalized Form of Nikiforov-Uvarov Method
Given a second order differential equation of the form In order to find the exact solutions to Equation (11), we set the wavefunction as ( ) ( ) ( ) where the wave function ( ) where ( ) s π is at most first order polynomials.
Likewise, the hypergeometric type function ( ) s φ in Equation ( 13) for a fixed n is given by the Rodriques relation as where n B is the normalization constant and the weight function ( ) In order to accomplish the condition imposed on the weight function ( ) s ρ , it is necessary that the classical or polynomials ( ) s τ be equal to zero to some point of an interval ( ) , a b and its derivative at this interval at ( ) 0 s σ > will be negative, that is ( ) Therefore, the function ( ) and the parameters λ required for the NU method are defined as follows: ( ) ( ) The s-values in Equation ( 19) are possible to evaluate if the expression under the square root be square of polynomials.This is possible, if and only if its discriminant is zero.With this, the new eigenvalues equation becomes On comparing Equation (20) and Equation ( 21), we can obtain the energy eigenvalues.

Parametric Nikiforov-Uvarov Method
The parametric form is simply using parameters to obtain explicitly energy eigenvalues and it is still based on the solutions of a generalized second order linear differential equation with special orthogonal functions.The hypergeometric NU method has shown high utility in calculating the exact energy levels of all bound states for some solvable quantum systems.
Given a second order differential equation of the form where ( ) given by the generalized hypergeometric-type equation Thus Equation ( 22) can be solved by comparing it with Equation ( 23) and the following polynomials are obtained The parameters obtainable from Equation ( 23) serve as important tools to finding the energy eigenvalue and eigenfunctions.Now substituting Equation (24) into Equation ( 19): ( ) ( ) ( ) where The resulting value of k in Equation ( 25) is obtained from the condition that the function under the square root is square of a polynomials and it yields, ( ) The new ( ) for the k − value, ( ) Using Equation ( 17), we obtain ( ) ( ) ( ) The physical condition for the bound state solution is 0 τ ′ < and thus ( ) ( ) with the aid of Equations ( 20) and ( 21), we obtain the energy equation as ) ( ) 2) The weight function ρ(s) is obtained from Equation ( 16) as ( ) ( ) and together with Equation ( 15), we have ( ) ( ) where 1, 1 where n N is the normalization constant.Given the radial Schrodinger equation as [26] ( ) ( ) ( ) ( )

Bound State Solutions of Schrodinger Equation
( ) and ( ) V r is the potential energy function given as where 0 V is the potential depth of the MGESC potential and α is an adjustable positive parameter and takes any value between zero and infinity Substituting the effective potential of Equation (41) into radial Schrodinger equation of Equation (39), we obtain Introducing the following dimensional parameters, ( )  Substituting the polynomial of Equation (47) into Equation ( 28), the following is obtained The discriminant of the expression under the square root in Equation (49) has to be zero for it to have equal roots.Therefore, we obtain On solving Equation (50), the following is obtained for ( ) ( ) where ( ) Substituting k ± into Equation (49), gives the following four possible solutions obtained for π(r) as From the four possible forms of π(r) in Equation (34), we select the one for which the function τ(s) in Equation ( 19) has a negative derivative.τ(s) satisfies these requirements with: Hence the new ( ) r π for which k − becomes ( ) ( ) From Equation ( 20), ( ) ( ) and also from Equation ( 21), ( ) ( ) solving Equation (57) and Equation ( 58) explicitly, we obtain ( ) Substituting the values of 2 , β ε and γ of Equation ( 45) into Equation ( 59) yield ( ) where ( ) ( ) Then the wave functions for the MGESC potential is expressed below as ( ) Substituting Equation (65) into Equation (64), we obtain ( ) ( ) ( ) is the normalization constant.

Solutions to the Radial Part of the Schrodinger Equation with the Yukawa Potential
Given the radial Schrodinger equation as where ( ) V r is the effective potential energy function given as 1 V s the potential depth of the YP and α is an adjustable positive parameter.
Inserting Equation (68) into Equation (67), we obtain Equation ( 69) cannot be solved exactly for 0 l ≠ hence to overcome this bar- rier, we introduce an approximation of the pekeris type for the centrifugal [24] [25] [26] [27] term as Again, applying the transformation e r s α − = to get the form that NU method is applicable, Equation (67) gives a generalized hypergeometric-type equation as Comparing Equation (71) with Equations ( 32), ( 26), ( 35) and (37) yields the following parameters Now using Equations ( 32), ( 72) and (73) we obtain the energy eigen spectrum of the YP as ( ) Equation ( 74) can be solved explicitly and the energy eigen spectrum of YP becomes ( ) ( ) We now calculate the radial wave function of the YP as follows: Using Equation (73), the weight function ( ) of Equation ( 33) is given as we obtained both bound state solution as well as un-normalized wave function of the Schrodinger equation after solving Equation (82) explicitly by applying the NU method as ( ) And the radial wave function expressed as substituting Equation (85) into Equation (84), we obtain ( ) ( ) ( ) where , n l N is the normalization constant.

Numerical Analysis
The aim of this report is to obtain both bound state and their corresponding eigenfunctions of the Schrodinger for the Mixed Potential (MGESCY) potential.
To fulfil this aim, we now use some of the previously derived equations to calculate numerical values for the MGESC potential, Yukawa potential and also the sum of both potential known as the MGESCY potential for diatomic molecules with different screening parameters α for 0 l = and 1 l = state using python program.

Potential Variation
We start by giving an overview of the differences in the effective potential plots against internuclear distance of some particles moving under the influence of the  4 and Figure 5.We have set l = 0, excluding the angular momentum quantum number in Figure 1 and Figure 4 for the MGESC potential and Yukawa potential respectively, at α = 0.01, α = 0.03, α = 2 and α = 5.Also, we chose l = 1 in Figure 2 and Figure 5, and l = 2 in Figure 3

Discussions
The variation of the MGESC potential with the radial distance of separation between the interacting particles (r) for different screening parameters (α) with   Comparing the energy plots of the Yukawa and the MGESC potential for both CO and NO molecules, one can see that as n→∞, the energy obtained E→0, which describes exothermal behaviour (supporting information).For the mixed potentials where 0 5 MeV V = and 1 10 MeV V = , the energy expression in Table 5 shows that both diatomic molecules possesses similar behaviour.

Conclusion
The analytical solutions of both Schrodinger for the more general exponential screened coulomb plus Yukawa (MGESCY) potential have been presented via the NU method.The Nikiforov-Uvarov (NU) method employed in the solutions enables us to explore an effective way of obtaining the energy eigenvalues and their corresponding eigenfunctions of the Schrödinger equations for any l-state.Finally, we calculate the energies and also obtained graphs of the MGESC potential, Yukawa potential and the mixed potential for diatomic molecules by means of Equations ( 60) and (83), for the l-states at different values of the screened pa- state energy eigenvalue calculations.They deduced three different energy representations for the following potentials namely the coulomb, Yukawa and inversely quadratic Yukawa as they obtained their normalized wavefunctions and energy eigenvalues, compared to other related work via the NU and AP method in their literature and the values obtained yielded reasonable result.Ita et al. [20] obtained bound state solutions of the Schrödinger's equation for Manning-Rosen plus a Class of Yukawa (MRCY) potential given as

r
is the distance from equilibrium position and α is the screening parameter.In their work, they obtained both bound and scattering state with energy spectrum of some special potential such as Hulthen, Manning-Rosen, Eckart and Wood-Saxon potential.Hansabadi et al.[33] studied a special kratzstate solution of the Klein-Gordon equation with position dependent mass ( ) trifugal term or potential barrier arising from the problem of interest.Not much has been achieved on the Schrodinger equation for the MGESCY potential over the years.The aim of this report is to obtain bound state solutions of the Schrödinger equation for the More General Exponential Screened Coulomb Potential plus Yukawa (MGESCY) potential.
hypergeometric-type functionsAnd on substituting Equation(12) into Equation(11), then Equation (11) reduces to hypergeometric type polynomials at most second degree and ( ) s τ is first degree polynomials.The parametric generalization of the N-U method is polynomials.The second part of the wave function is obtained from Equation (14) as

3. 1 .
Solutions to the Radial Part of the Schrodinger Equation with More General Exponential Screened Coulomb Potential (MGESCP) 60)To obtain the radial wave function o Equation (3), where 3 0 c → , the follow- Considering the bound state energy eigenvalue equation expressed in Equation (60), we obtained numerical values for different l-states at different screening parameters for CO molecule ( bound state energy eigen values of the Yukawa potential for diatomic molecules, we considered Equation (83) by subjecting V 0 = 0 for two states For CO and NO diatomic molecules moving under the influence of the mixed potential, we obtained the Energy eigenvalues given in Equation (83) and computed numerical values for different screening parameter.The r values for N 2 (1.0940), CO (1.21282) and NO (1.1508) were adapted from M. Karplus and R. N. Porter, Atoms and Molecules [39].

Table 3 .
Bound State Energy eigenvalues of the yukawa potential at 0

Table 5 .
Bound state energy eigenvalues of the mixed potential at 0 l = ,

Figure 6 ,
Figure 6, we have shown the variation of the effective potential (MGESCY) potential at α = 0.01, for l = 0 and l = 1.

Figure 2 .
Figure 2. Variation of the effective MGESC potential against distance for different α values at 1 l = , 0 2.75 MeV V = .

Figure 3 .
Figure 3. Variation of the effective MGESC potential against distance for different α values at 2 l = , 0 2.75 MeV V = .

Figure 4 .
Figure 4. Variation of effective Yukawa potential against distance for different α values at 0 l = , 1 2.075 MeV V = .

Figure 5 .
Figure 5. Variation of effective Yukawa potential for different α values at 1 l = ,

Table 2 .
Bound State Energy eigenvalues of the MGESC potential for

Table 4 .
Bound State Energy eigenvalues of the yukawa potential at