Influence of Culinary Treatment on Soriz Mineral Elements (Sorghum Oryzoidum)

Soriz (Sorghum oryzoidum) is a relatively new cereal of hybrid origin obtained at the Research Institute for Maize and Sorghum of Moldova. This paper presents and analyzes the results of the study of essential minerals content (K, Na, Ca, P, Mg, Fe) in native and hulled sorghum grains and their changes under the effect of hydrothermal treatment. The results show that the sorghum grains are a good source of essential minerals, especially of K, P and Mg and are less rich in Ca, Na and Fe. The experimental data have demonstrated that the technological process applied to obtain hulled sorghum leads to a considerable decrease in minerals content. Culinary treatment had a greater impact on the K content and lower on P and Mg content. The results will be used to op-timize the parameters of raw material processing and culinary treatment with the aim of minimizing the mineral loss as well as for the nutritional value balance of soriz sorghum dishes.


Introduction
Cereals and food derivatives from cereals are the staple food of the population all over the world, only the crops being different from one country to another [1] [2]. Diversifying the range of cereals is highly relevant in the context of nutritionists' recommendations to increase the intake of foods rich in complex carbohydrates in combination with decreased lipid intake, in order to reduce the risk of cardiovascular disease and other metabolic diseases [3] [4] which are the leading causes of death in European countries.
Cereal grains are the major source of dietary nutrients in the world. However, a large part of them is lost after processing (peeling, crushing, grinding, mois-turizing, boiling, frying, expanding, etc.). The loss of mineral elements in the process of decortication depends on the types of cereals, their sizes, the degrees of peeling, etc [5].
The content of mineral elements is also influenced by culinary technological processes, which refer to the ability of cereals to boil in the shortest possible time, accompanied by the improvement of organoleptic qualities.
Prior to the culinary treatment, the cereals are subjected to technological processes of primary processing such as: sorting (sometimes sifting) and washing.
The content of dry substances in the water after washing is: starch-about 41%, nitrogen-about 33% and sugar-about 13%. Some research on the influence of hydration (for 24 hours) of whole grains (corn, sorghum, rice, etc.) on the content of iron, zinc and phytates has shown that during hydration in the water passes a considerable amount of iron and less zinc [6].
Knowing the impact of processing on cereals could contribute to the selection of technological processes with a tolerant effect on nutrients, which will increase their accessibility and, respectively, will contribute to increasing public health.
Soriz (Sorghum oryzoidum) is a hybrid of sorghum that is characterized by glassy endosperm, similar to rice. It was obtained at the Institute for Scientific Research for Maize and Sorghum in the Republic of Moldova, by crossing Sudan grass (S. sudanense) and sorghum bicolor (S. bicolor) [7] [8] [9].
The advantages of this crop have many; sorghum is a local crop with high productivity, resistant to drought and high ambient temperatures, a source of macro-and micronutrients with high nutritional value. An important feature of soriz is the absence of gluten, which makes it an optimal alternative in the diver. Diversification of gluten-free products is a relevant and popular field of research, especially for the Republic of Moldova [7] [10] [11].
The paper presents and analyzes the results of the research of the content of essential mineral elements (K, Na, Ca, P, Mg, Fe) in whole grains of soriz and hulled soriz and the modification of their content in the culinary treatment.
The results obtained are useful for optimizing the manufacturing process and technological processing of sorghum grains and groats in order to minimize losses of mineral elements, evaluation and nutritional balance of sorghum-based preparations.

Materials
Whole grains of soriz and hulled soriz "Alimentar 1", purchased at the Institute of Plant Protection and Organic Agriculture of the Academy of Sciences of Moldova, were used as research material. The following materials were used for research (Table 1).

Methods
The ash content was determined after the removal of organic matter by dry  [13]. Initially, the weight of clean and dried crucible was measured (W1) and a 5 g of sample (W2) was added and charred in the hot plate under the hood. The charred sample was placed in a muffle furnace and ignited at 550˚C for 5 h until the sample became white/gray. The crucibles and their content were cooled in a desiccator and weighed (W3) to determine ash content. Minerals content analysis was determined according to AOAC, (2000) [12]. Sodium (Na) and potassium (K) concentrations were determined by using the standard flame emission photometer; phosphorus (P) was determined colorimetrically by vanadate-molybdate method procedure. Calcium (Ca) and iron (Fe), concentrations were measured by atomic absorption spectrophotometer.

Results
Minerals are considered to be essential in human nutrition [14] [15]. The concentration of mineral elements in cereals and cereal derivatives varies depending on genotypic and environmental influences, as well as the degree of technological processing.
Prior hydration of soriz grains in water for 8 hours before boiling slightly reduced the final losses of P and Mg by 3.13 mg/% and 7.0 mg/%, respectively, pos-sibly due to the shorter heat treatment period until the product is fully penetrated, but increased by about 3 mg/% the loss of potassium, which has a higher solubility than the first and can possibly diffuse into the water, including in the process of softening the grains.
Preliminary hydration of the grains had a more tolerant impact on most of the minerals studied. Thus, the Fe content of hydrated and boiled soriz grains is 3.48 mg/%, and in cooked grains without hydration −3.22 mg/%, which is a reduction of 17.1% and −23.3% respectively, compared to native samples. The boiling of the grains contributed to the increase of the share of Ca (by 15.80%) and Na (by 41.66%), compared to the native grains, and the share of Ca and Na in the boiled grains after prior hydration increased by 67.97% and 70.83% respectively in hydrated and boiled grains.
During the boiling process, the redistribution of the substances in the product takes place through mass transfer and diffusion processes. Thus, the increase in the mass fraction of calcium in the dry mass of boiled sorghum grains could be explained by the low solubility of Ca and sodium, possibly by locating this element in the inner layers of the grain, which slows down the diffusion of Na into the environment.
It has been established that the content of mineral elements investigated in native soriz hulled grains is lower than in grains, with the exception of Na. Thus, the dehulling of the grain led to a decrease in the content of К 2.5 times, Р-2.9 times, Mg-de 3.7 times, Са-de 2.4 times and Fe-3.2 times. This can be explained by the concentration of the mentioned mineral substances mainly in the upper layers of the grain which are removed in the process of peeling the grains. The potassium content in dehulled grains is slightly higher than in whole grains (1.2 times), which is possibly explained by the location of this element in the inner layers of the soriz grain.
Boiling the husked grains led to an even more significant reduction in the share of potassium (78.82%) and phosphorus (9.74%) in the finished product. The mass fraction of the other mineral elements (Ca, Mg, Fe) in the dry mass of the cooked husked grains has increased, which could be explained by their lower solubility in relation, for example, to that of potassium.
Analyzing the mineral content of whole grains and peeled boiled soriz grains (Table 2), it can be seen that whole grains are a more valuable source of potassium (301.87 -290.17 mg/%), whose content is 9 times higher than in dehulled grains (33.3 mg/%), and the phosphorus and magnesium content is higher in whole grains of boiled soriz (267.69 -277.3 mg/% and 146. 19 -157.41 mg/%) compared to boiled hulled grains (94.57 mg/% and 55.28 mg/%). The content of

Conclusions
Based on the results of the research, the following conclusions can be drawn: Whole grains of soriz, like other traditional cereals in the regional diet (wheat, rye, buckwheat, rice), are an important source of potassium, phosphorus and magnesium, but are poor in some essential mineral elements in human nutrition such as calcium and iron.
The shelling of sorghum beans has a negative impact on the content of mineral elements.
Boiling whole grains with pre-hydration has a more tolerant impact on the mineral content and could be recommended as a preliminary step in the cooking process of cereals.

Funding
This research was funded by state project "Personalized Nutrition and Intelligent Technologies for My Well-Being", No. 20.80009.5107.10, running at Technical University of Moldova and Contributions regarding nutritional eradication of gluten consumption diseases, No. 21.00208.5107.06/PD.