Hydrothermal Alterations in Irbiben Gold Deposit (Tagragra Akka, Western Anti-Atlas, Morocco): Petrographic and Geochemical Characterization

Irbiben is a small gold deposit of the Precambrian inlier Tagragra d’Akka located in the Moroccan western Anti-Atlas, approximately 160 km southeast from Tiznit. Petrographic study shows that host rocks of Irbiben deposit are green schist facies metamorphic rocks, like metamorphic sandstone and schist, meta-pelite and quartzite. Gold is located in quartz veins or host rock with frequent injections of quartz. The petrographic characterization of alteration through the description of the alteration profiles and the comparative study of protolith and altered rocks showed a development of dominant quartz and calcite in mineralization wall-rocks. In moving away from it, there is rather sericite and chlorite. These phenomena are materialized respectively by the development of SiO2 and CaO in the wall-rocks but rather that ferromagnesian elements (FeO, MgO) and K2O away from the mineralization. These trends were demonstrated by the geochemical study through Harker diagrams, description of alteration profiles, comparative study of protolith and altered rocks, and use of a new alteration index, MIA, elaborated during this work.


Introduction
The Irbiben gold deposit, formerly operated by the Akka Mine, is located in the Akka Tagragra inlier.It is located about 160 km Southeast Tiznit city, in the Western part of the Moroccan Anti-Atlas.This area is known for its numerous deposits, including the Imiter and Zgounder silver deposits as well as the Tiouit gold deposit.The inlier, outside Irbiben, also allowed the exploitation of gold in other sites such as Iourirn, Ifarar and Angarf.
As part of our missions in this area, we have made some observations: the presence of traces of hydrothermal activity in the wall rock of the mineralization.Indeed, in addition to the deformation caused by the placement of the gold-bearing quartz veins in the host rocks, a change, however minor, affects these in their mineralogy and their chemistry.This is why this paper proposes to identify and characterize this hydrothermalism through a petrographic and geochemical study of alteration.
This work deals with the study of hydrothermal alterations in Irbiben.Several studies [1] [2] [3] [4] have shown that there are close links between the development of gold mineralization and hydrothermal alterations.Indeed, this type of association occurs in deposits of the Tagragra of Akka [3] [5] of which Irbiben is a part of.

Global Geological Framework and Location
Morocco is subdivided into several structural domains which are from north to south: the Rifain domain, the Mesetian domain, the Atlasic domain, the Anti-Atlasic domain and the Saharan domain.Our study area is located in the Akka Tagragra inlier which is part of the Western Anti-Atlas area (Figure 1).This inlier is made of a Precambrian basement and a slightly deformed Palaeozoic cover.The Irbiben deposit is located in its eastern part (Figure 2), to Figure 1.Simplified geological map of the Anti-Atlas and its location in Morocco, with the location of the Tagragra of Akka inlier (Soulaïmani, 1998, modified) [6].

Lithology
The Irbiben deposit consists of rocks of both sedimentary and magmatic origin, with mineralization hosted in the sedimentary rocks.The age of the host is attributed to the Paleo-Proterozoic [7].
The sedimentary rocks consist of greywacke and sandstone alternating on a metric scale with pelites (Figure 3).These formations have been affected by the known epizonal metamorphism in the region, hence the presence of meta-sandstones, meta-greywacke, meta-pelites, quartzites and sandy shales in places.The sandstone material is dark gray and the pelites are black in color.The sandstone schist is distinguished from the other formations by their degree of schistosity.Meta-sandstones are sometimes deformed and injected with quartz.They can be mineralized.All these formations of the base are affected by the schistosity S 1 which follows the stratification S 0 , forming a fabric S 0 S 1 of medium direction N60.The schistosity S 2 is observed in several places and of direction near from N10 to N15.Some meta-sandstones are crossed by carbonate veins.
The proportion of quartz of certain silicified sandstones where the effects of regional epizonal metamorphism have not been detected, their hardness and their appearance make it possible to assimilate them to greywacke.
Magmatic rocks consist of diorite and quartz micro-diorite outcropping in the form of dykes, aplite vein and massive granite.
The dykes are scattered in the deposit near the mineralized structures and further in the southern part of the deposit where they are in contact with the The granite outcrops in the form of a massif.It presents in some places a clear limit with the dyke, of direction between N30 and N50.It intrudes the meta-sedimentary formations of the PI basement and occupies all the rest of the southern part of the eastern lobe of the inlier.Mortaji [8] assimilates it to granite with biotite or biotite and secondary muscovite.
The aplite there is lode, located in an intermediate zone between the granite and the dyke.

Materials and Methods
Twelve (12) samples were taken from the cross-bed siding at the level −70 m (TB-70), then in operation.They are designated A, B ... up to L (Figure 3).Eight samples designated IRBC43A to IRBC43H were also taken from the IRBC43 drill core that intersected the host formations and the NE gold quartz vein.
The petrographic study required a macroscopic and then microscopic flap, after preparation of thin plates.
Eight (8) samples were subjected to inductively coupled plasma mass spectrometric (ICP-MS) at the REMINEX research center of the MANAGEM group in Marrakech.These are two samples from the NE1 Irbiben structure of the −70 level and six from its vein wall and of the host on the sides of the vein.
Figure 3 shows the geological mapping of the southern cross-bench facing (TB-70), with the location of the samples taken and the gold structure.

Alteration Profiles Description
The study of alteration profiles in the Irbiben deposit required the prior observation of the hosting rocks crossed by the gold-bearing structure.The hydrothermal activity associated with the placement of the gold vein influenced the host rocks.This is reflected in an increase in their silica rate and an iron intake.This contribution is materialized by the deposition of ferriferous sulphide minerals such as arsenopyrite, pyrite or chalcopyrite that accompany the deposition of gold mineralization.The complete observation of the cores showed that the highest gold grades were found in the vein levels, where they could reach 14 g/t for the IRBC43 drilling or 13 g/t for IRBC16.The grades found in the metasedimentary material are less important, oscillating between 1 and 4 g/t.
Mineralized veins are mainly composed of silica and carbonates.This explains why the host rock affected by the hydrothermal fluid underwent enrichment in these elements, materialized by more developed quartz and calcite in the vicinity of the gold zone.The placement of the vein was also at the origin of the deformation detected in the host and materialized by a mylonitization.

Petrographical Characterization of Alteration
The mineralogical changes between the host rock and the wallrock of the gold vein reflect the decreasing impact of the hydrothermal fluid on the host by moving away from the vein.This is why we choose to highlight the comparative The protolith is located 3 m from the gold vein.This is sample D. It is a metagreywacke composed of quartz, healthy plagioclases and micas.Automorphic and sub-automorphic quartz and plagioclases have an initial orientation.Micas are interstitial.
The altered rock constitutes the wall of the mineralization (sample F).This is a distorted meta-greywacke.It contains much more quartz, fewer healthy plagioclases, most of which are altered, sericite, chlorite, calcite and epidote.
Observing also the mineralized vein (sample L), we find that it is essentially dominant quartz and calcite.The altered rock contains, in addition to the minerals of the control rock, new minerals such as well-developed calcite and epidote.Furthermore, the proportions of the minerals common to both samples vary in terms of the distance to the vein.Sericite and chlorite have higher grades in the hanging wall.These observations are illustrated in Figure 4.
By approaching the vein, the host is enriched much more in quartz and calcite than in sericite and chlorite.The host is metasedimentary, which explains the presence of sericite and chlorite in its composition.However, in contact with the vein, it knows enrichment in these minerals.The hydrothermalism accompany-

Alteration Geochemistry
The oxide weight grades of the samples analyzed show notable variations for some, in particular SiO 2 , for which they are between 82.49% and 54.52% (Table 2).The highest grade characterizes the gold vein and, on the mineralogical level, it is represented by an abundance of quartz minerals, in the form of 3 distinct petty-types.The quartz Q III which is the most recent and resulting from the hydrothermal alteration is the most represented.From the host rock to gold structure, the amount of quartz of the rocks increases, which is corroborated by the geochemical analyzes which show a gradual increase of SiO 2 of 54.52% in the host rock to values reaching 64.57% in the hanging wall to be maximum in the vein (78.45% and 82.49%).This increase is caused by the interaction of the hydrothermal fluid at the origin of the aqueous silica supply as in the Ifarar deposit [5].This influence is materialized on the ground by a silicification, more important in the level of the hanging walls and which is translated by a predominance of hydrothermal quartz Q III .
Except for CaO and MnO grades that increase with the SiO 2 grade in the rock, the other analyzed oxides show downward tendencies as they move closer to the gold vein (Figure 5).
To understand better the impact of the gold vein on its host rock, an average of the oxide weight grades was calculated for samples from rocks equidistant from the vein on both sides.The evolution has therefore been followed from the gold-bearing structure, passing through the hanging wall to the more distant rocks.These new calculated grades are presented in Table 3.Although the difference in grade between the gold vein and its hanging wall is significant (from 4.9% to 10.54%), it is not significant, as the rock is already rich in these oxides.This increase is due to a destabilization of the minerals of the host, such as plagioclases, the alteration of which produces sericite, which increases its proportion in the hanging walls.Moreover, the deposition of the mineralization is accompanied by the neo-formation of chlorite minerals.It is a previously observed iron chlorite and is described in other deposits of the Tagragra Akka inlier [3].An increase in the proportion of chlorite in host rock causes in the hanging wall an increase in the grade of FeO tot and MgO (Table 3), which corresponds to the analyzed and calculated grades.The plagioclases alteration which produces sericite and the neo-formation of ferric chlorite are hydrothermal events corresponding respectively to sericitization and chloritization of the host.
However, sericitization is much more related to the variation of alkalis elements, which increase significantly between the gold vein (1.42%) and the hanging wall (3.89%).The formed sericite mobilizes more K 2 O and Al 2 O 3 than ferromagnesians which are associated with chlorite.The highest grades of alkaline (Na 2 O + K 2 O), which are 5.3% and 5.47%, characterize the host rock originally formed from minerals containing potassium such as sericite or muscovite.
For the host rocks, the CaO grades varying from 0.16% to 0.27% are lower than that of the hanging walls, which is 1.06% (Table 3 and Figure 6).The highest grade is 3.14% and is associated with the gold vein.
In Irbiben, the gold quartz vein is predominantly composed of quartz, associated with calcite, as shown by the microscopic study (Figure 4).The lowest grades in host rock show a lack of calcite.The CaO grade of the vein and that of Figure 6.Harker diagrams of oxide variation of the samples as a function of SiO 2 , obtained from the mean of the grades for equidistant samples of the vein.
the hanging wall reveal the influence of the hydrothermal fluid on host rock by a carbonate supply.The orogenic gold deposits are characterized by aquo-carbonic fluids [9] [10] [11] and their circulation is almost always associated with the addition of CO 2 , K and S, with a slight addition or loss of other major elements [9].The presence of carbonates has also been reported, associated with the quartz of these veins [12].In Irbiben deposit, the mineralogical changes observed in the host rock make it possible to suspect a fluid of this type.Its interaction with the initial calcium (detected by geochemical analysis) of the host rocks caused the formation of hydrothermal calcite in the hanging walls, by alteration of the plagioclases.The formation of hydrothermal calcite in the deposit corresponds to calcitization.
The mobility of trace elements such as boron, barium, strontium and lead should be considered in the study of hydrothermal alterations.Table 4 presents the correlations between the major elements and significant traces in the study of the alteration.
Boron which is generally associated with hydrothermal minerals has good correlations with K 2 O (0.82) and FeO tot (0.68).In the Irbiben deposit, in addition to the ferrous sulphide minerals, some hydrothermal minerals may be ferriferous, such as the chlorite which accompanies mineralization.Changes in K 2 O are associated with sericitization.Boron associates with sericite and chlorite, which explains its high grades in the host rocks of the deposit (101 ppm to 123 ppm), except in the vein where values are very low (31 ppm to 52 ppm).
Barium has also a good correlation with TiO 2 , FeO tot and K 2 O.These oxides have their grades which increase with the alteration.Its strong negative correlation with calcium (−0.80) reflects the significant substitution of calcium from the host rocks by barium.This explains why the host rocks are not rich in calcite.

Discussion
The gold mineralization of Akka Tagragra inlier is carried by quartz veins and hosted by metasedimentary and igneous formations.Unlike the main deposit Iourirn in dykes of basic magmatic rocks [3], no dyke was intersected by gold veins at Irbiben.However, as at Iourirn where hydrothermal alterations were noted by Zouhair [7] and Benbrahim [3] the hydrothermal phenomena were recorded in Irbiben.The placement of these veins has led to the formation of quartz with recrystallization texture, iron chorite, recognized by Benbrahim [3] and sericite.The newly formed calcite associated with quartz corresponds to what has already been described by Dubé and Gosselin [12].The interest of this study was to demonstrate the hydrothermalism accompanying the setting of inlier mineralization.Following the example of the Ishikawa alteration index, the new MIA index developed in this study will show enrichment in iron and calcium in placement of gold veins in similar deposits.However, it would be interesting to carry out a further mineralogical characterization of the hydrothermal minerals by microprobe.Moreover, a combined study of fluid inclusions in the host rocks to compare them to metasomatised rocks would better characterize the hydrothermal fluid.

Conclusions
The host formations of the Irbiben deposit are composed of rocks generally metamorphosed in the green schist facies.They are predominantly sandstone schists and metasandstone, to which are added metapelites, quartzites and grauwakes.A granitic massif south of the deposit and diorite dykes has been identified.
The hydrothermal activity has led to the formation of secondary minerals such as calcite, sericite, chlorite or quartz Q III .These mineralogical changes are reflected in the chemical composition of the rocks, resulting in a much higher silica and calcium grade, much more important in the hanging walls accompanied by an increase in iron.These tendencies could be corroborated by the use of the new MIA alteration index bringing out the iron enrichment accompanying the calcitization, as well as the matrix of correlations showing the mobility of certain elements such as calcium and barium, or still the very positive correlation between boron, potassium and iron.By moving away from the gold structure, the predominant ferromagnesian and alkaline grades are due to sericitization and chloritization but also and above all to a predisposition of the host, initially rich in these elements.Such changes noted in the hanging walls and the host rock of the Irbiben deposit reveal aquocarbon mineralization fluid of the orogenic deposits.The latter can influence the host rock by adding aqueous silica.Its CO 2 component associated with the Ca of host rocks causes the formation of hydrothermal calcite in the hanging walls.This explains the importance of silicification and calcitisation in the hanging walls.

Figure 3 .
Figure 3. Geological mapping of the southern facing of TB-70 in the Irbiben deposit, with the location of the samples taken.
ing the placement of the vein influences the composition of the host rock by a contribution of silica and carbonates materialized by the appearance of quartz Q III and calcite or the development of quartz Q II .Alteration sericite originates essentially from the destabilization of pre-existing minerals such as plagioclases and chlorite comes from a neo-formation of minerals accompanying deposition of the mineralization.The various alterations are silicification which is the most important and which is associated with calcitization, sericitization and chloritization.Hanging walls are more marked by silicification and calcitization.These phenomena have already been observed in the Ifarar deposit[5].

Figure 4 .
Figure 4. Microphotographs of thin slides showing the mineralogical evolutionof the gold-bearing vein to the control rock.

Figure 5 .
Figure 5. Harker diagrams of oxide variation of samples as a function of SiO 2 .
Its use has shown certain tendencies, notably an evolution of the inverse index to that of the SiO 2 grade in the samples (Figure7).The enrichment of iron and calcium is related to the preliminary observations: the development of hydrothermal calcite and newly formed chlorite when getting close to the the mineralized vein.Iron-bearing sulphides are also more abundant at this level, as shown by the metallographic study.From another angle, the variation of this index shows an increase in magnesium and potassium when getting away from the gold structure.This tendency shows the development of sericitization.On the other hand, chlorite in this case is rather magnesian.Differences have been detected both in the microscope and in the microprobe[3].

Figure 7 .
Figure 7. Comparative variation of MIA and SiO 2 (upper); Variation of the MIA index as a function of SiO 2 content (bottom).

Table 1
filled with oxides and it crosses a metasandstone formation.The second gold level is rather a silicified meta-sandstone with numerous injections of gray quartz associated with carbonates.It is also with oxides, sericite, chlorite, pyrite, pyrrhotite and arsenopyrite.It marks a boundary between a metasandstone rock and a graphitized black metapelite.These observations show the existence of different auriferous structures of the quartz veins.It is the host, metasandstone or metapelitic, with numerous injections of mineralized quartz.

Table 1 .
Synthesis of the macroscopic study of core drillings crossing the Irbiben NE1 gold structure and the meta-sedimentary host in the Irbiben deposit.pyrite, pyrrhotite and arsenopyrite Journal of Geoscience and Environment Protection microscopic study of two samples, one considered as control rock and the other as altered rock.

Table 2 .
Geochemical analyzes in major elements of Irbiben samples.
81 Journal of Geoscience and Environment Protection

Table 3 .
Mean oxide grades calculated for samples situated at the same distance from the gold vein.However, the initial rock is potentially rich in these oxides, with about 10.38%.The gold vein presents the lowest grade which is of 4.9%.
Vein Au (L) Wall rock F − H E − I (2 m) D − J (3 m) The ferromagnesian (Fe + Mg) grades of the rocks are associated with the proportion of ferromagnesian minerals such as chlorite (corresponding oxides: FeO tot and MgO) and sericite (K 2 O).The highest oxide grade by weight corresponds Journal of Geoscience and Environment Protection to the hanging wall.

Table 4 .
Correlations matrix between major elements and traces revealing the alteration.Journal of Geoscience and Environment Protection In the Irbiben deposit, variations in lead and strontium are not significant, indicating poor mobility of these elements during alteration. New MIA alteration index This work led to the development of a new index of alteration MIA, resulting from the modification of that of Ishikawa, modified by substitution in the previous formula of sodium by total iron.It is calculated from the weight percentages of oxides and is obtained by the formula: