Study on a Polyamine-Based Anti-Collapse Drilling Fluid System

In complex strata, oil-based drilling fluid is the preferred drilling fluid system, but its preparation cost is high, and there are hidden safety risks. Therefore, the new progress of high-performance anti-collapse water-based drilling fluid at home and abroad is analyzed. It is difficult to prevent and control the well collapse. Once the well wall instability problem occurs, it will often bring huge economic losses to the enterprises, and the underground safety accidents will occur. In order to ensure the stability of the well wall and improve the downhole safety, the key treatment agent of water-based collapse drilling fluid is selected, the anti-collapse drilling fluid system is formulated, the evaluation method of drilling fluid prevention performance is established, and a set of water-based drilling fluid system suitable for easy to collapse strata in China is selected to ensure the downhole safety. The development trend of high performance anti-collapse water-based drilling fluid is expected to provide a reference for the research of high performance anti-collapse water-based drilling fluid system and key treatment agent.


Introduction
In recent years, the various complex conditions and accidents caused by the instability of the well wall have not only caused great economic losses, but also seriously affected the production efficiency of production. Well wall collapse is not only a simple mechanical problem, but also the hydration of mud shale is also The results showed that the formation, chemical, mechanical, physical and chemical factors had the greatest impact on the collapse. Through the analysis of formation collapse mechanism, the measures to strengthen plugging, restrain expansion and mechanical equilibrium are put forward to prevent formation collapse [7] [8] [9] [10] [11]. Therefore, we expect to find a low-cost, high-efficiency anti-collapse agent, and take it as the core, to formulate a set of anti-salt, calcium resistance, high-temperature anti-collapse drilling fluid system.

Laboratory Apparatus
The experimental instruments used are shown in Table 1.

Experimental Drugs
The main drugs used are shown in Table 2.

Preparation of Bentonite-Based Slurry
Preparation: Take 10 liters of hot water (60˚C -70˚C) and slowly add 400 g of bentonite while mixing. After the mud is evenly dispersed, slowly add 25 g of Na 2 CO 3 and stir evenly for 2 hours, and place the matched moving soil slurry for 24 hours.

Selection of Drilling Fluid Additives
Under the condition of meeting the performance requirements, the principle of

The Inhibitory Test
1) Accurately weigh 1.5 g of earth, 0.8 g, 60 purpose river sand, fully mix and stir well.
2) Pour the evenly mixed soil and river sand into the mold sleeve of the shale sheet press, shake the pressure rod up and down, so that the pressure gauge reads to 2 MPa, and press the sheet for 5 minutes.
3) Take out the shale chip press mold set, put a plastic with a small groove in it, make its lower contact shale pressing, groove facing, then after high speed mixing, has added the reagent drilling fluid into the right amount of surface plate, cover the filter paper, and has put into the plastic shale pressing mold on the surface of the filter paper.

Test of Heat Recovery Rate
In turn, the matched drilling fluid into the aging tank, called 30 g debris, respectively into the aging tank, temperature control in 180˚C, hot roll 16 h, oven cooling, pour out the aging tank drilling fluid and debris, with 40 standard sieve sieve in the drilling debris, and rinse with clean water, and then put the screened debris in the electric blast drying box, about 2 h, then weigh the debris X 1 , calculate a recovery rate. Add 350 mL of tap water into the aging tank respectively, and pour the weighed 1 recovery debris into the human aging tank respectively, Put the high temperature roller furnace heating rolling, temperature controlled at 180˚C, hot rolling for 2 h, out of the oven cooling. Take the debris in the aging tank with a 40-mesh standard sieve, dry it in the human electric blast drying box, and then weigh X 2 with an electronic balance to calculate two recovery rates.

Performance Evaluation of Zwitterionic Polymer Drilling Fluid
The system parameters of 9 groups of drilling fluid added with additives according to the anti-collapse reagent formula listed above are as follows, and the results are shown in Table 3. The formula is based on SPNH(sulfonated lignite resin) and PSC (sulfonated lignite), supplemented by high temperature stabilizer SMP (sulfonated phenolic resin), the high temperature stabilizer can maintain the original mobility and filtration loss under the condition of increasing drilling fluid temperature, add the aggravating material barite regulating density to adapt to the formation pressure of high temperature deep well, and add the inhibitor KCl to improve the inhibitory heat roll recovery of drilling fluid system.
In the experiment and species, the following formula 4% soil slurry + xy-27 + FA-367 + 2% SPNH + 2% PSC + 2% SMP + 4% KCl + 0.2% K-PAM + barite was obtained. According to the data in Table 3, after different amounts of anti-collapse reagent are added to the base slurry, the formed drilling fluid system has changed in terms of viscosity and filter loss compared with the original base slurry. The viscosity showed a trend to increase, while the filter loss showed a trend to decrease. By comparing the viscosity, filtration loss and other parameters of each group of drilling fluid system, the best anti-collapse drilling fluid system formula determined in the test is as follows: 4% Moving slurry + 0.2%xy-27 + 0.1%FA-367 + 2% SPNH + 2% PSC + 2% SMP + 4% KCl + 0.2% K-PAM + barite.
As can be seen from Figure 1, Figure 2 and Table 4, Table 5, after the mobility of the drilling fluid system after 180˚C hot roll, the filter loss of the zwitterionic polymer drilling fluid increased greatly, and the expansion volume increased

Performance Evaluation of Amine-Based Polymer Drilling Fluid System
The system parameters of 9 groups of drilling fluid added according to the anti-collapse reagent formula listed above, and the results are shown in Table 6.
Based on the blocking agent YL-301 and the filter reduction loss agent YL-201, the blocking anti-collapse agent YL-FT3 increased the anti-temperature and anti-collapse performance, and the amine-based polymer inhibitor XZ-301 was added to increase the suppression performance and thermal roll recovery.
It can be seen from Table 6: after different amounts of anti-collapse reagent are added to the base slurry, the formed drilling fluid system has changed in terms of viscosity and filter loss compared with the original base slurry.The viscosity showed a trend to increase, while the filter loss showed a trend to decrease. By comparing the comprehensive analysis of the viscosity and filter loss parameters of each group of drilling fluid system, the best anti-collapse drilling fluid system formula makes the following formula by adding the optimal amount and type in the experiment:4% Moving soil slurry + 0.3%YL-102 + 2%YL-103 + 3%YL-201 + 2%YL-301 + 3%YL-FT3 + 2%XZ-301 + barite.
As can be seen from Figure 3, Figure 4 and Table 7, Table 8, the filtration loss of the drilling fluid in the drilling fluid system increased slightly after 180˚C thermal roll.
Through the above performance evaluation and comparison, it is not difficult to find that the amine-based drilling fluid system has good high temperature resistance, inhibitory properties and outstanding water loss, so we can further    As can be seen from Table 9, Table 10, with the increasing amount of NaCl, the rheology, filter vector and inhibition of the drilling fluid system show a small increase trend. Drilling fluid system has good salt resistance.
As can be seen from Table 11, Table 12, with the increasing mobility of the drilling fluid system, the filter vector and inhibition show a trend of small increase. Drilling fluid system has good calcium resistance.
As can be seen from Table 13, after 180˚C thermal roll, the recovery rate of the polyurethane-based drilling fluid system is basically greater than 80%, which is obviously better than the comparative drilling fluid system and can meet the basic requirements of anti-collapse drilling fluid.

Conclusions
1) The influence of the amount of different monomer on the performance of drilling fluid is known the best amine-based polymer anticollapse drilling fluid system formula is: 4% soil slurry + 0.3%YL-102 + 2%YL-103 + 3%YL-201 + 2) At the high temperature of 180˚C, the mobility, filter loss and inhibition of the drilling fluid system are basically unchanged compared with that before the thermal roll, and its temperature resistance is good.
3) According to the experimental data of testing the amine-based polymer drilling fluid system, the best anti-collapse drilling fluid system selected in this experiment is mobility under the condition of 24.0% NaCl or 1.0% CaCl 2 , and the filter loss and inhibition are not much affected, and the salt and calcium resistance is good.

4)
Shale rolling recovery rate experiment shows that the first heat roll recovery rate and the second time are more than 80%, which basically meets the requirements of the site anti-collapse drilling fluid.