Recent Applications of Electrocoagulation in Treatment of Water and Wastewater — A Review

During the last two decades, and particularly during the last few years, the environmental sector has shown a largely growing interest in the treatment of different types of water and wastewater by electrocoagulation (EC). The aim of this work was to review studies, conducted mainly during 2008-2011, on the wide and versatile range of feasible EC applications employed in the purification of different types of water and wastewater. The EC applications discussed here were divided into 7 following categories: tannery, textile and colored wastewater; pulp and paper industry wastewater; oily wastewater; food industry wastewater; other types of industrial wastewater; surface water as well as model water and wastewater containing heavy metals, nutrients, cyanide and other elements and ions. In addition, this paper presents an overview of the optimum process conditions (treatment times, current densities, and initial pH) and removal efficiencies (mostly high) achieved for the EC applications discussed. In the vast majority of the studies discussed in this review, the aforementioned values were found to be in the range of 5 60 min (typically less than 30 min), 10 150 A/m and near neutral pH, respectively. Both operating costs and electrical energy consumption values were found to vary greatly depending on the type of solution being treated, being between 0.0047 6.74 €/m and 0.002 58.0 kWh/m, but in general they were rather low (typically around 0.1 1.0 €/m and 0.4 4.0 kWh/m).


Introduction
Electrocoagulation (EC) is an emerging technology that combines the functions and advantages of conventional coagulation, flotation, and electrochemistry in water and wastewater treatment.Each of these fundamental technologies has been widely studied separately.However, a quantitative appreciation of the mechanism of interaction between these technologies employed in an electrocoagulation system is absent [1].
EC has been known for over a century.Aluminium/ iron-based electrocoagulation was patented in the US already in 1909.EC was studied extensively in the latter half of the 20th century in both the US and the Soviet Union (former USSR), but at that time it was not found to be widely feasible for water treatment.This was mainly due to the then high electricity and investment costs [2].
Meanwhile, the demand for quality drinking water quality is increasing globally and environmental regulations regarding wastewater discharge are becoming increasingly stringent.Therefore, it has become necessary to develop more effective treatment methods for water purification and/or enhance the operation of current methods.This and eco-friendliness have led to increasing global interest in electrocoagulation as a research subject.Over the course of the last few decades, literature in the environmental sector has indeed shown a growing interest towards the treatment of different types of wastewater by EC.Particularly during the last few years, the amount of published literature on EC applications seems to have increased substantially.
Practical review papers on EC applications have been largely absent so far.To the best of our knowledge, only a few authors, e.g.[3,4] have addressed the subject recently, in addition to older reviews, (namely [1,2,5]), even though a significant number of studies on EC have been reported in the literature since then.Therefore, there is a need for an update on recent applications of EC.The aim of this work was to accomplish this, and based on the literature, to present an overview of practical optimum treatment times, current densities, electricity consumption, and operating costs in a wide and versatile range of feasible applications of EC in water and wastewater treatment, studied mainly during the years 2008-2011.

Principles of Electrocoagulation
Electrolysis is a process in which oxidation and reduction reactions take place when electric current is applied to an electrolytic solution.Electrocoagulation is based on dissolution of the electrode material used as an anode.This so-called "sacrificial anode" produces metal ions which act as coagulant agents in the aqueous solution in situ [1].At its simplest, an electrocoagulation system consists of an anode and a cathode made of metal plates, both submerged in the aqueous solution being treated [3].The electrodes are usually made of aluminum, iron, or stainless steel (SS), because these metals are cheap, readily available, proven effective, and non-toxic.Thus they have been adopted as the main electrode materials used in EC systems [6,7].The configurations of EC systems vary.An EC system may contain either one or multiple anode-cathode pairs and may be connected in either a monopolar or a bipolar mode [3].During EC, the following main reactions take place at the electrodes.Anodic reactions [2]:       Ferrous iron may be oxidized to Fe 3+ by atmospheric oxygen or anode oxidation, and may be considered as [8]:     Cathodic reactions [2]: Additionally, when chloride is present and the anode potential is sufficiently high, the following reactions may take place in the EC cell [9]: HClO H OCl The formation of active chlorine species (Cl 2 , HClO, OCl -) enhances the performance of the EC reactor through oxidation reactions.The dissolution of the anode metal is based on Faraday's law: where I is the applied current (A), t s is the treatment time (s), M is the molar mass of the electrode material (M Al = 26.982g/mol, M Fe = 55.845g/mol), z is the valency of ions of the electrode material (z Al = 3, z Fe = 2), and F is Faraday's constant (96485 C/mol).It has been found that the theoretical amount of anodic dissolution is exceeded in real EC applications.This phenomenon is referred to as superfaradaic efficiency, and the experimental values of anode metal dissolution have varied between 105% and 190% of the theoretically expected value [10][11][12][13][14][15].This phenomenon is thought to be attributed to pitting corrosion, especially in the presence of chlorine ions [2].
Electrochemically generated metal cations will react spontaneously, forming various monomeric species such as Al(OH) 2+ , Al(OH) 2+ , , and Al(OH) 4  [17][18][19].The formation of these complexes depends strongly on the pH of the solution.Above pH 9, Al(OH) 4− and Fe(OH) 4− are the dominant species [20].Aluminum and iron hydrolysis products then destabilize pollutants present in the solution, allowing agglomeration and further separation from the solution by settling or flotation.Destabilization is achieved mainly by means of two distinct mechanisms, i.e. 1) charge neutralization of negatively charged colloids by cationic hydrolysis products; and 2) "sweep flocculation", where impurities are trapped and removed in the amorphous hydroxide precipitate produced.Several factors such as pH and coagulant dosage have an impact on the relative importance of charge neutralization and sweep floccula-surfaces bring about electroflotation by adhering to agglomerates and carrying them to the water surface [21].
The most important factors influencing the efficiency of dvantages of EC over conventional coagulation (C

Evaluation Principles
presented in Chapters 3.1 -the EC process are the electrode materials used, applied current density, treatment time, and solution chemistry, including initial pH and the chemical composition of the aqueous solution being removed.The solution temperature, type of salt used to raise conductivity, presence of chloride, electrode gap, passivation of the anode, and water flow rate also have an impact on the removal efficiency and economic durability of a given EC application.
The a C) include economic aspects (relatively low investment, maintenance, energy, and treatment costs), significantly lower volume of sludge produced, better sludge quality (lower water content, much larger and more stable flocs with better settlability), similar or slightly better efficiency, avoidance of chemical additions, ease of automation, simple equipment and compact size of EC systems (allowing decentralized treatment), greater functional pH range and pH neutralization effect, and the presence of electroflotation (EF) [5].
The removal efficiencies (R%) 3.7 have been calculated with the Equation (11): where c 0 and c 1 are pollutant concentrations before and c c  after EC treatment, respectively.Hydraulic retention times (HRT, min) were calculated with Equation (12): where Q is the flow rate (l/min).Current densities (i, A/m 2 ) can be calculated with the Equation (13): where A eff is the effective, submerged area of the anode (m 2 ).When no current density values were given by the authors, either the current or voltage value in optimum conditions is presented in Tables 1-7.The electrical energy consumption (EEC, kWh/m 3 ) presented in Chapters 3.1 -3.7 has been calculated with the Equation ( 14): 60 where U is the applied voltage (V), t is the treatment time (15) where a and b are the current market pric (min) and V is the volume of the treated water (dm 3 ).Operating costs (OC, €/m 3 ) have been calculated with the Equation (15): es of electricity (€/kWh) and electrode materials (€/kg), respectively, and EMC (kg/m 3 ) is electrode material consumption.The market prices used in calculating economic value have varied slightly from one paper to another, depending on the country and year of publication (prices have been on the rise over time), but they have been within a very similar range.Derived from Equations ( 14) and (15), EEC and OC per kg of specific pollutant/parameter (kWh/kg x and €/kg x ) can also be readily calculated based on the removal percentage and initial/final concentrations of the pollutant.These values have been presented also by some of the authors.The pH values presented in Ta- bles 1-7 represent the range in which the EC application performed the best (the highest value is marked in brackets), even though the process would have performed nearly as well with pH values outside of this range.If the natural pH of the aqueous solution was inside this range, it has been noted separately.
In a handful of papers, the author did not present economic values and current densities in optimum conditions, but they could be approximated by using the values (total submerged anode surface area, applied current and voltage or current density, volume of the wastewater treated, treatment time, initial concentration, removal efficiency, etc.) given in the article.It should be strongly underlined that these rather simple calculations were done only when the authors of the corresponding papers had not presented the numbers themselves but had clearly stated the values needed for the calculations, or when the values could be easily deducted from the publication in question.The approximation calculations were based on Equations ( 11) and ( 13)- (15).Current market prices were estimated to be approximately 0.10 -0.11 €/kWh (in Finland in July 2011, including electrical energy, distribution of electricity, and taxes) and 1.6 -1.7 €/kg for aluminum and 0.33 -0.37 €/kg for iron.These values are also similar to those used in the reviewed papers.All currencies (usually United States dollar) given in the papers for OC values have been converted to euros (in Tables 1-7) using up-to-date exchange rates.
Additionally, in some articles all the optimum values were not clearly stated or no specific values were given.In such cases, the missing values have been estimated, if possible, and if the results were reasonable and in line with the text.Estimations were based on the figures, tables, and text presented.Also, in a few papers additional optimum parameters were taken into account, meaning e.g. that when a major drop in treatment time, current density, or EEC-value was found to correspond with only a slight reduction in removal efficiency, the lesser removal efficiency (and corresponding other) values were also considered optimal in economic terms.Whenever any of these actions have been performed, it has

Wastewater Recently Treated
Chapters 3.1 -3.7 present a summary of recent applicans of EC with different types of water and waste d into categories by economic values and essential operational parameters in optimum process conditions are presented in Tables 1-7 along with other specifications (i.e.electrode materials, genuineness/artificiality and initial pollutant levels of the water, reactor type, volume of water treated, electrode gap) of the research in question.If multiple electrode materials were tested, the optimum values presented are for the electrode configuration found best (if any), which is noted in the corresponding columns in Tables 1-7.

Tannery, Textile and Colored Wastewater
The global tannery industry represents an important ec nomic sector in many countries.The quantity of efflue generated is about 30 l for every kilogram of hide or sk processed and it contains high concentrations of organic pollutants and Cr (III), which could be oxidized to highly toxic and carcinogenic Cr (VI) [22,23].
Dye-containing wastewaters are a major environmental concern because of their unaesthetic nature and their ability to hinder the penetration of hich is detrimental to living organisms in bodies of water [24,25].Azo dyes are one of the most widely used synthetic dyes.They can be toxic and mutagenic to aquatic life and are molecularly stable, rendering them resistant to biological and even chemical degradation [24].Table 1 presents a summary of recent applications wastewater from a tannery plant using the EC technique.A bench-scale system with iron electrodes was employed.The wastewater had high initial pollution parameter levels (see   .After optimization, the EC treatment was found v gure 1).The natural pH of the wastewater (7.0 -8.7) was found to be within the optimum range of values.The EEC and OC values were found to be low, 0.13 kWh/m 3 and 0.25 €/m 3 , respectively.Parallel monopolar connections were found to be more suitable for the treatment process than monopolar serial and dipolar parallel connection modes [11].Another investigation compared EC and EF (Electro-Fenton process -the addition of H 2 O 2 to an EC process to bring about oxidation reactions) in treating genuine, highly polluted tannery wastewater [26].It is worth mentioning that treatment of tannery wastewater by conventional biological methods is often inadequate for complete purification, especially of ammo-  removed were taken as the system responses, while current density, initial pH, and treatment time were the input parameters [28].
A batch EC system with Al electrodes was proposed for decolorizing synthetic azo-dye-containing industrial wastewater.Direct Red 81-dye concentration was measured using ultraviolet-visible spectrophotometry (maximum absorbance at wavelength I max = 522 nm).It should be noted that this procedure was also used to estimate dye concentrations in other works presented in Table 1 when synthetic dye solutions were used, employing relevant maximum intensities.In this study, however, four su hydrogen yields were compared, de choice because of its possibility to fo designed properly.EC was found more ef uded to be promising in treating azody pporting electrolyte types were compared; of these, NaCl showed the best performance.This was suggested to be due to Cl − anions destroying the passivation layer formed on the aluminum electrode, leading to a greater rate of anodic dissolution.A decolorization rate of 98% was reached in optimum conditions [29].
Two different types of synthetic dye effluents were prepared and treated with an EC apparatus working in a continuous upflow mode.This EC system also applied a hydrogen gas collecting system.The dyes used to prepare the wastewater were azo-based Direct Red 23 and Reactive Blue 140.In Table 1, the first number presents the wastewater containing Direct Red 23; the latter is the wastewater with Reactive Blue 140.Experimental and theoretical maximum noting 89% -94% efficiency in the gas collecting system.The results showed that the energy yield of harvested hydrogen (converted to electricity for the EC process with an assumed efficiency of 50%) could reduce the EEC-value of the EC process by 13% and 8.5% for Direct Red 23 and Reactive Blue 140 solutions, respectively.It was also stated that the high-quality hydrogen collected could also have been saved for use as a reactant in industrial processes.Decolorization rates of 99% and 89% for a 5-min EC-run applying a current density of 30 A/m 2 and 40 A/m 2 were found to be the optimum conditions for the Direct Red 23 and Reactive Blue 140 solutions, respectively.EEC-values were found to be low and the OC of the EC system was calculated as being less than 0.12 €/m 3 [30].
A typical textile effluent may have fluctuating properties because it contains various types of dye molecules.Therefore, a study was set up to investigate the decolorization of two different dyes (Reactive Blue 140 and azo-based Disperse Red 1) and a mixed dye made of them.Real textile wastewater was also treated with the same batch-EC system.All three synthetic wastewaters had results very close to each other (both EEC-values and removal efficiencies, which showed complete decolorization), therefore their values are given as their approximate averages in Table 1, followed by the results for real wastewater.Three different electrode configurations were tested, of which iron electrodes proved to be superior.The same optimum parameter values that were used for the synthetic dyed wastewaters prior to it were also used for the treatment of real wastewater, thus these values might have not been optimal for it.Of the five EC tests run in these conditions, one seemed to have failed (it was not in line with the others) and was therefore ruled out [31].
A batch EC system was employed to treat a synthetic crystal violet (CV) solution.Na 2 SO 4 was used as the support electrolyte in this work, which claimed that NaCl was a controversial rm organic chlorine by-products.In this study, a twolevel full factorial experimental design (2 k ) was employed to evaluate decolorization of the CV wastewater by EC.The levels of four variables (initial pH, CV concentration, supporting electrolyte concentration, current density) were studied.Reduced empirical models for both Al and Fe anodes were proposed for CV removal with EC.The correlation percentages were 96% and 83% for Al and Fe anodes, respectively.Iron was found superior to aluminum in this application, and residual amounts of less than 1 mg/l of iron were detected after an optimal 5-min EC run, while color and COD were fully removed [32].
A comparison of EC and EO (electro-oxidation) in treating Acid Green dye 50-based synthetic wastewater was done.Both processes were carried out in novel cathodic H 2 -gas-stirred batch reactors.This was proposed to reduce the capital and operating costs of the reactor by making mechanical stirring unnecessary, provided that the EC cell is ficient: in optimum conditions, practically complete decolorization and a COD reduction of 87% versus 68% were accompanied by clearly lower energy consumption than what was achieved with EO.However, it was concluded that further studies on different types of dyes are needed to confirm this [33].
EC was employed to remove Acid Brown 14 from an aqueous solution by bench-(500 ml) and pilot-scale (9000 ml) batch processes.This type of dye was chosen because of its high level of usage in the textile industry.Aluminum was found superior to iron as the anode material for this application.Rather low values of current density (6.329/2.58A/m 2 ) were found optimal for the batch-and pilot-scale systems, leading to very low EECvalues (0.053/0.037 kWh/m 3 ) while achieving substantial removal efficiencies for COD and color.The EC process was concl e-containing wastewater [34].Optimization of Acid Red 14 azo dye removal by a batch-EC (Fe/steel electrodes) process with RSM was performed.Evaluation was based on the simple and combined effects of three main independent parameters: current density, treatment time, and initial pH of the wastewater.The study showed clearly that RSM was suitable for optimizing the EC process operating conditions and maximizing dye removal (91.27% in 4 min, whereas 93.93% in 4.47 min was predicted by the model, see Figure 2).A high coefficient of determination (R 2 = 0.928) ensured satisfactory adjustment of the model derived from the experimental data [35].
iron used as the electro .Generation of gr etrimental and lim /l.Optim A continuous EC system with a 450-ml electrolytic cell bearing aluminum electrodes was utilized in treating synthetic wastewater polluted with azo-based Orange II dye.In this experiment, it was found clearly evident that when operating in optimum conditions (near-neutral initial pH, 350 ml/min flow rate, 4 g/l added NaCl), the color of the dye solution had almost completely vanished.The EC apparatus was summarized to be simple to design and operate and is an inexpensive tool for treatment of dye-containing textile wastewater [36].
Treatment of other artificially colored wastewater by batch EC was investigated, with de material due to its clear superiority over aluminum here.The dye used in the experiments was azo-based Reactive Black 5, which was chosen because of its extensive annual consumption rate.Complete decolorization of 100 mg/l initial dye concentration was achieved rapidly in 5 min, by adding of 3 g/l NaCl and applying a current density of 45.75 A/m 2 .Optimal initial pH was found to cover a broad range of pH values [12].
An Indigo Carmine (Acid Blue 74)-based aqueous solution was treated with a batch EC system employing mild steel/SS electrodes.The gap between the vertically positioned electrodes was only 3 mm een iron(II) hydroxide into the solution changed its color from dark blue to dark green and further to yellow brown.At the end of the EC process, stirring was halted and sedimentation and flotation occurred, and a removal efficiency of 96% was achieved in optimal conditions.The observed color change during the EC process is depicted in Figure 3.A wide range of initial pH values were found to be suitable for this application.It was also shown that controlling pH (preventing it from rising by acid addition) during the EC process was d ited the development of flocs, at least in this case.NaCl was proposed as a better choice than Na 2 SO 4 as a supporting electrolyte [37].
A red dye solution of 2-naphtoic acid and 2-naphtol was treated with Al-EC in a continuous mode.The reactor consisted of two compartments, the first being the actual electrolytic cell and the second a settling compartment filled by overflow from the first one.The initial COD value of the solution was 2500 mg/l when the total concentration of the dye mixture was 100 mg dye al results were achieved with a 14-min residence time (of which only 5 min in the EC compartment), resulting in 95% dye removal efficiency and a 3.2 kWh/m 3 EECvalue.The EEC-value could still be halved by increasing the conductivity of the water by adding NaCl, but this led to a slight reduction in removal efficiency.The high performance of EC in a continuous mode in removing this type of dye from wastewater was proven in this pa-per [38].
To summarize, EC treatment of tannery, textile, and colored waters has been under extensive development in recent years, with promising results.Wide research has been done in this field in addition to the studies presented in Table 1; e.g.those published in [8,25,[39][40][41][42][43].

Pulp and Paper Industry Wastewater
The pulp and paper industry is one of the major waterintensive chemical process industries, contributing significantly to environmental pollution, e.g. in the form of black liquor organic load, suspended solids (mainly fibers), COD, and BOD (biological oxygen demand) are characteristic of effluents from pulp and paper industry.Arsenic may also be present.The strong color of the wastewater derives mainly from polymerization between lignin-degraded products and tannins.The drawbacks associated with conventional treatment techniques have made it necessary to develop more effective methods for treating this type of wastewater.Table 2 presents a summary of recent applications of EC in the treatment of pulp and paper industry wastewater [44].
Genuine black liquor wastewater with a high conce tration of po of 12 was roving being removed.However, aluminum was sl The paper mill effluents from a modern bleached kraft centra-st was also conducted in a se co the tissue paper industry was treated by

3.
. Blackish color, high amounts of nllutants and a high pH value treated with a batch EC system.The main characteristics of the wastewater before treatment are presented in Ta- ble 2. Repeatability tests were performed under the same experimental conditions.A relative standard deviation R.S.D) value of less than 3% was achieved, p ( good repeatability of the EC process.Aluminum and iron were very close to each other in efficiency with different pollutants ightly better overall and was chosen as the optimum.Also, Fe electrodes caused the water to turn green at first, and then to yellow and turbid due to Fe(II) and Fe(III) species generated, whereas the resulting effluent treated with Al was found very clear and stable [45].mill were utilized in an EC study.The lignin con tion of the pretreated, brown effluent was extremely high, 13514 mg/l.All experiments were repeated twice, and the experimental error was approximately 4%.Aluminum was found superior to iron as the electrode material.The effect of initial pH was not studied in this work (the near-neutral original value was used).The high EECvalue of COD compared with that of lignin is related to its significantly lower initial concentration in the wastewater.The results of this study were found to suggest that EC is an effective alternative in paper mill effluent treatment [46].
Pre-treated wastewater from another paper mill with color, pH, and COD similar to those in the previous study was treated by EC in a batch mode.The wastewater was constantly circulated in the EC system with a peristaltic pump.A settling te parate 46-cm-high glass column at the end of the test.All tests were done in triplicate.No clearly superior single electrode configuration could be found here, considering all aspects.Aluminium had somewhat better removal efficiency (except for lignin) than Fe, but the flocs it produced were clearly weaker in quality (SVI index values of 0.081 -0.091 l/g and 0.207 -0.310 l/g for Fe and Al, respectively) and more difficult to handle.The research group concluded that they will therefore use Fe in their consecutive studies.However, Al was chosen as the optimum here based on raw efficiency numbers.EC was proposed as a very effective tool for treating wastewater of the paper industry [47].
Highly polluted paper mill wastewater was treated by EC.No clearly superior single electrode configuration uld be found of the four that were tested.Using Fe caused color reduction to be only 62%, and when using Al, COD and phenol reductions were 77% and 91%, respectively.Hybrid electrodes were the most constant in every parameter investigated, with results between those of Al and Fe.It should be pointed out that the optimum current density suggested (700 A/m 2 ) was the highest one presented in Table 2 and significantly higher than in other studies.It was found that the water could be purified optimally directly without pH adjustment.After duplicating all tests, the experimental error was found to be below 4% [48].
Wastewater from EC with an aim to obtain water quality acceptable for reuse.Real wastewater with high pollution levels (see Table 2) was employed.A scale-up system of the Albatch EC process was also tried, with similar efficiencies and EEC-values.The results showed that a separation gap of 10 mm produces a faster build-up of sludge between electrodes.However, it yields more efficient removal of turbidity and lower energy consumption than larger gaps.EC was concluded to have proven to be an efficient method for removing turbidity from this type of wastewater, producing water of quality (8 NTU) suitable for reuse in the paper bleaching stage [10].
In addition to the studies presented in Table 2, at least [44,49,50] have also recently contributed to EC research in this particular sector.On the whole, treating paper industry wastewater by EC seems to be a feasible alternative and a subject of interest.

Oily Wastewater
Oily wastewaters with greatly varying compositions and very high pollutant levels are generated by various sources, such as petroleum refineries, discharge of bilge alues for a MP configugnificantly lower than those of eductions were found type of wastewater [64].
An industrial waste emulsion containing fluorescent penetrating oil used in aeronautics was treated with EC using Al electrodes.The parameters shown in Table 3 are for the industrial-scale EC system only, as in this study a successful two-step scale-up (from a batch mode laboratory system to continuous pilot-and industrialscale systems) of the EC process with very similar performance parameters was conducted.The values given for the aforementioned EC process in Table 3 were ones achieved after additional sand and carbon filters, which contributed approximately 5 -10 additional percentage points to removal efficiency.In this study, the industrial-scale system used utilized an innovative partial re-circulation of sludge supernatant (see Figure 4 for a presentation of the EC process pilot prototype), which was found to enhance coagulation (increasing removal efficiency) without increasing the EEC-value and to diminish the sludge generation rate.This phenomenon was proposed to be due to introduction of a basal quantity of and ballast water, workshops, petrol stations, rolling mills, restaurants, edible oil and soap factories, as well as other general industrial sources.Oil-in-water can be found as free-floating oil, as an unstable oil/water emulsion, and also as a highly stable oil/water emulsion, which are all difficult to treat [7,51].
Sunflower oil refinery wastewater with a natural pH value as low as 1.4 and COD as high as 15000 mg/l was treated in a batch EC reactor with aluminum electrodes.Na 2 SO 4 and PAC (poly aluminum chloride) were added to the water to increase its conductivity and enhance coagulation.The addition of 0.5 mg/l PAC raised the removal efficiency of COD from 94.5% to 98.9% in optimum conditions (see Table 3).A significant initial pH adjustment to 5 -7 was found to be required for optimal functionality.The treated effluent was very clear and its quality exceeded the local direct discharge standard and therefore EC was found very efficient in treating this omising results, which shows that there is a high interest in EC research in the field of oily wastewater purification.
A synthetic industrial oil-in-water emulsion was prepared and treated with EC.The original oil concentration of the emulsion was 5%, which corresponded to extremely high COD and turbidity values of 62300 mg/l and 29700 NTU, respectively.Nevertheless, very high RSM-optimized removal efficiencies of 90% for COD and 99% for turbidity were achieved in less than 22 min with ANOVA showing a high variance coefficient (R 2 = 0.998), ensuring satisfactory adjustment of the model with the experimental data [62].
Purification of oily wastewater resulting from washing the bilges of boats using EC working in a batch mode was studied.Iron was found to best Al as the electrode material.EC treatment with both materials was tested using monopolar (MP) and bipolar (BP) electrode configurations.The EEC-and OC-v ration were found to be si a BP configuration, whereas COD r rather similar, thus making Fe-MP the most feasible solution.The initial green color of the wastewater disappeared after EC treatment and the effluent became more transparent.A very low OC value was achieved along-   [67].
The efficacy of EC for treating petroleum-contamated groundwater (from a site n refinery) was evaluated and quantified as total petroleum hydrocarbons (TPH) removed.Al, Fe, and SS in different combinations were tested as electrode materials, of which a SS/Fe-combination proved to be the most suitable.The EC process was studied with systems working in both batch and continuous modes.The natural neutral pH of the groundwater was found to be optimal and increasing HRT was found to improve TPH removal in the continuous EC systems.Note that the removal efficiencies shown in Table 3 were achieved with aeration in the EC cell, which added approximately 22 percentage points to the removal efficiencies (see Figure 5).This was proposed to be due to aeration-transferred oxygen accelerating the oxidation of Fe 2+ (dissolved from the anode) in solution to Fe 3+ , which in turn resulted in formation of greater Fe(OH) 3 flocs, thus improving TPH removal by adsorption.EC was summarized to be a promising technique in eliminating TPH from groundwater [68].
Biodiesel production generates large amounts of alkaline and highly oily wastewater with low nitrogen and phosphorus content, rendering it unable to be purified by biological treatment [69].Such wastewater (with frying oil waste and crude palm oil used as biodiesel feedstock) Industrial wastewater generated in rose oil processing search group, Fe was proven better as the electrode material than Al for this type of wastewater.This was due to clearly lower residual metal concentrations, which were less than 0.2 mg/l with Fe.In this paper, CC, EF, and two different Fenton processes were compared.It was concluded that the EC process was most suitable for this type of wastewater, while CC performed the worst.Initial pollutant concentrations in the wastewater were very high (see Table 3).Note that even though 6.4 was found to be the optimum initial pH value, an acidic natural pH value of 4 was used to achieve the efficiencies presented in Table 3, because the difference in removal efficiencies was negligible [71].

Food Industry Wastewater
Wastewaters from agro-industries come from a myriad of sources and their compositions vary greatly.On the whole they are, however, characterized by high COD and BOD due to their high le e 4 presents a summary of recent applications of EC in the treatment of food industry wastewater.
The dairy industry is associated with generation of huge amounts of wastewater (approximately 0.  4 are in the form batch/ continuous) pre-industrial scale-up experiments showed that EC is an effective technology for treating wastewater from the almond industry, as the initially brown and murky wastewater turned colorless and clear as a result of EC treatment.Initial pollutant values were very high: e.g.5300 -6300 ppm COD and 3200 -4000 FTU (formazin turbidity unit) turbidity.The results obtained for Al/Fe and Fe/Al electrodes were very similar, however the first was chosen over the latter mainly for practical reasons.The treated water was found to satisfy wastewater discharge legislation and the electrogenerated sludge was discovered to be neutral and non-toxic.This work also proved that EC can also be transferred (see )-pre flow High rem were achi toxicity t ved with 2 st was also 0-min C-tre ent this study, a biste luminum was found to outperform Fe as the electrode material, mainly because of the greatly lower color reduction efficiency of iron, while for COD removal, aluminum was found only slightly more effective.The initial COD concentration of the water was 4120 mg/l and it was dark brown in color (3390 Hazen units).The EECvalue was given only at the natural initial pH of 8.82, at which the results obtained were, however, very similar to those of pH 5. The results showed that almost 99.5% of the Al released precipitated in the form of EC sludge and the supernatant had an Al content of about 2.3 mg/l [15].Simulated (SWS) and genuine egg processing industry wastewaters (EPW) with very high pollutant levels (see Table 4) were treated with batch-EC with multiple elec-trode compositions, of which SS was considered most suitable.The effect of adding 200 mg/l of bentonite coagulant was also studied using the real wastewater.The results presented in Table 4 are in the form SWS/(EPW, EPW + coagulant).The results obtained for both wastewaters showed very similar high removal efficiencies in a short treatment time.Additionally, EC yielded valuable by-products bearing high digestible protein and fat values.Addition of the coagulant further enhanced the EC process slightly.An economic analysis of EC indicated that th nted in T T entage points less) pe Th is treatment is economically feasible and capital investments in equipment for a large-scale commercial egg processing plant could be recovered in 14 months [82].
Dark brown baker's yeast wastewater (BYW) with high pollution levels (see Table 4) was treated by batch-EC.The results are presented in the form Al/Fe, because neither of the electrode materials used was proven to be universally superior to the other.Al was found to achieve slightly better removal efficiencies but at significantly higher operating costs.It was suggested that albeit the EC process could be adapted effectively for treatment of BYW, the effluent still contained a large amount of COD, which needed to be further treated by a secondary process [83].
Four wastewater samples (SP 1 -SP 4 ) were taken from different points in constructed wetlands following the outlet of a tea factory, and their treatment by batch-EC with steel electrodes was tested.The results prese able 4 are those of waters SP 1 /SP 4 .The results of waters SP 2 and SP 3 were found rather similar.The waters were highly colored before the EC-treatment (2004/9210 mg/l Pt-Co), however 100% color removal in all the samples, SP 1 -SP 4 , was recorded.No NaCl was added to the wastewater samples even though their conductivities were low (134 -317 µS/cm).Thus, it can be assumed that the energy consumption values could have been lower than the ones obtained.Diluting the waters prior to EC was found to be detrimental in terms of the EECvalue [84].

Other Types of Industrial Wastewater able 5 presents a summary of recent applications of EC in the treatment of other types of industrial wastewater.
Treatment of highly complex and highly polluted industrial wastewater (a mixture of wastewaters from 144 different factories received at a wastewater treatment plant) by batch-EC was studied.Three different electrode combinations were studied.Using aluminum and iron anodes simultaneously (corresponding cathodes were made of the same material as the anode) was found to outperform (better removal efficiencies, less sludge produced) the use of either metal alone as the anode material, combining the advantages of both.Complete disinfection of the wastewater was achieved.A short EC treatment time of 30 min resulted in almost similar (removal efficiencies only a few perc rformance as a 60-min treatment time, for which the results are given in Table 5 [85]. Electroplating, metal finishing, and mining are industrial process in which large volumes of hazardous wastes containing heavy metals and free and metal cyanides are generated.Generally, cyanide removal from wastewater is carried out by chlorination, requiring high operating costs [86].EC-treatment studies of separate cadmium and nickel electroplating rinse wastewaters (results in this order in Table 5) also containing high amounts of cyanide were carried out using iron electrodes in a batch mode.The raw pH values of both the wastewaters were found optimal.In optimum conditions (see Table 5), complete metal and cyanide removal was observed for both wastewaters, with OC-values of 1.05 €/m 3 (cadmium-laden wastewater) and 2.45 €/m 3 (nickel-laden wastewater) [87].
Removal of Ni, Cu, and Cr from very heavily polluted industrial galvanic wastewater was carried out by batch-EC.The raw pH of the wastewater was 1.5, which is strongly acidic, and adjustment to 5 was found necessary.
e wastewater had very high conductivity (41 mS/cm) and its metal content was extremely high; around 2 g/l Ni, 2.5 g/l Cu, and 0.7 g/l Cr (70% present as Cr(VI)).The optimum electrode configuration of the EC system consisted of two separate anode-cathode-pairs used simultaneously instead of a single one made of Al or Fe.This novel EC process was found very efficient (see Table 5) in removing metals from galvanic wastewater.It was concluded that EC could be a good alternative or an after-treatment (the varying composition of such wastewaters may limit the feasibility of EC as a primary method) to conventional methods in this application [88].
Another study of Ni, Cu, and Cr removal from real industrial metal plating wastewater by batch-EC was conducted.The natural initial pH of the wastewater was 3 and it was chosen as "optimal" (optimal values presented in Table 5 given for this pH value) to avoid major addition of chemicals for pH adjustment, even though higher initial pH values (7 -9) resulted in higher metal removal efficiencies, which were also obtained significantly faster.A Fe/Al electrode configuration was found most suitable of the four combinations of Al and Fe tested, however Fe/Fe was found to be nearly as efficient.
In the end, it was concluded that EC in optimum process conditions could effectively reduce metal ions in the metal plating wastewater to a very low level, yielding 100% removal efficiencies for Ni, Cu, and Cr in 20 min [89].
Complexing agent and heavy metal (Zn, Ni) removal from a genuine, highly polluted metal plating effluent The natural pH of the wastewater was found to be optimal.NaCl additions were also found unnecessary due to th lec lyte .5 g/ lori co n i ater.EC was concluded to be a promising treatment method for complexed metal removal from wastewater originating in the metal plating industry [90] ile its ea artic size s a inu ule as was found to remove 85% of COD in 20 min with a low EEC -value of 0.64 kWh/m 3 .The very fast COD removal by the EC process was considered a great advantage of EC.The kinetic data obtained matched the pseudo irst-or Tables 1-7 [96].
A study on decolorization of coking wastewater containing inorganic pollutants and organic contaminants by a continuous EC process using Fe/Ti electrodes was conf Real carwash wastewater was treated by a combined EC/EO batch process.After Fe-EC, a 90-min EO-step at 100 A/m 2 current density was conducted using a boron-doped diamond (BBD) anode.The removal efficiencies and EEC-values presented in Table 5 are in the form EC/EC + EO total; other values are given for the ECstep only.After the EC-step in optimum conditions, 75% of COD was removed rapidly with low energy consumption (0.14 kWh/m 3 ).Total surfactant removal was also noted after the EC -step.No pH alterations were found necessary.After the additional EO-step, 97% of COD was removed with a total EEC-value of 12.0 kWh/m 3 .In an earlier study by the same authors, only EO was used to treat the same wastewater, achieving decolorization (91% color removal efficiency) of coking wastewater with only a slight initial pH alteration from the natural 7 to 8 needed.Adding NaCl to the water showed a substantial increase in removal efficiency, possibly due to electrogeneration of Cl 2 , a strong oxidant [97].
An EC technique with aluminum electrodes was used in a batch mode to remove toxic and carcinogenic antimony from antimony mine flotation wastewater.The antimony concentration of the water being treated was 10 -30 mg/l.The water also contained As (10 -25  in the initial pH range of 6 -10 as in the optimal range of 2 -6, indicating a wide scale of applicability and the redu ng 90% -97 ult of the EC tre ere significantly higher.Therefore, Al (mono emoval by EC could be described with a alue was mentioned.Solution temperature was fo in a ba ndancy of pH adjustment (the pH value of raw water was near 7).In optimum conditions (60 min of electrolysis at 166.67 A/m 2 current density), complete As removal and nearly complete antimony removal efficiencies were achieved along with 71% -77% removal efficiency for SBX, indicating that EC is a promising technology for removing antimony from industrial wastewater [98].
Laundry-based wastewater accounts for approximately 10 % of municipal sewer discharges; thus the efficiency of a batch electrochemical system using aluminum electrodes in treating real laundry wastewater (see Table 5 for composition) was investigated [99].All experiments were repeated twice and the experimental error was below 3%; average data are reported.The unaltered, nearneutral initial pH value was found optimal.Removal efficiencies in optimal conditions were high, bei %.Therefore, it was concluded that when compared with other treatment processes, EC is more effective in treating laundry wastewater.In another study (not presented in Table 5) on EC treatment of (artificial) laundry wastewater, 62% COD removal efficiency was reached [100].In this study, the application of ultrasound was studied and found to clearly enhance the EC process.
The treatability of paint manufacturing wastewater (PMW) by EC in a batch mode was investigated and found economic and The performance of Al electrodes was found to be better than that of Fe electrodes in terms of removal efficiency and OC.Initial pollutant concentrations in PMW were very high (COD 19700 mg/l, BOD 2800 mg/l, SS 1100 mg/l), however in optimal process conditions (fast 15-min treatment at a low current density of 35 A/m 2 ), very high removals of 94% for COD and 89% for TOC were achieved.Absorbance decreased substantially as a res atment, indicating a significant change in the color of the water.No pH alteration of the PMW was found necessary [101].
Removal of suspended solids and turbidity from marble processing wastewater by EC was studied using a batch laboratory-scale (250 ml solution) reactor.Both Al and Fe were tested as electrode materials.When iron was used as the electrode material, removal efficiencies were found to be only slightly lower than those of Al, but the OC values w polar parallel connection) was chosen as the better option.The initial concentrations of the wastewater were very high (turbidity 2640 FTU, TSS 5178 mg/l).EC treatment neutralized the wastewater, slightly lowering its pH value towards 7 from the initial optimal value of 9 (naturally 8.23).Complete removal of TSS and turbidity was achieved rapidly within 2 min and even only 0.5-min EC treatment was able to provide 99% removal efficien-cies for TSS and turbidity.Therefore, the EEC and OCvalues were very low (see Table 5) and the EC process was concluded to be highly effective in this application [102].
Polyvinyl alcohol (PVA) is a well-known water-solu ble polymer that is hazardous and barely biodegradable.PVA is found in wastewaters of a wide range of industries; thus the feasibility of batch-EC in removing PVA from a synthetic (100 mg/l) aqueous solution was investigated.Of the four different electrode combinations tested, Fe/Al was found clearly the most efficient.The effect of altering the initial pH of the PVA solution was not studied.The experimental results showed that the kinetics of PVA r pseudo-second-order model (R 2 = 0.99).In optimum conditions, 77% of the initial PVA was removed [103].
Salicylic acid (SA) is widely used in the pharmaceutical and cosmetic industries and it potentially has adverse health effects in animals and humans.EC -removal of SA (100 mg/l) from a synthetic industrial aqueous solution using aluminum electrodes in a batch mode was investigated and suggested to be promising.The effect of the initial pH of the SA solution was not studied and no base pH v und to slightly affect removal efficiencies (up to about 9 percentage points in otherwise similar process conditions); 298 K was found optimal.In optimum conditions (applying a low current density of 12 A/m 2 ), 87% SA removal efficiency was documented, also providing an extremely low EEC -value.According to the kinetic data obtained, a pseudo-second-order kinetic model described SA removal best (R 2 = 0.98) [104].
The performance of Fe-EC in a batch mode in removing hardness from drinking water was evaluated.The water distribution system water used in this study had a pH value of 8.35 and total and calcium hardness values of 300 mg/l CaCO 3 and 138 mg/l CaCO 3 , respectively.In optimum conditions, 98% of the former and 97% of the latter were removed, thus it was shown that ions responsible for water hardness could be removed by EC [105].
Raw municipal wastewater was electrocoagulated tch mode using SS-electrodes [106].The EC-treatment was found effective and rapid, as it took only 5 min to achieve 99%, 93%, and 95% removal efficiencies for BOD particulate , turbidity, and TSS, respectively.EC test runs were conducted using only raw wastewater with a pH of 7. In another study (not presented in Table 5) on actual municipal wastewater, it was concluded that by using very low currents (10 A/m 2 ), EC can reduce phosphorus and pollution associated with colloids, helping to diminish the organic load of the effluent [107].
Underground water (containing colloidal particles which cause membrane fouling in reverse osmosis, RO) used as the feed water of a RO desalination plant was Copyright © 2013 SciRes.GSC treated with a batch EC-system using electrodes made of SS.A sand filter (2 l) also containing a Birm (a solid similar to active carbon, used for iron removal) filter was ad ded and stable colloidal particles which de arried out in a batch electrochemical cell equippe increased water tempe us l -EC in a ded to the process line after the EC unit to remove coagulated matter.The removal efficiencies given in Table 5 were achieved after the whole process.Before EC, the water had turbidity and TSS values of 150 NTU and 300 mg/l, respectively, and its pH was 7.0.Experiments were conducted using this initial pH only.For both parameters, very high removal efficiencies were achieved rapidly (6 min) and with low current values.Further RO studies conducted using EC-pretreated water proved that all fouling indicators such as flow, pressure drop, and silt density index (SDI) showed less fouling when EC was added prior to EO [108].
Mineral treatment processes produce wastewater containing suspen grade recirculation of water in processing plants.Such synthetic aqueous solutions containing quartz were treated by batch-EC using Al/SS electrodes.The median particle size of the quartz-in-water (320 mg/l quartz, initial pH 4) was 11.61 µm.A comparison between EC and CC (using aluminum sulfate in jar tests) was made, achieving similar removal efficiencies (around 90%) when similar amounts of aluminum were added to the water.The optimum pH range of CC was found to be 6 -9, which was wider than that of EC.However, CC was found to acidify the water, whereas EC treatment shifted the initial suspension pH towards neutral.A 10-min treatment was sufficient for both methods and the kinetics of EC could be modeled with a second-order rate equation.No clearly superior treatment method for the wastewater in question could be proposed within the scope of the study, as no economic values were presented [109].
In another study, EC-treatment of synthetic wastewater was c d with iron electrodes.Bentonite suspensions (~20 NTU turbidity) represented colloid-polluted wastes, as clays behave like hydrophobic colloids in water.Turbidity removals of 80% -85% could be obtained with very low currents (4 A/m 2 , 40-min EC-run).The effect of initial pH was explored with values of 3, 7, and 12, and only the neutral initial pH gave poor results.This was explained as being due to different destabilization mechanisms being prevalent in medias of different pH values.In acidic media, charge neutralization was considered to be the main removal mechanism, whereas sweep flocculation would be dominant in an alkaline solution of this type.It was concluded that the EC process can be applied to treatment of wastes polluted with colloids [110].

Surface Water and Other Natural Water
Table 6 presents a summary of recent applications of EC in the treatment of surface water and other natural water.
Treating simulated surface water containing algae (one of the most dominant cyanobacteria, Microcystis aeruginosa) by batch -EC was studied.The initial cell density used in the experiments was maintained at 1.2 × 10 9 -1.4 × 10 9 cells/l.Aluminum was found to be an excellent electrode material for this application compared with iron (no coloration of water and substantially greater removal efficiency).Interestingly, it was found that algae removal was accelerated dramatically with rature.Ultimately, complete algae removal was achieved with low values of current density and EEC: 10 A/m 2 and 0.4 kWh/m 3 , respectively.Thus, the results were proposed to indicate the effectiveness of EC in algae removal, from both the technical and economic points of view [111].
Laboratory experiments were carried out to investigate the effectiveness of disinfection by EC in a batch mode ing artificial wastewater containing Escherichia coli.Real north-Algerian dam water from Ghrib (known for having high hardness) and Keddara (high algae content) dams were also used.The EC parameters presented for the three waters in Table 6 are in the same order as mentioned above.Aluminum electrodes were found slightly more efficient than ordinary steel (Fe) and stainless steel electrodes.Electrochemical disinfection was proven effective, because the treatment times were rather low and total disinfection and algae removal were achieved [112].
In another study (not presented in Table 6), A batch mode was found to be a suitable process for decreasing hardness and removing bacteria, algae, and bacterial nutriments from two different raw surface waters.The water samples originated from a river and a pond.Complete disinfection was achieved [113].
Reduction of humic acids (HA) from 1000 mg/l synthetic solutions by a batch Al-EC system was studied [114].The effect of applying electromagnetic (EM) treatment prior to EC was also investigated in both batch and continuous modes, of which the latter was found more suitable.EM is an attractively simple approach in which the water being treated flows through a magnetic field, and it consequently slightly changes some of its physicochemical properties.Both EM and EC processes were found to perform best at neutral pH.The 10-min EM-pretreatment was found to slightly further increase the removal efficiency of HA by EC from 96% to 100% [114].
Removal of NOM (natural organic matter) from surface water (inlet flow of a Finnish paper mill) by a batch EC process using aluminum electrodes has been studied using RSM and ANOVA.In modeled optimum conditions, the applied current density, treatment time, and EEC-value were low, with simultaneous high removal efficiency.A slight lowering of initial pH (naturally 5.8) decrease the performance of the EC process to near the level of 0 rpm.This was proposed to be due to the break-up of flocs because of the high shear forces applied.Under optimal conditions, the EEC-values were around 0.3 kWh/kg algae harvested for P. tricornutum and approximately 1.5 -2.0 kWh/kg algae for C. vulgaris, while the respective microalgal recovery rates were 80% and 95%.In specific triplication tests, the process was found to be repeatable.Compared to centrifugation, EC was thus suggested as substantially more energy-efficient.Finally, it was concluded that EC is a promising technology for harvesting marine microalgae, but tests with large-scale pilot EC reactors need to be done to confirm this [118].A batch EC system using a Fe/SS electrode configuration was used to treat model pesticide-contaminated (metribuzin, MB) groundwater.Metribuzin is considered a general-use pesticide which belongs to the group of Copyright © 2013 SciRes.

GSC
Although boron is a vital micronutrient for plant and crop growth, high boron concentrations in irrigation water are known to be detrimental to them.Therefore, treatment of genuine geothermal water containing 24 mg/l boron was st the EC system performed well and i optimum conditions very high removal efficiencies with very low current density values were achieved (see Table 7) [123].
Magnesium was used as the anode material (with a SS cathode) in yet another study.The synthetic water being treated contained boron and the batch EC system performed well in removing it.A scale-up batch EC system with an 8.5-l cell volume was also built and tested.It was found to produce exactly similar removal efficiencies with similar % of initial boron removed at an initial pH of 7, using a low current density of 20 A/m 2 ).This was concluded to show the robustness of the EC process [125].
Removal of cadmium from aqueous solutions was studied with Al-EC in a batch mode.In addition to using a regular DC power source, application of an alternating pulse current (APC) to prevent passivation of the electrodes was studied.EC in the APC mode was found to perform slig , with nearcomplete ca ntly shorter treatment time required.Also, a pilot-scale batch-EC system with a 2000-l cell volume was built and tested in this study.The results were consistent with the results obtained from the laboratory scale, showing that the process was technologically feasible and scalable.Adding high concentrations of co-existing ions (carbonate, phosphate, silicate, or arsenate) to the solution was found to decrease cadmium removal efficiency sign cantly due udied with an EC system working in a batch mode and using aluminum electrodes.An initial pH value of 8 was found optimal, which was near to the natural value of 6.5.It was found that decreasing the current density value from 60 A/m 2 (proposed as optimal) to 30 A/m 2 or 15 A/m 2 corresponds to a tremendous decrease in the EECvalue from 12.8 kWh/m 3 to 2.3 kWh/m 3 and 0.73 kWh/m 3 , respectively, while boron removal efficiencies decreased from 96% to 84% and 73 %, respectively.It was concluded that after the EC process, the effluent water could be used for irrigation [120].
Studies on mercury (II) removal from water were conducted using a laboratory-scale (100 ml) batch-EC system.A synthetic mercury-containing (4 mg/l) solution was first used to optimize the process.Iron was found to perform better than aluminum; however, both electrodes achieved very high removal efficiencies over a wide pH scale.Mercury was then added to a river water sample achieved very high removal efficiencies over a wide pH scale.Mercury was then added to a river water sample and the solution was treated in the previously determined optimum process conditions (see Table 6).Complete mercury removal was achieved also from the semi-synthetic mercury-contaminated river water, with 90% COD removal, as well.It was concluded that EC can be effective in the treatment of water polluted by mercury(II) ions [121].

Model Water and Wastewater Containing Heavy Metals, Nutrients, Cyanide and Other Elements and Ions
EC studies presented in this category of waters can be simplified to have been conducted using small-scale laboratory Al, Fe, or SS batch reactors and synthetic model water or wastewater with only one particular pollutant removed (see Table 7).Therefore, not all of the studies [13,[122][123][124][125][126][127][128][129][130][131][132][133][134][135][136][137] are discussed in the following text (although the optimum conditions found are presented in Table 7), but only those which differ notably from this in some way.Table 7 presents a summary of recent applications of EC in the treatment of waters containing heavy metals, cyanide, and other elements and ions.Arsenic removal batch-EC experiments using iron were conducted in a laboratory with synthetic solutions, providing complete As(V) removal with a short treatment time.The experiments were further expanded to field tests in which 50-l batches of real arsenic-and phosphate-containing groundwater were treated.In the field tests, a filtration step was also added after the EC, raising the removal efficiency of total arsenic from 97% to 100%.
The economic values were found to be very low and the naturally neutral initial pH of the water was found optimal [122].
Iron-containing (25 mg/l) synthetic solutions were treated by batch-EC.Magnesium was used as the anode material (iron as the cathode), which is rare, but n (optimum) process conditions (86 htly better than in the DC mode dmium removal and a significa ifito competition for adsorption binding sites [126]. Removal of chromium from synthetic solutions with concentrations of 50, 100, 500, and 1000 mg/l (values given in this order in Table 7) were treated with a batch-EC system using aluminium/iron electrodes.Use of APC was also studied in addition to the DC mode.During these experiments the polarity of the anode and cathode was thus changed every 4 min.It was found that the APC mode was more efficient than the DC mode here, also, with operating times 3%, 6%, 15%, and 25% shorter when treating initial Cr(VI) concentrations of 50, 100, 500, and 1000 mg/l, respectively.This makes the APC mode more cost-effective.Also, the turbidity values of the treated water were 1 NTU and 20 NTU with APC and DC, respectively.NaCl, KCl, PAC, and NaNO 3 were tested as a supporting electrolyte; NaCl and KCl were found most suitable in every aspect.In optimum conditions, complete removal of chromium was achieved [127].
Solutions containing radioactive strontium were treated with a batch-EC system.Initial concentrations of  of the studies discussed here, the electro terials used were made of aluminum, iron, or SS in different combinations, with only a few exceptions.As it can be seen from Tables 1-7, the superiority of different electrode materials seems to vary between different types of aqueous solutions being treated and must therefore always be researched case-specifically.In some of tment costs and efficienc rial uld t be factors when choosing between different electrode materials to be used, because other technical aspects (e.g.floc properties, coloration of water by iron, etc.) may also Table 7).This could be mainly due to the fact the waters in this category were synthetic, modeling the removal of only one pollutant at a time and at mostly relatively lo a The distance between the electrodes fluctuated between 2 -70 mm; however, most setups used by the authors considered here had as electrode gap of 5 -20 mm.The effect of this parameter on the feasibility of the EC treatment was rarely studied; e.g.[10,29,124,134].This also applies to the effect of temperature and stirring, although all of these have been shown to have a varied effect on the removal efficiencies of EC [31,48,115,117,120,134,138].
Even though the EC process seems to function well over a wide range of pH values in most studies, generally a relatively narro aterials used) where the process performed optimally could be found.This pH range was mostly found to be close to neutral pH values, as observed in Tables 1-7.
The treatment costs and electricity consumption of the EC process in optimal process conditions were not calculated and presented by all the authors, but the aforementioned values were mostly somewhat low when they were presented (typically around 0.1 -1.0 €/m 3 and 0.4 -4.0 kWh/m 3 , respectively, see Tables 1-7).On the whole, the values for optimal treatment costs and electricity consumption varied greatly between different studies and different types of aqueous solutions, the aforementioned values fluctuating between 0.0047 -6.74 €/m 3 and 0.002 -58.0 kWh/m 3 , respectively.However, both values were close to the lower end of the scale presented above.
In most of the papers reviewed in chapter 3.1 the EEC -values were given, most of them being inside or close t a range of 0.1 -0.lated in only tw found to be similar in degree: 0.12 and 0.24 €/m 3 , which can be considered very low.Oily wastewaters had economic numbers close to each other.As for OC, 0.2 -0.4 €/m 3 seemed to be an average value, and correspondingly, 2 -6 kWh/m 3 was the average EEC -value.The results of a very recent investigation of EC treatment of bio oil-in-water and synthetic oil-in-water emulsions support these findings [139].
Food industry wastewater treated with EC had OC -values lf of the papers).The papers presented in chapter 3.5 had economic numbers presented in about half of the papers and their fluctuation was considerable (between 0.062 -6.74 €/m 3 and 0.14 -19.8 kWh/m 3 ).This can be considered to be mainly due to the significant variance of and 3.6 had no OC-values given.Paper industry wastewater EEC-values were also absent, whereas in surface water category they fluctuated substantially (between 0.4 -23.6 kWh/m 3 ).
The observed optimal current densities varied greatly, but in most studies they were found to be in the range of 10 -150 A/m 2 .Wh t ns.N rly al f the C tr had ve men sult or waters s wh to categories (chapters 3.1 -3.7), it seems the optimal current density values of oily wastewaters were the highest of all the categories, on average (approx.160 A/m 2 ).Waters from other industries also had optimal current density values often higher than average.The corresponding value for waters and wastewaters presented in chapters 3.6 and 3.7 were the lowest, on average: approx.45 -50 and 60 -65 A/m 2 , respectively.Both water categories had most of their optimal current values inside the range of 5 -60 A/m 2 .For wastewaters pres r 3.5, optimal current density values were largely in the range of 100 -150 A/m 2 .These observations could be related to the high levels of pollutants in oily and other industrial wastewaters and, on the contrary, to surface waters and modeled waters and wastewaters being only mildly polluted in comparison, with relatively low concentrations of pollutants.
One of the advantages of the EC process is its fast treatment capability, and in a vast majority of the studies discussed in this paper, optimal treatment times were found to be in the range of 5 -60 min (these figures do not take required sedimentation times into account, which are generally rather short).More than half of the authors found an optimum treatment time of 30 min or less.In some cases a two-to three-hour EC treatment time was needed, however some wastewater could be purified rapidly in a few minutes.As with other functional parameters, treatment duration seems to be strongly dependent on the type of water being purified and its concentration.The applied current density also has a significant impact on treatment duration.

Conclusions
The range of feasible EC applications is expanding.In a vast majority of the studies discussed in this paper, optimal treatment times were found to be in the range of 5 -60 min (not taking into account required sedimentation times).More than half of the authors found an optimum treatment time of 30 min or less.Observed optimal cur-rent densities varied greatly, but in most studies they were found to be in the range of 10 -150 A/m 2 .Even though the EC process seems to function well over a wide range of pH values in most studies, generally a relatively narrow pH range could be found where the process performed optimally.This pH range was mostly found to be €/m and 0.4 -4.0 kWh/m , respectively).To , pp.
close to the neutral pH value.The superiority of different electrode materials seems to vary between different types of aqueous solutions being treated, and must therefore always be studied casespecifically.Both OC and EEC-values were found to fluctuate greatly between different water types being treated, between 0.0047 -6.74 €/m 3 and 0.002 -58.0 kWh/m 3 , but they were generally rather low (typically around 0.1 -1.0 3 3 conclude, EC has great potential in purification of various types of water and wastewater and seems to be a feasible and economical alternative in this field, although more research is needed, especially using larger-scale and/or continuous systems and focusing on the fundamentals of the EC process.

Figure 4 .
Figure 4. Scheme of the EC pilot prototype set up (see above).Adapted from [65].
er rarely) graphite as the cathod aterial.Box-Behnken design-based RSM optimization was a the best process conditions.T results m tched experiment alu ery ll; d i ues for initial pH, voltage, an ction tim 06, 18.2 V, and 23.54 min, respectively, w v encies all within 0.7 percenta im ly.Ultim , E as found suita primary treatment of biodiesel wastewater, which, however, still requires further biological was purified by EC.In a previous study by the same revel of organic content [72].Ta- bl of effluent per liter of processed milk) that is high in nu-on th rem val of a func batch-EC p cess as treate with nd (rath atch C sy m u g alu inum as e

Table 1 . Recent applications of EC in the treatm nt of tannery, textile and colored wastewater.
h = Additional "optimum value" estimated from the data in the article; n.d.=Not determined.. Overview

Table 4 . Recent applications of EC in th
2 l to 10 l p

reatment of food industry wastewater.
The natural, unmodified pH value of the water or wastewater (found optimal); e = tion calculation based on values given in the article at issue = Optimum value estimated from the data in the article (precise value not given); n.d.
a = HRT (hydraulic retentio e) in EC systems with continu s mode of operati he best electrode config ion of those te =

Table 4 ,
very similar results) to an automated industrial scale.No