Porous Structure of Municipal Solid Waste Incineration Bottom Ash in Initial Stage of Landfill

For quantitative estimation of the intra-layer porous structure in the initial stage of landfill formation with municipal solid waste incineration (MSWI) bottom ash, the water absorption of individual MSWI bottom ash particles was measured under still-water, degassed, and agitated conditions. The ratio of the water absorption rate found for the still-water procedure to the effective absorption capacity which was the one under degassing was 35.2%. In the water flow experiment of a column filled with MSWI bottom ash, the true density of the bottom ash was higher after water flow than before, which indicated that dissolution of the soluble components of the bottom ash particle surfaces resulted in a loss of apparent particle volume that more than offset the accompanying weight loss. The volume-based water absorption rate found for the bottom ash particles following 50 mL/h water flow through the column, as a ratio to the effective absorption capacity was about 51.8% of the effective absorption capacity. In a landfill layer comprised of MSWI bottom ash, it was suggested that some regions of the ash particle interiors underwent almost no contact with water.


Introduction
In Japan, approximately 80% of municipal solid waste is incinerated and its importance is growing, as finding new sites for final disposal has become more and more difficult, particularly in urban areas.Municipal solid waste incineration (MSWI) residues constitute the main material in final waste disposal, accounting S. Sakita  for about 74% of all landfilled waste [1].
Internal stabilization of landfill layers formed by waste materials begins with component washout by rainwater.MSWI residues are similar in composition to the raw material of cement [2] [3], and in a landfill layer may be expected to harden and solidify over time as its components undergo hydration [4] [5].Incineration residues are high in calcium (Ca) content and may be expected to undergo mineralization and changes in physical microstructure, with carbonation by carbon dioxide (CO 2 ) generating mainly such minerals as calcite (CaCO 3 ), ettringite (3CaOAl 2 O 3 CaSO 4 •32H 2 O), gypsum (CaSO 4 •2H 2 O), and anhydrite (CaSO 4 ) [6]- [11].These changes are known to result in the gradual formation of water pathways within the landfill layer [12] [13] [14].Rosqvist and Destouni performed tracer experiments in undisturbed landfill waste samples and showed that approximately 55% -70% of the infiltrating water followed preferential flow paths [15].This tends to prevent homogeneous washing of landfilled waste components by rainwater and hinders external release of gases generated within the landfill layer [16].
MSWI bottom ash particles occur in many different derivations, shapes, and sizes.They are porous, with a small pore size and large pore density, and exhibit capillarity that becomes high with decreasing pore size [12].Because the MSWI bottom ash particle surface is generally hydrophobic, however, it is believed that water either does not penetrate to the particle interior (and thus is not absorbed), or penetrates only over an extremely long time span.Stabilization of the particle interior may therefore lag far behind the particle surface.At present, much remains unknown in regard to water pathway formation in MSWI bottom ash landfills and the water absorption of the MSWI bottom ash particles themselves, and the effects on leachate properties and stabilization of landfilled wastes.
In this study, for quantitative estimation of the intra-layer porous structure in the initial stage of landfill formation with MSWI bottom ash, the water absorption of individual MSWI bottom ash particles were measured and then investigated the flow of water through a column filled with the MSWI bottom ash as a simulated landfill layer, and its effects on the intra-layer porous structure accompanying the elution of its soluble components.

Samples
The samples used in this study were composed of water-quenched MSWI bottom ash generated in a semi-continuous stoker furnace with unburned materials and incombustible parts like metals removed as much as possible.The particle size distribution is shown in Figure 1, and the true density measured by a pycnometer method was 2.54 kg/cm   1.

Bottom Ash Particle Water Absorption
MSWI bottom ash particles are porous, with the pores varying in size.In this experiment in order to estimate void structure, water absorption rate (%) of MSWI bottom ash particles, which is defined as the rate (%) of the water content of ash particles after absorption of pure water for a specified time and surface drying to the dry weight of them.Mercury porosimeter method and nitrogengas adsorption isotherms are commonly used to investigate the void volume and void distribution in porous bodies, but here we applied the coarse-aggregate water absorption rate measurement method specified in the Japanese Industrial Standards (JIS A1110).
Figure 2 schematically shows the three states of water absorption by bottom ash particles.In the wet state, the absorbed water extends to the particle surface.
In the dry-surface state, the water has been removed from the surface of the wet-state particle.In the absolute-dry state, the dry-surface state sample has been further dried by heating at 110˚C until the weight of the particle becomes constant.
The water absorption rate of MSWI bottom ash was measured by the following three procedures, using samples with particle sizes d ≥ 2 mm.a) Still-water absorption: 50 g of the sample and 500 mL of pure water were placed in a 500 mL beaker and water absorption was allowed to proceed while Cumulative passing (%) Particle size (mm)  For each experiment, a preliminary trial was first performed to confirm attainment of a constant weight within the specified period.Each procedure was followed by filtration through 1.0 μm membrane filter, measurement of the wet-particle weight m 2 (kg) of the sample (with water present both on the surface and within the particles), oven-drying at 110˚C for 24 hours, and air cooling followed by measurement of the resulting dry weight m s (kg).The sample was then immediately immersed in 500 mL of pure water, quickly followed by filtering through a 1.0 μm membrane filter and measurement of the resulting wetsurface weight m 3 (kg) of the sample (with water present only on the particle Journal of Geoscience and Environment Protection surface).The water absorption rate was calculated as the weight-based rate P (w/w %) and as the volume-based rate P' (v/v %) using Equations ( 1) and (2), respectively.Each procedure was implemented with 50 bottom ash particles.
( ) Here, P is the weight-based MSWI bottom ash particle water absorption rate (w/w %), P′ is the volume-based incineration ash particle water absorption rate (v/v %), m s is the weight (g) of the sample in the absolute-dry state, m 1 is the weight (g) of the sample in the dry-surface state, ρ s is the true density of MSWI bottom ash (g/cm 3 ), and ρ w is the density (g/cm 3 ) of pure water at room temperature (20˚C).

Water Flow Experiment through a Column Filled with the MSWI Bottom Ash
An acrylic column was filled with MSWI bottom ash to simulate an actual landfill layer, water was flowed into the column, and the bottom ash was investigated for macro changes in intra-layer porous structure resulting from elution of its soluble components in the water flow.As shown schematically in Figure 3 of their high inorganic contents, the NaCl solution was used as a tracer in this case because it was flowed after EC reached very low.The leachates were periodically sampled using a fraction collector (CHF 121SA, Advantec Toyo Corp.).
After filtration through 1.0 μm membrane filter, pH, EC, evaporation residue, Cl, Ca, K, Na, Cr, Cu, Zn, Cd, and Pb concentrations of each leachate were measured.
After completion of water flow, the bottom ash particles were removed from the column, their true density was measured using a pycnometer, and the porosity of the waste filled in the column was calculated using Equation ( 3).The water absorption rate of the 50 bottom ash particles was measured after the 50 mL/h flow procedure.
Here, ε i is the porosity, m i is the filled sample weight (g), ρ s is the true density of the sample (g/cm 3 ), and V is the packing volume (cm 3 ).Water absorption rate (%) Agitated mean was higher than those found for the other procedures.The measured values ranged from 0.31 to 2.08 times the mean values, due to the particle heterogeneity.The water absorption rate under degassing was higher than those found for the other procedures, and apparently represents the maximum attainable ratio for such particles.It is therefore referred to as the "effective absorption capacity" in this study.The ratio of the water absorption rate found for the stillwater procedure to the effective absorption capacity was 35.2% in the weightbased, which was the lowest found in any of the procedures and showed that only about 1/3 of the effective absorption capacity was utilized in still-water.

Water Absorption of Bottom Ash Particles
Under agitation, the water absorption rate was 58.5% at 100 rpm and 71.4% at 200 rpm as a result of volume-based.The water absorption rate thus increased with stirring speed, and at 300 rpm reached 86.4% of the effective absorption capacity.
In actual landfills, the coefficient of permeability in layers composed primarily of MSWI bottom ash is low, and the results of this experiment indicate that in such regions the water flowing between bottom ash particles does not completely fill the particle interiors, with about two-thirds of the pores undergoing little or no water washing.

MSWI Bottom Ash Packed Column Water Flow
Figure 5 shows the relation between the L/S ratio and the leachate pH, EC, Cl − , Figure 5. Relation between L/S ratio and pH, EC, Cl − , and evaporation residue concentration, under pure water flow.L/S Journal of Geoscience and Environment Protection and evaporation residue concentration under flow of pure water into a column filled with MSWI bottom ash.The EC, Cl − , and evaporation residue concentration fell sharply as the L/S ratio rose to about 3, indicating rapid elution of readily soluble components of the bottom ash.The pH rose just after water flow and then declined to about 11, but no large change was observed under the flow rates used in this study.The cumulative evaporation residues at L/S ratios of up to 10 were 3.89, 4.41, and 4.82 g/kg-dry bottom ash under water flow rates of 50, 110 and 320 mL/h, respectively, thus showing increasing elution of the bottom ash particles and their soluble components with increasing water flow rate.
Table 2 shows the true density found for the bottom ash particles and the porosity of the packed bed in the column before and after water flow, as calculated by Equation (3).The true density was higher after water flow than before, which indicates that dissolution of the soluble components of the bottom ash particle surfaces resulted in a loss of apparent particle volume that more than offset the accompanying weight loss.The decrease in true density after water flow increased with the flow rate, with a similar trend found for the cumulative evaporation residue.The porosity of the packed bed in the column was 22% -44% higher after water flow than before, which also indicates that the inter-particle void fraction increased with decreasing particle volume.
Figure 6 shows the relation between the L/S ratio and the Cl − concentration in Table 2. True density of bottom ash particles and porosity of packed bed, before and after water flow.ing in an increased porosity of the packed bed in the column (Table 2), thus facilitating water flow.
Figure 7 shows the volume-based water absorption rate found for the 50 MSWI bottom ash particles following 50 mL/h water flow through the column, as a ratio to the effective absorption capacity.Also shown are the ratios found for the still-water and agitated absorption (See 2.2).Despite the water-saturated state in the column flow experiment, the water absorption rate was only about 51.8% of the effective absorption capacity, which indicates that the particle interiors remained unsaturated in the saturated inter-particle porous environment.
In summary, the results indicate that in a landfill layer comprised of MSWI bottom ash, some regions of the ash particle interiors undergo almost no contact with water.This in turn implies that a landfill meeting the leachate standards for its quality may actually retain harmful or hazardous materials.

Conclusions
The water absorption rate of MSWI bottom ash was measured under still-water, Figure 7. Ratio of MSWI bottom ash water absorption rate to effective absorption capacity, in column with flow rate of 50 mL/h, the still-water and agitated absorption.In the water flow experiment of column filled with MSWI bottom ash, the true density of the bottom ash was higher after water flow than before, which indicates that dissolution of the soluble components of the bottom ash particle surfaces resulted in a loss of apparent particle volume that more than offset the accompanying weight loss.The porosity of the packed bed in the column was 22% -44% higher after water flow than before, which also indicates that the inter-particle void fraction increased with decreasing particle volume.
In the tracer experiment with NaCl solution, the retention time at each water flow rate was decreased.The shorter retention time following NaCl solution flow breakthrough was presumably attributable to elution of the readily soluble components during pure water flow, resulting in an increased porosity of the packed bed in the column, thus facilitating water flow.
The volume-based water absorption rate found for the bottom ash particles following 50 mL/h water flow through the column, as a ratio to the effective absorption capacity was only about 51.8% of the effective absorption capacity.This indicates that the particle interiors remained unsaturated in the saturated inter-particle porous environment.
Further investigation will be necessary on long-term hardening and solidification of the landfill layer, allowing uniformwater and gas transport inside and outside the landfill layer.

Figure 2 .
Figure 2. Water absorption states of bottom ash particles in (a) absolute-dry, (b) postwater absorption wet, and (c) dry-surface states.

Figure 3 .
Figure 3. Schematic of column water flow experiment.

Figure 4 Figure 4 .
Figure 4 shows the water absorption rate ((a) weight-based, (b) volume-based) found for the bottom ash particles in the still-water, degassed, and agitated procedures.Volume-based water absorption rate was calculated from weight-based one using Equation (2).The measured values ranged from 0.31 to 2.08 times the

Figure 6 .
Figure 6.Relation between C/C 0 and L/S ratio (C: Cl − concentration in column leachate; C 0 : Cl − concentration in column feed).
Journal of Geoscience and Environment Protection the leachate under injection of the NaCl solution in the tracer experiment.The vertical axis represents C/C 0 , where C is the Cl − concentration in the column leachate and C 0 is the Cl − concentration in the inflow solution.The rise in outflow Cl − concentration to a value slightly higher than that for the feed Cl − concentration indicates that a small amount of Cl − remained present in the column after pure water flow.The rise in Cl − concentration showed a tendency to occur earlier at higher flow rates.The retention time at 50, 110, and 320 mL/h, as calculated from the effluent discharge during pure water flow and after breakthrough following the change to the NaCl solution divided by the time, were 8.19, 4.05, and 1.19 h, respectively, just after pure water flow, and 6.20, 2.81, and 0.96 h, respectively, after NaCl solution flow breakthrough.The shorter retention time following NaCl solution flow breakthrough are presumably attributable to elution of the readily soluble components during pure water flow, result- 100 rpm 200 rpm 300 rpm Ratio of iMSWI bottom ash water absorption rate to effective absorption capacity (%) Agitated Journal of Geoscience and Environment Protection degassed, and agitated conditions.The ratio of the water absorption rate found for the still-water procedure to the effective absorption capacity was 35.2%.Under agitation, the water absorption rate increased with stirring speed, and at 300 rpm reached 86.4% of the effective absorption capacity.In actual landfills, the coefficient of permeability in layers composed primarily of MSWI bottom ash is low, and the results indicate that in such regions the water flowing between bottom ash particles does not completely fill the particle interiors, with about twothirds of the pores undergoing little or no water washing.
et al.

Table 1 .
Sample content and JLT13 leachate concentration.