Concentrations in Common Polishing Materials Consumed by Inhabitants in Saudi Arabia

Knowledge of radioactivity present in polishing materials enables one to assess any possible radiological risks to human health. In this work, the radioactivity due to the presence of Ra, Th, K, and Cs has been measured in polishing materials consumed in Saudi Arabia using gamma spectrometry with HPGe. The activity concentrations of Ra, Th, K and Cs ranged from 13.61 ± 0.005 to 0.60 ± 0.002, 18.43 ± 0.003 to 0.78 ± 0.001, 342.59 ± 0.009 to 2.47 ± 0.001 and 1.47 ± 0.001 to 0.55 ± 0.001 Bq/l, respectively. For Ra and K, the highest values are measured in stainless steel polisher. The highest values also measured in metal polisher (copper-chrome) and disinfectant cleaner and polisher sample for Th and Cs. Radium equivalent activity due to the natural radioactivity of the investigated samples ranged from 51.37 to 1.24 Bq/l. This value is less than the recommended values in the established standards. The evaluated data were compared with the literature data. Our results indicate that no significant radiological hazards arise from using investigated samples hence quite safe to be used as polishing materials.


Introduction
Naturally occurring radioisotopes ( 238 Th, 232 U series and 40 K) are the main source of both external and internal radiation exposure in humans, whence the radiation finds its way into building materials, air, water, food, and eventually the human body.Human beings are exposed to external radiation from cosmic rays and terrestrial radiation.exposure to internal radiation [1] [2].According to the report by UNSCEAR, the total exposure per person resulting from ingestion of terrestrial radioisotopes was 0.3 mSv, of which 0.17 mSv comes from 40 K and 0.12 mSv comes from thorium and uranium series.Exposure from inhalation of terrestrial radioisotopes contributes another 0.01 mSv.
Thus, the internal dose of terrestrial radioisotopes can be estimated from the concentrations of natural radioisotopes in foods [3].Internal radiation exposure, mainly affecting various levels of the respiratory tract, is due to the deposition of short lived progeny products of radon, which are exhaled from building material into indoor air [4] [5].Radon ( 222 Rn), a gaseous product of decay of 226 Ra, is extremely important in an indoor exposure.Radon easily diffuses from the ground and building materials to indoor air and is the source of exposing bronchus and lungs [6]- [8].The isotope 137 Cs is produced anthropogenically by several types of nuclear activity, including past testing of nuclear weapons, accidents in nuclear facilities, reprocessing of spent nuclear fuel and nuclear power reactors.All these materials contain some amount of natural radionuclides that cause exposure of people to ionizing radiation.The measurement of activity concentrations of radionuclides in polishing materials is important in the assessment of population exposures, as most individuals spend 80% of their time indoors [9].
Long exposures to low levels of ionizing radiation and poor ventilation of residential buildings can seriously increase health risks to polishing materials [10].Polishing materials have a variety of chemical natures and some of them are toxic to humans and may cause sickness including cancers and death [11].Even nontoxic polishing materials can pollute the land or water.Therefore, care needs to be exercised when using and disposing such materials [12].The present study was undertaken with the purpose of determining natural radioactivity in some polishing materials.The data obtained are essential for the development of standards and guidelines concerning the use and management of polishing materials.

Sampling and Measurements
Twenty-two samples representing commercial species of the most commonly consumed polishing materials were collected from Saudi Arabia local market.They were being used for cleaning and polishing purposes of marble, granite, ceramic, tiles, stucco, brick, porcelain, chrome and metal, houses and vehicles.Weighed samples were stored in standard polyethylene Marinelli beakers of 650 cm 3 volume each.The beakers were tightly sealed for 4 -5 weeks to reach secular equilibrium where the rate of decay of the progeny becomes equal to that of the parent (radium and thorium) [13].Table 1 shows samples description.

Gamma Spectrometric Measurements
The activity concentrations of 226 Ra, 232 Th, 40 K and 137 Cs were measured with gamma-spectrometric system based on HPGe.The samples were counted using a gamma spectrometry (Canberra coaxial-type Model GC2520) with relative efficiency of 25% and resolution FWHM of 0.2 keV for 1332.5 keV gamma-ray peak of 60 Co and a peak to Compton ratio of 50:1.The gamma-spectrometry system consists of HPGe connected to a desk top computer provided with a Canberra multichannel analyzer (MCA) in conjunction with a configuration software for spectrum acquisition and evaluation [14] [15].
The specific activities were averaged from gamma-ray photo peaks at several energies.The gamma-ray lines at 295.2 and 351.9 keV from 214 Pb and at 609.3 and 1764.5 keV from 214 Bi were used to determine the specific activity of 226 Ra.The gamma ray lines of 338.4 keV; 911.2 keV and 968.97 keV from 228 Ac, the 238.58 keV and 727.3 keV from 212 Bi and 583.2 keV from 208 Tl were used to determine the specific activity of 232 Th.The specific activities of 40 K and 137 Cs were measured directly by its own gamma-ray lines at 1460.8 and 661.66 keV, respectively [13].The minimum detectable amount (BDLs) for 226 Ra, 232 Th, 40 K and 137 Cs were 0.312 ± 0.16, 0.340 ± 0.16, 1.660 ± 1.10 and 0.45 ± 0.06 Bq/l respectively.Radioactivity concentrations of each sample were measured for about 23 h.The data acquisition, display and spectrum analysis were carried out using a dedicated software program [16], which enabled also the concentrations of 226 Ra, 232 Th and 40 K to be calculated.The degree of secular equilibrium reached between 226 Ra and 232 Th and their decay products was taken into account during the concentration calculations.

Results and Discussion
The specific activity of 226  P6, P5 and P8 respectively, whereas the lowest average concentrations 226 Ra, 232 Th, 40 K and 137 Cs (0.60 ± 0.0015, 0.78 ± 0.0011, 2.47 ± 0.0005, 0.55 ± 0.0008 Bq/l respectively) were found in samples P3, P17, P15 and P5.The 40 K activity concentration dominated over that of the 226 Ra and 232 Th, as normally happens in samples, while the highest activity level of 40 K (342 Bq/l) which was recorded in sample P5 was lower than that of the global average of 400 Bq•kg −1 [17].
The variation among the activity levels in different samples may be attributed to the pH, and chemical composition of from they derived [18].Some studies present the concentration values of 226 Ra only and do not consider the 238 U presence taking into account the fact that 98.5% of the radiological effects of the uranium series are produced by radium and its daughters [19].
The activity concentrations of Ra, presented here, fall within the range reported by other authors.Both Th and K in this work revealed higher concentration levels compared to those level for painting oxides and paints.However, their levels were lower than in the case of titanium enamel frits (Table 3).According to the recommended reference level of 30, 25 and 370 Bq/kg for 226 Ra, 232 Th and 40 K, respectively, for the world average concentrations published by UNSCEAR [1], it was noted that the obtained results in all samples are lower than the recommended reference level.

Radiological Parameters Radium Equivalent Activities (Raeq)
Uniformity of the distribution of 226 Ra, 232 Th and 40 K in materials with respect to radiation exposure has been described by a common index.This index is called the radium equivalent (Ra eq ) activity and is defined as a weighted sum of the activity concentrations of the above three radionuclides.Ra eq is given in Bq•l −1 to compare the specific activity of materials containing different amounts of 226 Ra, 232 Th and 40 K.It was assumed that 370 Bq•kg −1 of 226 Ra, 259 Bq•kg −1 of 232 Th or 4810 Bq•kg −1 of 40 K produce the same γ-ray dose rates [20]; Ra eq is calculated through the following relationship: 1.43 0.077 where C Ra , C Th , and C K are the specific activities of 226 Ra, 232 Th, and 40 K, respectively, expressed in Bq•l −1 .The maximum value of Ra eq in building materials must be less than 370 Bq•kg −1 for safe use of materials in the construction of buildings [1], to keep the external dose below 1.5 mSv•y −1 [21].The results obtained by us showed that the lowest Ra eq was equal to 1.24 Bq•l −1 in sample P17, while the highest value reached 51.37 Bq•l −1 in in sample P5 (Table 2).All the studied samples showed lower values than the recommended worldwide mean value 370 Bq kg −1 .Thus, every material used to clean and polish of marble, granite, ceramic and tile can be considered to does not reveal a significant radiological hazard.

Conclusion
The activity levels of the natural terrestrial radionuclides as 226 Ra, 232 Th, 40 K and artificial 137 Cs were determined using a gamma-ray spectrometry in 22 samples of polishing materials collected from local stores.The obtained values were, in general, comparable to the corresponding ones obtained from other studies, and they all fell within the average worldwide ranges.Basing on the measurement results, the values of the radium equivalent activities Ra eq were calculated to assess the radiological hazard for inhabitants of Jeddah.The obtained values displayed to be below the permissible limiting values.

Table 1 .
Sample code and their description.

Table 2 .
Ra,232Th, 40 K and 137 Cs, in the samples are shown in Table2.The highest average concentrations of226Ra, 232 Th, 40 K and 137 Cs (13.60 ± 0.0015, 18.43 Average of 226 Ra, 232 Th, 40 K and Ra eq of polishing materials in the current study.
ND: Not detected.

Table 3 .
Comparison of concentrations range of 226 Ra, 232 Th, and 40 K (Bq•kg −1 ) recorded in various polishing materials of several studies.