A Clean Technology for Future Prospective : Emission Modeling of Gas Based Power

The aim of present research is to study the dispersion of air pollutants using the air quality model, AERMOD and to predict the impact of pollutants (PM10, NO2 and CO) at the receptor level released from Gas Based Power Plant (GBPP). The netconcentrations including monitored data plus predicted values of PM10, NO2 and CO would be increased from base value 75 to 77.61 μg/m with an increase of 3.48%, 22 to 26.66 μg/m with an increase of 21.18% and 428 to 538.37 μg/m with an increase of 25.79% respectively. The study of hill effect showed that it had profound impact upon the dispersion of pollutants and the ratio (with hill and without hill) of each pollutant was 3.89 for PM10 (24 hr), 2.40 for NO2 (24 hr) and 13.98 for CO (1 hr). The natural gas based plant not only decreases the pollution level but also reduces the hospital treatment cost and protects the public health. The modeling results suggest that the GBPP could be a clean technology as replacement of coal power plants located in the city which pollute the environment considerably in spite of control measures installed.


Introduction
Industrial activities are continuously releasing huge amounts of health affecting air pollutants which can jeopardise the environmental health and impair the balance of the ecosystem.These air pollutants formed in the atmosphere gradually come down and concentrate in the breathing zone or are deposited on the ground level under gravitational pool [1].All environmental receptors, including plant and animal life are severely affected, eventually resulting in their death [2] [3].Many Air Quality Models (AQMs) have been developed over the years to predict the atmospheric build-up of pollutants and to determine the ground level concentration, which are likely to affect property and life [2].These air pollutants can directly be measured qualitatively and quantitatively by various chemical methods.But recently mathematical models have become more popular and reliable tools to predict the ground level concentration of air pollutants at selected location in downwind direction.These modern and sophisticated AQMs provide the exposure level in any particular direction and distance from the point sources at different heights [3].Such AQMs are widely used because of their cost effectiveness and ease of operation as compared to actual field survey for the proper management of the impact of pollutant emissions on the environment.These models also provide many micro details in advance regarding the rate of transport, rate of transformation from one chemical form to another in the atmosphere depending upon the prevailing climatic conditions, vertical/horizontal turbulence and diffusion/dispersal of pollutants and gravitational settling of pollutants [4].AQMs in general, use the meteorological data, stack configurations (stack elevation from the ground level, stack height, effective stack height, stack inner diameter at exit point, flue gas discharge velocity and stack gas temperature), type of raw materials, process technology, chemical reaction in the atmosphere, terrain topology and topography especially the altitude of nearby hills and nature of valley as well as ambient air related parameters for the assessment of the dispersion of air pollutants [5].
Fragmented information is put together for simulation through complex mathematical calculations using permutation and combinations by the AQMs.These models produce valuable information which is likely to occur at different situations or different seasons viz.summer or winter [6] [7].Based on these predictions, preventive measures could be taken in advance to reduce the magnitude or to dilute the effects so that deleterious effects upon human/animal life, property, flora and fauna, terrestrial/aquatic ecology can be avoided.Land and natural resources could be conserved from further degradation [8].
The atmospheric build-up of hazardous air pollutants may result in fog formation in a location especially valley of a hilly region.It is due to the poor atmospheric stability conditions like thermal inversion and extremely stable condition.They have become a frequent phenomenon adversely affecting flora and fauna of the surrounding environment [8] [9].
The main objective of this modeling study therefore, is to estimate the potential of air emissions from a gas based power plant (GBPP) and to determine the maximum ground level concentration of particulate matter (PM 10 ), carbon monoxide (CO) and nitrogen dioxide (NO 2 ) on the existing air quality and its negative effect on surrounding environment.

Sampling Location and Frequency
Three locations taken average of each was selected and monitored to determine the concentrations of existing air quality of plant area which was considered for further calculations.The sampling frequency was twice in a month for 24 hr.

Sampling Procedures
Particulate Matters: Particulate Matters (PM 10 and PM 2.5 ) are the two major components of inhalable particles which are targeted in this investigation.Respirable Dust Sampler (APM 460, Envirotech, New Delhi) was operated at a flow rate of 1.1 m 3 /min.
The particles ≤ 10 μm in size were separated from non-respirable coarse particles by centrifugal force, collected on the EPM 2000 filter, 8" × 10" (Whatman), previously conditioned at 70˚C -80˚C were determined gravimetrically [10].Simultaneously, the monitoring of PM 2.5 was carried out using Fine Particulate Sampler (APM 550) fitted with a WINS-Anderson Impactor, Envirotech, New Delhi and was operated at a constant flow rate of 16.6 L/min.In PM 2.5 sampler, the air stream leaving the WINS cascade impactor consists of only fine particulates with an aerodynamic diameter ≤ 2.5 μm.
Teflon filters (47 mm) were used for gravimetric analysis of PM 2.5 [11] [12].Samplers were always installed at a height of 4 feet above the ground level to collect representative particulates present in the breathing zone.
Sulphur Dioxide: The best method currently available for SO 2 analysis is the modified West-Gaeke method.It can measure concentrations over a range of 0.005 -5.000 ppm with an accuracy of ± 10% (including sampling and analysis) at the lower end of the range and ± 5% at the upper end with a precision of about 2%.In this method, a known quantity of air was passed for 8 hr through an impinger containing known quantity of absorbing solution, sodium tetra chloro mercurate (NaHgCl 4 ).The absorbed sample and solution forms a stable color complex of di-chloro sulphito mercurate with p-rosaniline hydrochloride.The intensity of color developed was estimated by a spectrophotometer at 560 nm using a calibration curve.
Oxides of Nitrogen: A known quantity of air was bubbled for 8 hr through an impinger containing NaOH solution as absorbing media which formed a stable solution of sodium nitrate.The nitrite ion produced during sampling was determined colorimetrically at 540 nm by reading the exposed absorbing chemical solution with phosphoric acid, sulphanilamide and N-(1-Napthyl) ethylene di-amine di-hydrochloride following the modified Jacob and Hochheiser method.
Carbon Monoxide: Online CO analyzer was used to continuous monitoring of CO.
This equipment works on Non-Dispersive Infrared (NDIR) spectroscopy.NDIR photometry provides a method of utilizing of integrated absorption of infra-red energy over most of the spectrum for a given compound to provide a quantitative determination of concentration of CO in ambient air.

Source Characteristics
The AERMOD modeling system requires a physical description of the ground surface i.e. topography and topology of the surface area.Plant has one stack and its parameters are presented in Table 1.

Land Use and Geo-Physical Parameters
The geo-physical parameters are land use pattern, terrain topology, surface roughness, albedo and bowen ratio (Table 2).The NED data was processed with AERMAP, a pre-processor program which was developed to process terrain data (with base elevation and hill height) in conjunction with a layout of receptors and sources to be used in AERMOD [14] [15].This study model was run with elevations and without elevations to understand the impact of hills.

Meteorological Data
The AERMOD modeling system requires a meteorological data like wind speed, wind

Results and Discussion
The particulate concentrations (PM 10 and PM 2.5 ) in the ambient air ranged from 49.

Evaluation of Dispersion Modeling Output
The modeling was carried out with both terrain options: 1) flat land (considering zero elevation) and 2) Elevated land (considering the hill heights).By this approach, the magnitude of impact of hills was measured.The predicted ambient air concentrations for PM 10 , NO 2 and CO were estimated for various averaging periods (24 hr and annual) for PM 10 and NO 2 whereas 1 hr and annual for CO.The predicted highest value of each average period was compared with the standard of NAAQS [16].

Predicted Value of Particulate Matter (PM10)
The model computed concentrations for PM 10 are mentioned in Table 5.For elevated terrain (with hills), the highest concentration was 2.61 µg/m 3 for 24 hr and it was 0.24 µg/m 3 for annual.Both these concentrations were found well below the standards of    2 and Figure 3).

Predicted Value of Nitrogen Dioxide (NO2)
The model-computed concentrations for NO 2 are given in Table 5.During the modeling for NO 2 , the plume volume molar ratio method was considered.The ambient equilibrium ratio NO 2 /NOx was taken as 0.90.When the hill height was taken into consideration, the highest predicted value of NO 2 was 4.7 µg/m 3 for 24 hr as compared to 1.94 µg/m 3 without considering the hill height.The observed concentrations were found below the NAAQS for NO 2 (Standard: for 24 hr 80 µg/m 3 and for annual 40 µg/m 3 ).The  individual highest concentrations for 24 hr and annual are shown in isopleths (Figure 4 and Figure 5).

Predicted Value of Carbon Monoxide (CO)
The model computed concentrations for CO are given in Table 5.When the hill height is taken into consideration, the highest predicted values of CO were 110.37 µg/m 3 for 1 hr and 0.90 µg/m 3 for annual.The concentration of carbon monoxide for 1 hr was  found to be below the NAAQS for CO (Standard: for 1 hr 4 mg/m 3 ).The isopleths related to highest values for 1 hr and annual at receptor locations are shown in Figure 6 and Figure 7 respectively.
The higher concentration of particulate matter (PM 10 ) with respect to gaseous pollutants was found to be within the plant boundary area as compared to the outside area.
This may be attributed to higher mass and density of particulate matter than gaseous pollutants; therefore particulate matter cannot disperse easily with time.Because of the  It is evident from the isopleth shown in Figure 2 that the highest concentration of particulate matter-PM 10 was within the plant boundary in North-East direction.The annually dispersion of PM 10 was in East (Figure 3).It is clear from the isopleth shown in Figure 6 that the higher concentration (110.37 µg/m 3 ) of carbon monoxide for 1 hr was found in area close to stack and the dispersion of carbon monoxide were in East direction (Figure 7).

Impact of Hill upon Dispersion of Pollutants
Since the plant is situated in the lap of the hills, henceforth it becomes imperative to carry out AERMOD to study the effect of hills upon dispersion of pollutants.The annual concentrations of PM 10 , NO 2 and CO with hill were 0.24, 0.65 and 0.90 µg/m 3 respectively while their corresponding values were 0.08, 0.26 and 0.32 respectively without hill.The percentage increase due to the presence of hills was 26% for PM 10 , 42% for NO 2 and 7% for CO.The ratio (with hill and without hill) of each pollutant was 3.89 for PM 10 (24 hr), 2.40 for NO 2 (24 hr) and 13.98 for CO (1 hr) while the annual ratio (with hill and without hill) was 3.00 for PM 10 , 2.50 for NO 2 and 2.81 for CO.The ratio denotes the fold increase of pollutants because of hills present in the area.The overall model output for PM 10 , NO 2 and CO for averaging periods are summarized in Table 6.
The net-concentrations including monitored data plus predicted value of PM 10 , NO 2 and CO would be increased from 75 to 77.61 µg/m 3 with an increase of 3.48%, 22 to 26.66 µg/m 3 with an increase of 21.18% and 428 to 538.37 µg/m 3 with an increase of 25.79% respectively.These calculated net-concentrations of PM 10 , NO 2 and CO are found to be within their prescribed Indian standards of NAAQS.
The highest values obtained from the modeling output for PM 10 , NO 2 and CO for each averaging period were compared and found to be below their respective standards of NAAQS.Finally, the model-computed concentrations were superimposed on the monitored data obtained from field survey to calculate the net-concentrations for each pollutant and were compared with their standards.Results suggested that even after consideration of maximum existing pollution levels; the net-concentrations will remain within the limits of NAAQS and thus plant will ensure the compliance of pollution norms.
Table 6.Overall modeling output, monitored GLC and superimposed data with their standards [16].

Pre-Conditions Required for Development of Catastrophe Like Situation
The more complex the situation a model is required to simulate, the poorer its performance is likely to be.However, AERMOD models will handle complex terrain much more realistically than others.Since plant will be commissioned in undulating terrain and surrounded by many hills; AERMOD to ISCST3 were preferred which consider both downwash and non-downwash.The model was run repeatedly for better predictions to visualize a variety of scenarios that may arise due to sudden change or build up of pollutants in the atmosphere during different climatic conditions and also to nullify the erratic output.
It is not possible to gauge the situation under all the unwanted happenings likely to occur could not be possible to gauge the situation in advance through modeling.Since chimney height is less than the heights of surrounding hills, there is a fair chance of trapping of pollutants released from stack within mixing height and not sufficiently dispersed.Moreover, these dispersed air pollutants may strike back after hitting the surface of hills and accumulate in the valley region.There is one such imaginary catastrophe phenomenon which may appear during winter season when the mixing height (110 m) is significantly low and other atmospheric conditions are stable.In worst case, when there is continuous drizzling for a few days with blowing of clammy wind (≤ 0.5 m/s); the atmospheric air parcel may get saturated with water vapour.The densities of pollutants proportionately increase and become heavier than the air.The buoyancy of pollutants decreases and they slowly come down to the earth's surface.Formation of photochemical smog could not be ruled out during the day time when enough sun rays are available.In such a scenario human, flora and fauna will be affected immensely (Figure 8).The possibility of occurrence of such critical circumstances however, is rare because the life cycle of dumping weather remains usually for only 1 to 2 days in this part whereas at least 3 to 5 days is required to form such a worsening situation.If really such a grave situation happens in reality then plant should be shut down for few days.India is a tropical country and Rajasthan's Thar Desert is nearer to project site.Project area experiences a longer summer season followed by monsoon season.Winter season is comparatively short ranging from 2 to 3 weeks during December to January.Hardly, there is any rainfall during winter season therefore, it is expected that the water vapour in the atmosphere is relatively low.Moreover, as the sun rises, the ambient air temperature becomes normal.The average air temperature is about 16˚C which can radiate sufficient energy to disperse the accumulated pollutants/fog developed in the night or during wee hours of the day.

Possible Harmful Health Effects of Pollutants
All the three critical health affecting parameters (PM 10 , NOx and CO) have undesirable, asymptomatic and unmeasurable effects on human and environmental health [14].Entry of pollutants in the human body through inhalation of contaminated air is an important route of exposure [17].It was reported that higher the levels of PM 10 , greater the chances for cardiovascular and respiratory diseases (such as asthma, bronchitis, lung cancer) and increased risk of preterm birth.Human exposure to particulate air pollution has long been identified as a risk factor for human mortality and morbidity and many developed countries have amended and implemented the stringent limits for PM 10 and other pollutants.Nevertheless, the threshold levels of PM 10 at which exposure does not lead to adverse effects on human health have not yet been clearly identified and there is a substantial individual variability in exposure and in the response.It is difficult to establish a particular standard or guideline value that will lead to a complete protection of every individual against all possible cumulative and/or synergistic adverse health effects of fine and ultrafine particles.The effect of fine and ultrafine particles largely depends on the concentration, mass and number, shape and size, load of toxic metals (As, Ni), the composition and concentration of other inorganic and organic pollutants viz.PAHs and bio-aerosols containing pathogenic bacteria, pollen, fungi and various spores [18] [19].
In India, plant burns natural gas which is compared of hydrogen and carbon only.Its produces substantial amount of NOx but it does not emit sulphur dioxide.Normally, nitric oxide (NO), the primary pollutant is discharged by industrial processes and it instantly undergoes chemical reactions in the atmosphere and is converted to NOx.These oxides of nitrogen are the main sources of secondary pollutants of solid aerosols or liquid droplets.Besides, in the lower troposphere, oxides of nitrogen react with other reactive gases and water vapour in the presence of solar energy to form harmful photochemical smog.This smog has often been detected in the urban atmosphere and accumulates in the breathing zone owing to its higher density than air [14].
Carbon monoxide (CO) is a poisonous gas and has 120 times greater affinity than oxygen molecule to bind to haem protein of haemoglobin of red blood cells and produce carboxyhaemoglobin (COHb).This COHb might be the major cause of thrombosis and brain haemorrhage due to shortage of oxygen in brain [20].Unburned/partially burned hydrocarbons (UBHC) and CO are strongly associated for black coughing and eye irritation [11].
Although the concentrations of NOx and CO were found to be below their threshold values; there are numerous studies demonstrating that gaseous pollutants cause respiratory diseases even at low concentrations.It is known that there is a link between NO 2 and the risk of lung cancer [21] [22].

Conclusions
From this modeling study, the following inferences may be affirmed that the plant will release notably low concentration of PM 10 , NO 2 and CO emissions in the surrounding environment.The net-concentration was found to be 77.61µg/m 3 with an increase of 3.48% for PM 10 , 26.66 µg/m 3 with an increase of 21.18% for NO 2 and 538.37 µg/m 3 with an increase of 25.79% for CO from their baseline data respectively.These observed net-concentrations of PM 10 , NO 2 and CO are found to be within the prescribed Indian standards of NAAQS and thus project will certainly ensure the compliance of pollution norms.Modeling results clearly showed that the hills may have a profound impact upon the dispersion of pollutants and the ratio (with hill and without hill) of each pollutant was 3.89 for PM 10 (24 hr), 2.40 for NO 2 (24 hr) and 13.98 for CO (1 hr).We assume that there is a possibility of pollutants building up for a short period in the atmosphere because of surrounding hills during winter.It is forecasted from joint study of field survey and AQM modeling that there might be less chance of fog formation and secondary pollutants viz.photochemical smog and ozone.Predicted results suggest that the intensity of adverse impacts likely to occur due to installation of plant is minimal.
Natural GBPP not only decreases the pollution level but also reduces the hospital treatment costs and protects the public health.We recommend that clean GBPP could be the best alternative for replacement of polluted functional coal power plants located in urban areas which are causing havoc by creating pollution problems (e.g.Indraprastha in New Delhi).

FrequencyFigure 1 .
Figure 1.(a) Wind Rose plots and (b) Histogram of wind class frequency distribution.

Figure 7 .
Figure 7. Isopleth of CO concentration for annual.

Figure 8 .
Figure 8. Schematic effects of hills upon dispersal pathway of pollutants and formation of photochemical smog and its impact on receptors.
[13]AQMs are developed using the mathematical formulae and statistics to measure the atmospheric build up and dispersal of pollutants released from a source.AERMOD modeling software version 6.6 developed by the United State Environmental Protection Agency (USEPA) in conjunction with American Meteorological Society (AMS) has been used for point source emission.It is commonly known as AMS-USEPA regulatory model or AERMOD.It takes into account the terrain topology, boundary layer and meteorological data to model pollutants transport and dispersion to calculate the temporally averaged air pollution concentrations[12][13].

Table 1 .
Model input related to stack, pollutants emission rate and fuel.
9 Emission rate of CO 36.5 kg/hr 10 Emission rate of NOx 99.8 kg/hr 11 Emission rate of SOx Nil (no sulphur in the fuel)

Table 2 .
Land use and geo-physical patterns of the study area.Albedo is defined as the ratio of diffusely reflected to incident electromagnetic radiation.**The Bowen ratio is the mathematical method generally used to calculate heat lost (or gained) in a substance; it is the ratio of energy fluxes from one state to another by sensible and latent heating respectively.direction, ambient air temperature, relative humidity, atmospheric pressure, rainfall, solar radiation, cloud cover, mixing height (the maximum level to which a parcel of air *will rise under a given set of conditions) and others.Auto Weather Station (Envirotech, New Delhi) was set up for collection of meteorological data.

Table 3 .
Effect of ambient air temperature, vapour pressure and relative humidity on pollutants.

Table 4 .
Frequency distribution (%) of wind speed (m/s) and wind direction.