Sauna Technique , Drying Kinetic Modeling and Effectiveness on Solar Drying Compared with Direct Drying in Drying Process of Kappaphycus striatum in Selakan Island Malaysia

A sauna drying technique—the solar drier was designed and imposed, constructed and tested for drying of seaweed. The seaweed moisture content was decreased around 50% in 2-day sauna. Kinetic curves of drying of seaweed were known to be used in this system. The non-linear regression procedure was used to fit three different drying models. The models were compared with experimental data of red seaweed being dried on the daily average of air temperature about 40 ̊C. The fit quality of the models was evaluated using the coefficient of determination (R2), Mean Bias Error (MBE) and Root Mean Square Error (RMSE). The highest values of R2 (0.99027), the lowest MBE (0.00044) and RMSE (0.03039) indicated that the Page model was the best mathematical model to describe the drying behavior of sauna dried seaweed. The percentage of the saved time using this technique was calculated at 57.9% on the average solar radiation of about 500 W/m2 and air flow rate of 0.056 kg/s.


Introduction
Seaweed has been given much more concern because of its high nutritional value [1] and its short-term growth that is only 45 days per cycle [2].Seaweed is mainly cultivated in Sabah due to its suitability like environmental and geographical factors compared with peninsular Malaysia [3].In addition, Malaysia lies entirely in the equatorial region.On average, Malaysia receives 4.21 to 5.56 kWh/m 2 of solar radiation a year.ETP focus is mainly to transform the system in seaweed to make it one of the industries, which is also competitive, standardized and independent like other agriculture sectors [4].It also will provide a lot of job opportunities for the people in Sabah, decrease the poverty of pupils especially in west coast of Sabah and increase of farmers' household income.Moreover, it also will attract investors to come and invest in our country.
According to [5], the main extraction from seaweed is because of its carrageenan.The carrageenan is used in human food and non-food, pet food, cosmetics, meat binders and etc. [6].East ASEAN Growth Area (BIMP-EAGA) mentions that the world demand of carrageenan from seaweed will increase to 80% by the year 2020.Traditionally seaweed is dried in open sunlight.Drying of seaweed by using hanging method in an open area or on a wooden platform depends on the weather, large open space areas and long drying time and has low product quality and other contaminations [7].The weaknesses of direct drying affect the income of the farmers and make the payment delay [8].It is necessary that the period of drying be decreased without affecting the quality of the seaweed [9].
Several experimental and theoretical studies have been reported on the development of various types of solar drying system for agricultural and marine products [10].Recently, many researches on experimental studies and mathematical modeling have been widely and effectively used for analysis [11]- [16].Although many mathematical models have been proposed to describe the drying process, a limited number of reported studies are on mathematical models of drying behaviors of seaweed and it seems that no work is done to do sauna on seaweed as pre-treatment to decrease the period of drying without affecting the quality of the carrageenan.
This study is conducted to explain novelty of the sauna process, to propose thin layer solar drier model of seaweed after sauna process (Kappaphyccus striatum variety Sacol) under climatic condition of Malaysia and compare the drying period with traditionally drying.

Material
The seaweed (Kappaphyccus striatum variety Sacol) used in this study was obtained from PELADANG association in Semporna, Sabah as shown in Figure 1.The initial moisture content of seaweed was determined by measuring the initial and final weight.Then, it calibrated with oven drying method at the temperature of 115˚C in order to obtain constant weight.Average initial moisture content obtained was 92.68% [17].

Sauna Technique and Experimental Procedure
Experiment was done between 8:00 am and 5:00 pm from 19/3/14 until 22/3/14 in Selakan Island, Malaysia.On the 17/3/14, 5 tons fresh seaweed was harvested with the seaweed complete one cycle of cultivation (45 days).After determining the initial weight, the fresh seaweed was closed tightly using white anti UV-plastics as shown in Figure 2.This is the sauna process which the seaweed sample will change the color from natural color to the whitish.The next day around afternoon, the plastic opened to flip over the seaweed so that equal formation of the whitish seaweed formed.Then, the plastic was closed tightly again.The seaweed was undergoing the sauna process for 48 hours as shown in Figure 3 and Figure 4. On the second day, the plastic was open and throw away all the water inside plastic and all the sample was wash using sea water went through sauna process.The main objective of sauna is to reduce the moisture content to 50%.The remaining about 2.5 tones after sauna was arranged in the Green V-Roof Hybrid Solar Drier (GVRHSD) with same depth and surface area for the drying process as in Figure 5. On the same day, around 5 tan of fresh seaweed are bought to compare the drying period and effectiveness of sauna technique.ature, relative humidity), radiation intensity, and air velocity.For ambient relative humidity and temperature, we used hygrometer.Air temperature was measured by T-type thermocouple, and the intensity of solar radiation was measured using pyranometer.The moisture loss was determined by means of a digital balance which having an accuracy of 0.01 g [18].Mathematical modeling of drying curves.
The moisture content was expressed as a percent wet basis.The experimental drying data for red seaweed were fitted to the thin layer drying models in Table 1, the moisture ratio (MR) can be calculated as [19] 0 where, M e = Equilibrium moisture content; M 0 = Initial moisture content; The moisture content of materials (M) can be calculated by two methods on the basis of either wet or dry basis using the following equation.

Results and Discussion
During the four days of experiments, the variations of the solar radiation (S), ambient temperature (Ta), and average relative humidity of ambient (Ha) are shown in Figure 6 and Figure 7. From these figures, the daily mean of the drying air temperature, relative humidity of drying and solar radiation range from about 35˚C -40˚C, 32% -80%, 100 -1100 W/m 2 , respectively.During the 4-day drying, the daily averages of relative humidity at the drying were obtained in range 43% to 45%.About 2500 kg of sauna seaweed and 5000 kg of fresh seaweed are being dried under the sun, drying of sauna seaweed takes two days to reduce the initial moisture content of 96.28% to 35%, equivalent to 2500 kg to 281.5 kg while drying sauna directly will consume about 4 days to produce the dried seaweed about 560.3 kg from fresh of 5000 kg seaweed.During the two days drying for sauna, the daily averages of air temperature at the drying platform were 45˚C and 50˚C and average solar radiations 453 and 562 W/m 2 at mass flow rate 0.0536 kg/s, as shown in Figure 6 and Figure 7.The efficiency of saving time about 22 hour using the sauna technique is with the percentage of 57.9%, as shown in Figure 8 and Figure 9.
The kinetic curve of both the drying technique was studied.The sauna and direct drying at two conditions were decreased moisture content and drying as shown in Figure 10.Drying curve for both of the technique can also show the profile change in moisture content (X) versus drying time (t), as shown in Figure 11 and Figure 12.The drying kinetics for both of the technique can be accurately predicted using Newton's model, logarithmic model and Henderson and Pabis model (Gupta et al. [25]).Azoubel et al. [26] reported that Page model clearly improved the simulation in comparison with the results obtained using the diffusion model, having the best fit to the experimental data, with calculated average error ranging from 1.89% to 12.76% and R 2 values greater than 0.99.Page model has shown a better fit than other models at accurately simulate the drying curves of chili pepper [27], rapeseed [28], green beans [29], okra [30], kiwi [31] among others.
Page's equation can also be written to the equation ( )  Drying models were fitted with the experimental data of drying in the form of changes in moisture content              On the other hand, as far as the drying behavior of lemon grass is concerned, the Newton's model showed a better fit to the experimental data among other semi-theoretical models.Comparison of experimental MR with predicted MR from models drying.The distribution of experimental values in the vicinity of the straight line shows the expected value of Page model, as shown in Figure 14.

Figure 2 .
Figure 2. Fresh seaweed put inside the plastics.

Figure 3 .
Figure 3. Plastics being dried under the open sun.Then the tray arranged into the open sun.Number of samples was selected with same amount and put in the different places in the tray.The purpose was to study the drying kinetics in drying time of samples.During the drying experiment, the weather was sunny overall.The data measured include air temperature (ambient temper-

Figure 4 .
Figure 4. Photograph of sauna seaweed after one day.

Figure 5 .
Figure 5. Photograph of sauna seaweed in solar drier.
MR = a exp(-kt) where, w(t) = mass of wet materials at instant t; d = mass of dry materials.The values of the coefficient of determination (R 2 ), Mean Bias Error (MBE) and Root Mean Square Error (RMSE) were used to determine the quality of the drying model.The highest R 2 values and the values of MBE and the lowest RMSE were selected to estimate if the drying curve is the best [21] [22].

Figure 7 .
Figure 7. Temperatures & relative humidity of ambient.Listen Read phonetically Equation (8) is the relationship

Figure 8 .
Figure 8. Drying curve: wet basis moisture content versus drying time.

Figure 10 . 2 - 4 .
Figure 10.Drying curve: dry basis moisture content versus drying time.versus drying time.In these drying models, changes in moisture content versus time calculated using Excel software.Fitting some of the drying model has been done with the experiment data, as shown in Figures 11-20.The values of R 2 , MBE, RMSE and the parameters a, n and the constant k for the different models were listed in Tables 2-4.The highest value of R 2 and lowest value of MBE and RMSE indicated the goodness of the fit.Results presented in Table4showed the model from sauna dried seaweed of the Page model has the highest value of R 2 (0.99027), as well as the lowest values of MBE (0.00044) and RMSE (0.03039), compared to Newton's model and Henderson and Pabis model.Accordingly, the Page model was selected as the suitable model to represent the thin layer drying behaviour of sauna dried seaweed.This is in accordance with Fudholi et al.[15]-[17] that Page model was shown to be a better fit to drying seaweed among other one-term exponential models thin layer drying models.

Figure 15 .
Figure 15.Plot of ln MR sauna versus drying time (Henderson and Pabis model).

Figure 16 .
Figure 16.Comparison of experimental MR sauna with predicted MR sauna from Page model.

Figure 19 .
Figure 19.Plot of ln MR direct versus drying time (Henderson and Pabis model).

Figure 20 .
Figure 20.Comparison of experimental MR direct with predicted MR direct from Henderson and Pabis model.

Table 2 .
Constants value fitting of the sauna drying models.

Table 3 .
Constants value fitting of the direct drying models.

Table 4 .
Best fitting different drying technique models.