The Effect of Measuring Magnetic Susceptibility of Water Samples by Starting with Isothermal Remanent Magnetization ( IRM ) before Anhysteretic Remanent Magnetization ( ARM )

Estimating magnetic properties of water samples by first measuring the Anhysteretic Remanent Magnetization (ARM) before Isothermal Remanent Magnetization (IRM) is induced has been costly due to the discard of samples measured by staring with the latter before the former. However, no clear understanding exists on the effect of measuring magnetic properties values by first inducing IRM before ARM. This study explored the effect of measuring concentration related parameters (χlf, χfd and χARM), a mineral related parameter (S−300) and grain size parameters (χfd% and χARM/SIRM ratio) from water samples by starting with IRM before ARM. Forty three surface water samples were collected from the estuarine of Yangtze River (China) with the aim of measuring magnetic characteristics by starting with IRM before ARM. The results indicated that, measuring magnetic properties by either starting with ARM or IRM led to similar values for χlf, χfd, χfd%, χARM, S−300 and χARM/SIRM ratio (p > 0.05). These results imply that, measuring concentration related parameters does not necessarily require measuring ARM first and then IRM. Researchers can start by measuring any parameter between ARM and IRM without affecting the final results of the water samples, but with proper demagnetization when started with IRM. Corresponding author. M. K. Mzuza, S. M. Limbu


Introduction
Measuring magnetic susceptibility is an important aspect in understanding the magnetic properties of water samples.The magnetic properties availed can be used to outline the status of an area such as pollution level and soil contamination with heavy metals [1].Through the use of magnetic properties, it is also possible to trace the source of sediments affecting an area.Magnetic methods using geochemistry and mineral analysis have been utilized in measuring magnetic properties since 1980's [2]- [4].The experimental study of magnetic materials requires a means of producing the field which will magnetize the material and a way of measuring the resulting magnetic effect on the material [5].
The common method for measuring magnetic properties of samples is to first measure the Anhysteretic Remanent Magnetization (ARM) before Isothermal Remanent Magnetization (IRM) is induced into the sample [6].The preference of inducing first ARM revolves around the fact that, ARM is the magnetization which has been left behind in a ferromagnetic material after an external magnetic field is removed.Consequently, the procedure of inducing ARM first and measuring its value using magnetometer then detaching it using an alternating field (a.f) demagnetizer destroys the ARM.This process of demagnetization helps to return the remanence of the sample to zero.In so doing, ARM has been used as a useful laboratory technique for characterizing magnetic properties.
One of the limitations of this method is that many researchers discard samples when they make a mistake by starting measuring IRM before ARM with a fear that results obtained would be wrong.This has been costly to scientists because acquiring samples involves substantial amount of time and money.It has been advised for researchers to continue measuring the IRM and fully demagnetize the samples before measuring ARM [7].However, no clear scientific explanation exists on the effect of measuring magnetic properties values by first inducing IRM before ARM.The aim of this study was therefore to explore the effect of measuring magnetic properties of water samples by starting with IRM before ARM.It was hypothesized that magnetic properties for the parameters measured would have significant different values when estimated by starting with IRM before ARM.

Water Sample Collection and Analysis
Surface water samples were collected from the estuarine of Yangtze River (China) with the aim of measuring magnetic characteristics.The normal procedure was followed: Membrane were numbered then weighted on beam balance.Water sample was filtered using a pump into jug through a plastic pipe.The sediments remained on the membrane was dried at a temperature below 40˚C for 72 hours (3 days).After drying, the membrane was weighed again to determine the weight of the sediments by subtracting the weight of membrane from the total weight of membrane and sediment.Average total number of samples was 43 which included the spring tide and neap tide samples.
Following usual procedure, BartingtonMS2B magnetic susceptibility meter was used to find the low and high magnetic susceptibility.Samples magnetic properties were analyzed at low frequency susceptibility of 0.47 kHz and high frequency susceptibility of 4.7 kHz (χlf and χhf, respectively) [3] [8]- [10].Frequency dependent susceptibility (χfd) was calculated as χfd = (χlf − χhf).IRM was imparted at 1 T and then backfields at −100 mT and −300 mT.Then the samples were demagnetized to zero before ARM was acquired in a 0.04 mT direct current field superimposed on a peak AF demagnetization field of 10 mT and 100 mT [11].

The Process of Demagnetization
The same water samples were then demagnetized to zero.This was done by removing the samples from the sample holder, placing the sample membrane into another polyether paper (shaking) and then placing them back into the sample holder.Then these samples were put into Molspin and demagnetized to zero.The samples were left idle for two months.Thereafter, since the low frequency susceptibility (χlf) and high frequency susceptibility (χhf) were already measured, the next step after demagnetization was acquiring ARM.ARM was acquired in a 0.04 mT direct current field superimposed on a peak AF demagnetization field of 10 mT and 100 mT, and expressed as susceptibility (χARM) by normalizing ARM with dc field.
Isothermal Remnant Magnetization (IRM) was then imparted again at 1 T and then backfields at −100 mT and −300 mT.This was done so that the results can be used for reference to the first IRM which was obtained at the beginning.Concentration related parameters (χlf, χfd, χARM and SIRM), mineral related parameter (S −300 ) and grain size parameter (χARM/SIRM) were calculated to compare the results [2] [3] between samples measured by starting with IRM and those started with ARM.The values of χfd were estimated to reflect presence of fine viscous grains close to the super-paramagnetic (SP)/single domain (SD) boundary [3] [12].The parameter χARM was calculated for sensation of single domain ferromagnetic grains.The ratio of χARM/SIRM was then calculated to show variation trend of magnetic grain size of the samples [2] [3] [11] [13].This was in line with calculations of S −300 , which indicates the mineral assemblage variations between samples and it can be influenced by grain size variation in ferromagnetic minerals with higher SD grains coercivities than multidomain (MD) grains [14]- [16].

Statistical Analyses
Results are presented as mean ± standard error of the mean (SDM) and data were tested for homogeneity of variances using Levene's test to avoid violating parametric test assumptions.After confirming homogeneity, two sample t-test was used to compare the means of χlf, χfd, χfd%, χARM, S −300 , and χARM/SIRM ratio for samples measured by starting with IRM and ARM at 5% level of significance.All analyses were conducted using Statistical Package for Social Science (SPSS) for Windows version 20.

Discussion
The results have indicated similar values for χlf, χfd, χARM, S −300 , χfd (%) and χARM/SIRM ratio between samples measured by starting with IRM and ARM.The similarity in χlf and χfd parameters shows that, the presence of fine viscous grains which were close to the super-paramagnetic (SP)/single domain (SD) boundary was not affected [17].Fine viscous grains remained the same in both samples whether measured by starting with ARM or IRM.This is also applied to χARM which was calculated to estimate the sensation of single domain ferromagnetic grains.Viscous grains are usually very intact in samples in such a way they are not altered by the inducing ARM before IRM [18].These results prove that the sensation was not affected in any way in both cases.These results imply that concentration related parameters may not be affected when magnetic susceptibility are measured by starting with IRM or ARM.The mineral related parameter (S −300 ) was also similar between samples measured by starting with IRM before inducing ARM.This parameter represents the water-rock interaction which plays a vital role for water chemistry in a particular area [19].In general, water chemistry is determined by lithological influences, complex weathering process and ion exchange along with influence of ions from anthropogenic impact [19].These factors are unaltered during measurement by starting with IRM or ARM.The similarity in S −300 indicates that mineral properties of water samples were not altered by either starting with ARM or IRM.Based on the current results, measuring magnetic properties by starting with IRM and then ARM may not affect mineral related parameters.
The values of χfd% and χARM/SIRM ratio were calculated to show variation trend of magnetic grain size of the samples.The similarity in these parameters between the two methods of measurements helps to prove that even magnetic grain size was not affected in any way.This is in agreement with [13] who argued that χARM/ SIRM ratio is commonly used as a grain-size indicator of ferrimagnetic minerals which peaks in the single domain (SD) range and decreases with increasing grain size.Its value remains unaltered when measured by first imparting IRM or ARM.These results imply that, measuring χfd%, XARM and χARM/SIRM ratio do not necessarily require measuring ARM first and then IRM.These results show that the magnetic grain size parameters were the same and were not affected by the change in the method whether starting imparting IRM in samples and then demagnetize before imparting ARM.Researchers can start by measuring any parameter between ARM and IRM without affecting the final results of the samples.
In general, the results have indicated that it is possible to obtain similar values for χlf, χfd, χARM, S −300 , χfd (%) and χARM/SIRM ratio between samples measured by starting with IRM and ARM.However, the experience of this experiment shows that, it is too involving and just wastage of time.In addition, sometimes it is not easy to be sure whether the samples have been completely demagnetized to zero or not.Therefore, to avoid wasting time and making mistakes, it is advisable to start with ARM and then finish by imparting IRM as proposed by [12].However, in case by mistake someone has started imparting IRM before ARM, it is better to demagnetize the samples to zero and then impart the ARM.There is no need to throw away the samples because they can still be used with a caution that they are first demagnetized to zero before ARM measurements are taken.In this way, costs of time and money involved in obtaining samples are not wasted.

Conclusion
This study has shown that it is possible to start imparting IRM to samples before imparting ARM and obtain the same results as long as the samples are demagnetized to zero before imparting ARM.The only challenge is that it is too involving and time consuming.Moreover, the assurance that the samples have been demagnetized to zero is not a grantee.Therefore, it is better to follow the normal procedure of starting imparting ARM and finish with IRM to be assured of correct results.This approach may be helpful to researchers during laboratory analysis, because many researchers discard samples when they make mistakes by starting measuring IRM before ARM fearing that results obtained would be wrong, consequently costing more money to scientists to collect other samples.Thus, the results of this research will help many scientists including those in environmental magnetism.

Table 1 .
The magnetic properties of samples measured by starting with Anhysteretic Remnant Magnetization (ARM) and Isothermal Remnant Magnetization (IRM) during the study period.
All values of the magnetic parameters measured were statistically similar (p > 0.05).