Trifuntional Oligoetherols and Polyurethane Foams with Carbazole Ring

The method of synthesis of trifuntional oligoetherols with carbazole ring from 9-(2,3-epoxypropyl)carbazole and diethanolamine and oxiranes like ethylene and propylene oxide was presented. Structure and some physicochemical properties of the products were described. The oligoetherols were demonstrated as good substrates for synthesis of polyurethane foams of enhanced thermal resistance. It has been found that the obtained foams are rigid at room temperature and their apparent density was 34 kg/m44 kg/m. The water uptake was low, maximum to 10.5 mass%. Dynamic thermal analysis of this foams showed that 5% mass loss starts at 200 ̊C 220 ̊C, while temperature of 50% mass loss was 340 ̊C 370 ̊C. Concomitantly the increase of compression strength was observed.


Introduction
Polymers containing carbazole ring have the critical importance for physical parameters of polymers, like: phase transition temperatures, solubility in polymer in organic solvents, electric conductivity, and ability to form chargetransfer complexes [1][2][3][4][5][6][7].Carbazole decomposes at temperatures higher than 260˚C.High thermal stability of carbazole prompted us to introduce carbazole into polyetherols in order to obtain products of high thermal stability, i.e. polyetherols themselves and polymeric products obtainable from them; polyurethanes and polyesters.Carbazole is mono-functional compound and this is the reason of limited application for synthesis of oligoetherols by its reaction with oxiranes.Therefore, previous studies were devoted to increase its functionality and solubility of carbazole derivatives in oxiranes [8].The di-functional oligo and polyetherols with carbazole ring were not known till now except for some preliminary results from this lab [9][10][11].Here we have presented the method of synthesis of tri-functional oligoetherols with carbazole ring inside chain and apply them to obtain polyurethane foams with enhanced thermal resistance.

Opening of Epoxide Ring with Diethanolamine
To a 100 cm 3 three-necked roun bottom flask equipped with reflux condenser, mechanical stirrer and thermometer 18.0 g (0.11 mole) of EPC and 15.6 cm 3 (0.16 mole) of diethanolamine (DEA, pure, Fluka, Buchs, Switzerland) were introduced.The mixture was stirred and heated until dissolving of substrates (at temperature ca.60˚C), then 0.1 cm 3 triethylamine (TEA, pure, Fluka, Buchs, Switzerland) catalyst was added.The mixture was heated to 120˚C.The progress of reaction was monitored by determination of epoxide number (EN).Then, 50 cm 3 distilled water was added, the mixture was vigorously stirred and heated at 90˚C for about one hour to rinse the diethanolamine off.The mixture was cooled down to room temperature and water layer was removed, washed couple of times with water and final product: 9-(9-carbazolyl)-3-aza-6-oxanonane-1,6-diol (CAOD, I) as dense brown resin was vacuum dried at 80˚C to remove water.

Reaction of CAOD with Oxiranes
In a pressure reactor of 250 cm 3 volume equipped with magnetic stirrer and thermometer 25.0 g (0.076 mol) of CAOD, 1 cm 3 (0.007 mole) catalyst (TEA) and 20.1 g (0.46 mola) of ethylene oxide (EO, pure, Fluka, Buchs, Switzerland) or 26.5 g (0.46 mol) of propylene oxide (PO, pure, Fluka, Buchs, Switzerland) were placed.The mixture was stirred and heated to 75˚C.The progress of reaction was monitored by determination of EN.The products were brown resins, from which the catalyst was removed by distillation under reduced pressure (p = 2132 Pa, temp.80˚C).

Analytical Methods
The progress of reaction of carbazole with epichlorohydrin and oxiranes was monitored by EN, which was determined by hydrochloric acid method in dioxane [12].Elemental analysis for C, H, N, were done with EA 1108, Carlo-Erba analyzer.The 1 H-NMR spectra of products were recorded at 500 MHz Bruker UltraShield in DMSO-d 6 with hexamethyldisiloxane as internal standard.IR spe-ctra were registered on PARAGON 1000 FT IR Perkin Elmer spectrometer in KBr pellets or ATR technique.The number-average molecular mass M n of obtained oligoetherols was determined cryoscopically in DMSO solvent.Thermal analyses of oligoetherols and foams (DTA, DTG and TG) were performed in ceramic crucible at 20˚C -600˚C temperature range, about 200 mg sample, under air atmo-sphere with Termowaga TGA/DSC 1 derivatograph, Mettler.

Physical Properties of Oligoetherols
Refraction index, density, viscosity, and surface tension of oligoetherols were determined with Abbe refractometer, picnometer, Höppler viscometer (typ BHZ, prod.Prüfgeratewerk, Germany) and by the detaching ring method, respectively.

Foam Preparation
Foaming tests were conducted on laboratory scale in 250 cm 3 paper cups at room temperature.In details oligoetherol (10 g) was mixed with 0.2 g of Silicone 5340 (pure, Houdry Hülls, USA) as surfactant, TEA as catalyst (1.25 -3.76 wt%) and water (2% wt%) with respect to oligoetherols.A calculated portion of diphenylmethane 4,4'-diisocyanate (commercial isocyanate containing three-functional isocyanates at the level of 30%; MDI, pure, Merck, Darmstadt, Germany, was used) was then added and the mixture was vigorously stirred until the contents were creamed.Test samples were cut out from the foams thus obtained.The following properties density [13], water uptake [14], linear shrinkage estimated on the basis of the change of linear dimension of the sample heated for 4 hours at 100˚C [15], thermal stability as the weight loss at 150˚C within one month and compression strength [16].

Results and Discussion
The reaction of carbazole with ep formation of EPC (II), which underwent ring opening upon reaction with diethanolamine in presence of TEA to give three-functional semiproduct (I) according to the following reaction scheme: The process was perform without any solvent, using tw ed o equivalents of diethanolamine.The obtained product was semisolid resin, which was identified by elemental analytical, IR and 1 H NMR spectra (see Experimental; Analytical of CAOD).In the 1  The aromatic C-H bands were observed at 747 and 720 cm -1 in the IR spectra, the stretching OH and NH bands were found at and 1152 cm -1 and 1652 cm -1 respectively, while valence bands of C-O-C were found at 1034 -1066 cm -1 .The obtained product is readily soluble in oxiranes: EO and PO at room temperature.Addition of TEA to such a solution and heating the mixture to 60˚C triggered the reaction of formation of three-functional oligoetherols III according to the scheme: Elemental analysis and M the structure of the oligoetherols (III, x + y + z = 6, Table 1).IR spectra of ol .Some physical parameters like I) n confirm igoetherols (Figure 1) are remarkably different from that of semiproduct.The intensity of the band at 1098 cm -1 increased indicating formation of ether bonds.Also the band at 2900 cm -1 grew, indicating the incorporation of oxyalkylene units into oligoetherol.The intensity of the resonance at 3.5 ppm in the 1 H-NMR of oligoetherols (Figure 2) increased according to the increase of number of oxyalkylene units in a product.Simultaneously the resonances at 4.2 -4.6 ppm diminished illustrating the disappearance of hydroxyl protons due to progressing reaction of OH with oxirane.
The oligoetherols were obtained from the CAOD: oxirane 1:6 molar ratio system refraction index, density, viscosity and surface tension in function of temperature were studied (Figures 3-6).Typical changes of those parameters in function of temperature were observed.The products obtained from EO had higher refraction index and density than those synthesized from PO. Generally the physical properties of oligoetherols synthesized here are similar to those of typical polyols used for obtaining polyurethane foams [17], with     the exception of viscosity, w ichever is higher h thesized oligoetherols have good thermal resistance (Table 2).Their thermal decomposition starts at 230˚C -decomposition falls into 460˚C -480˚C region.High thermal resistance of these products suggested their usefulness as substrates for thermally resistant polyurethane foams.
The polyurethane foams were performed on laboratory scale (Table 3).The optimization of amount of isocyanate, foam 240˚C (mass loss 5%), while their temperatur igoetherol was performed for foaming.The water amount was optimized as 2% water related to mass of oligoetherol; the use of higher water percentage led to the formation of irregular pores.The amount of catalyst was also crucial; the rigid foams were obtained when 1.25% catalyst was applied in case of oligoetherol obtained from EO was used and 3.76% in case of oligoetherol obtained from PO.
The best foams were obtained when the molar ratio of 4,4'-diphenylmethane diisocyanate to number of hydroxyl g etherol obtained from EO and 1.44 in case of the oligoetherol synthesized from PO. Lower or higher ratio led to underhardened foams with large pores.
Foaming compositions showed short creaming times (to 15 sec) and expanding times (to 44 sec).Drying times in case of compositions from EO was 1 in case of PO it was as long as 60 seconds.
The best foams, the rigid ones and with unisized pores were subjected to density, size stability at 150˚C, water uptake, thermal resistance and change of mech rties upon thermal exposure (Table 4).It has been found that the obtained foams are rigid at room temperature and their apparent density was 34 kg/m 3 -44 kg/m 3 .The water uptake was low, maximum to 10.5 mass%.The dimensional stability at 150˚C measurements revelaed that the dimension change it was no larger than 8.0% of initial dimension.
Dynamic thermal analysis showed that 5% mass loss starts at 200˚C -220˚C, while temperature of 50% mass loss was 340˚Crements of thermal resistance were conducted at 150˚C for one month (Figure 7).Continuous decrease of foam

Summary and Conclusions
1) Three-functional oligoetherols with carbazole ring can be obtained starting from carbazole, by consecutive conversions with epichlorohydrin to 9-(2,3-epoxypropyl)carbazole, ring opening with diethanolamine, and finally by reaction with oxiranes EO or P used regularly for obtaining polyureth higher thermal resistance of the former.
3) Obtained oligoetherols are useful substrates for synthesis of polyurethane foams which have enhanced thermal resistance and remain unchanged upon long exposure at 150˚C.

Figure 1 .
Figure 1.IR spectrum of oligoetherols obtained in reaction of CAOD with EO.
H NMR spectrum the multiplet at 7.0 -8.1 ppm from carbazole ring protons was observed.The resonances of -OH and NH were present together with 3.9 -4.1 ppm region, the signals of methylene protons of -CH 2 O-were found at 3.2 -3.5 ppm, while methine proton resonances were observed at 4.65 ppm.

Figure 3 .
Figure 3. Refractive index of oligoetherols obtained in reaction of CAOD with oxiranes versus temperature.

Figure 4 .
Figure 4. Density of oligoetherols obtained in reaction of CAOD with oxiranes versus temperature.

Figure 5 .
Figure 5. Viscosity of oligoetherols obtained in reaction of CAOD with oxiranes versus temperature.

Figure 6 .
Figure 6.Surface tension of oligoetherols obtained in reac

Figure 7 .
Figure 7. Thermal stability of polyurethane foams as the weight loss after heating at 150˚C for a month.mass was observed throughout the test, however the larnthesized from CAOD and PO or EO was 15 -20 mass% within