High-Performance Room-Light-Driven β -AgVO 3 /mpg-C 3 N 4 Core/Shell Photocatalyst Prepared by Mechanochemical Method

A new highly efficient, visible light active, silver vanadate/polymeric carboni-tride “core/shell” photocatalyst was prepared mechano-chemically prepared by grinding mixtures of β-silver vanadate and mesoporous graphitic carboni-tride. Besides the core/shell photocatalyst, β-silver vanadate/mesoporous polymeric carbonitride composites and supported mpg-C 3 N 4 @β-silver vana-dates were prepared. The materials were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), nitrogen ad-and de-sorption, diffuse reflectance UV-Vis measurement (DRS), infrared spectroscopy, Raman microscopy, and time-resolved photoluminescence spectroscopy. The photocatalytic performance of the materials was investigated in the degradation


Introduction
The sufficient supply of clean and drinking water for industrial, agricultural and human use, the supply of green, sustainable energy and protection of the environment from pollution are the main challenges to be solved in this century.The search for new materials and processes for more efficient use of energy resources and for remediation of water and the environment from pollution is of importance for solving these problems.The use of solar light as an ideal renewable energy source is believed to be the key to replace and save fossil energy resources with the efficient merits of the pollution less and non-exhaustible greenhouse gasses.Additionally, photocatalysis with solid-state semiconductors is of great potential for the development of new technologies addressing the above-mentioned concerns as hydrogen production from water and remediation of the environment from hazardous contaminations [1] [2] [3] [4].Photocatalysis is a green technology, can be economically driven by sunlight, and is renewable, environmentally benign and safe [5].
A new emerging problem even in developed countries is the contamination of water by low concentrated but harmful pharmaceutical, hormones and endocrine-disrupting compounds.Photocatalysis with titania is an attractive method for water remediation, which can provide clean and drinking water [6] [7].However, the titania photocatalysts still suffer from efficiency due to low quantum yield, low charge separation and the limited use of the spectral range of the sunlight.Attempts to improve the efficiency by increasing visible light response mainly by doping with metals and non-metals were performed.Despite the achieved success, the visible light response and overall efficiency are still limited [7] [8] [9] [10].Therefore, the development of new visible light-active photocatalytic materials is still demanded.
Many attempts to discover new visible light active materials with the band gap energy in the range of the visible light (420 -800 nm) were done.However, the band gap energy must be large enough to provide the valence band holes (h + ) and the conduction band electrons with appropriate potential required for water and pollutant oxidation and oxygen reduction to superoxide radicals ( • 2 O − ).For example, TaON, Ta 3 N 5 [11], CaBi 6 O 10 [12], Sr 0.25 Bi 0.75 O 1.36 [13], and Ag 3 PO 4 [14], BiVO 4 [15] were shown to be visible light active in the oxidative photocatalytic degradation of organic pollutions.
Especially, silver vanadate materials, Ag x V y O z were shown to be an active p-type semiconductor with improved visible light activity due to its narrower band gap energy of 2.0 -2.4 eV [16]- [24] compared to ZnO and TiO 2 which have higher band gap energies (~3.2 -3.4 eV) [5] [25].Recently, the influence of cation substitution in vanadates on the band gap was studied and compared to silver vanadate.Substitution with cerium led to a further decrease in the band gap energy [25].Besides, large progress was achieved in the development of visible active graphitic carbonitrides, an n-type semiconductor, which has opened a new pathway for increasing efficiency.The influence of elemental doping or heterojunction on photocatalytic activity was extensively studied [26] [27] [28] [29] [30].
Only very few papers reported on silver vanadate carbon nitride composites, where the synthesis was carried out in solution via precipitation of silver vanadate on carbon nitride support which also resulted in side formation of metallic silver.Atomic silver in parallel takes part in photocatalysis as an electronic sink helping e − -h + charge separation.In this paper, we report new β-AgVO 3 /mpg-C 3 N 4 core/shell and composite photocatalysts prepared by rapid solid-state mixing and thermal treatment.For comparative studies, β-AgVO 3 /mpg-C 3 N 4 composites were also prepared via co-precipitation in solution.The photocatalytic performance in the degradation of hazardous pharmaceutical contamination using ibuprofen (IBP) as a model compound was studied under sunlight equivalent UV-Vis and room light LED irradiation.The obtained composites have shown markedly improved activity compared with the single components.The β-AgVO 3 /mpg-C 3 N 4 core/shell photocatalyst displayed superior activity with 2 -3 times increased activity compared to that of the composites.The atom efficiency regarding the precious metal content was significantly increased.The contribution of reactive oxygen species (ROS) and electron holes was investigated using scavenger molecules.Additionally, the charge migration and recombination in the composites after optical excitation were explored with time-resolved photoluminescence experiments.

Materials and Synthesis
All of the chemicals were of analytical grade and used without further purification: sulfuric acid (Fisher Scientific, 95%), Pluronic F68 (Sigma-Aldrich, 96%), Benzoquinone (Sigma-Aldrich, 98%).In the following, we describe the syntheses of the 4 kinds of samples to fulfill our study.
1) Synthesis of beta silver vanadate (β-AgVO 3 ).Nanorods of β-AgVO 3 were prepared by the precipitation route as reported before with some modifications [16] [23].Typically, AgNO 3 (8.5 mmol, 1.443 g) and NH 4 VO 3 (8.5 mmol, 0.994 g) were dissolved separately in 50 mL deionized water.Both solutions were simultaneously poured drop-wise from separate funnels into a 250 mL round bottom flask containing 30 mL deionized water in duration of 5 minutes, followed by stirring for 30 minutes.The formation of a bright yellow precipitate was noted.The yellow suspended solution was refluxed with vigorous stirring for 3 hours.A change in color from yellow to orange was noticed.The reaction mixture was aged for 14 hours followed by filtration with F4 filter.The collected precipitate was washed with 50 mL deionized water and ethanol respectively.Finally, the orange-colored solid (nanorods) was dried at room temperature for 5 hours and then at 110˚C for 12 hours.In order to obtain silver vanadate powder, the material was calcined at 500˚C for 3 hours.In the process of calcination, β-AgVO 3 melts at 476˚C.After calcination β-AgVO 3 was obtained as a solid block and powdered with mortar and pestle.
2) Synthesis of mesoporous graphitic carbonitrides (mpg-C 3 N 4 ).The mpg-C 3 N 4 was prepared according to the reported procedure [43], however, using the amphiphilic block copolymer Pluronic F68 (EO 80 PO 80 EO 80 , M = 8350, Aldrich) as a template.Typically, the mixture of melamine (5 g) and template Pluronic F68 (1.5 g) was refluxed in deionized water for 1 hour.To the cool solution, 3 mL of H 2 SO 4 aqueous solution (H 2 SO 4 :H 2 O = 1:1) was added.A white precipitate was obtained by filtration and dried at 80˚C overnight.The obtained powder was heated up to 380˚C with a rate of 5˚C•min −1 , then to 600˚C by 1.5˚C•min −1 in a quartz tube under flow of argon, and kept at this temperature for 4 hours.The resulting yellow powder was recalcined in a muffle furnace at 300˚C for 3 hours in order to obtain the powdered sample.

Characterization Methods
The crystallinity and structural phase of all used materials were characterized by powder X-ray diffraction (P-XRD) with the X-ray diffractometer STADI-P (STOE) and Ni-filtered Cu-Kα 1 radiation (λ = 1.5418Å) in transmission.A curved Ge (111) monochromator (40 kV, 40 mA, linear PSD) was used.The Advances in Chemical Engineering and Science morphology and size of the catalysts were characterized on a LIBRA 120 transmission electron microscope (TEM) operated at 120 kV using carbon-coated copper grids.The porosity, specific surface area, pore volumes and pore sizes were determined by N 2 -adsorption and desorption isotherms using an automated device "Sorptomatic" (Porotec, ThermoScientific).The optoelectronic properties of the samples were studied with UV-Vis diffuse reflection measurements.The spectra were recorded on a fiber-coupled Araspee 2048 (Avantes) spectrometer equipped with an Avalight-DHS light source and a special reflection device suitable for measurements of solid materials.The band gap energies of the materials were obtained by a Tauc plot, in which for direct band gap (hνα) 2 is plotted against the photon energy hν, where h is the Planck's constant, ν the photon frequency, and α the absorbance at the considered frequency.The band gap energy is calculated using Schuster-Kubelka-Munk theory [44] [45] [46] [47] [48].The FTIR spectra were recorded in the spectral range of 500 -4000 cm −1 using a Nicolet 380 FT-IR spectrometer with a Smart Orbit ATR device.A Lab RAM HR 800 HORIBA Jobin Yvon Raman spectrometer equipped with an Olympus BX41 microscope with changeable lenses was used to record Raman spectra.The excitation of the samples was performed with a red laser (633 nm, 17 mW) or an infrared laser (785 nm, 100 mW) at ambient temperature.ESI-TOF-MS measurements were performed using an electrospray ionization mass spectrometer coupled with HPLC system 1200/ESI-TOF-MS 6210 (Agilent) to investigate qualitatively the formation of intermediates during photocatalytic treatment of the aqueous ibuprofen solution.The luminescence lifetimes and spectra were measured by a streak camera system (Streakscope C10627, Hamamatsu).The samples were illuminated with a frequency-doubled femtosecond pulse at 388 nm delivered from a Ti: Sapphire laser system (CPA 2001, Clark MXR).The sample powders were attached to glass substrates by a double-faced adhesive tape.The photon flux of the excitation was kept the same for all measurements to avoid intensity-dependent differences.

Photocatalytic Testing and Analysis
The photocatalytic abatement and adsorption of nonsteroidal anti-inflammatory drug IBP were studied under batch condition.The 250 mL glass beaker (batch reactor) containing 250 mL of a 10 ppm aqueous IBP solution and 10 mg of the catalyst was placed into a closed aluminum box equipped with a visible white light lamp (Toshiba 16 W, LED cold white light lamp), which is usually used for illumination of offices (rooms).For the UV-Vis illumination, four UV-Vis solarium lamps (Phillips) were used on the top with a total power of 60 W (4 lamps × 15 W, Phillips).The irradiation intensity of the experimental setup was ca.3.2 mW/cm 2 in the case of UV-Vis solarium lamp.These lamps mainly simulate the UV part of sunlight besides additional emission lines in the visible light range.
The solution was mixed magnetically during the photocatalytic experiments.
For quantitative analysis of the irradiated solution, aliquots were taken at certain time intervals using a syringe equipped with a PTFE filter.Adsorption experi- UV-Vis spectrometer (Varian, Cary WinUV).After a particular interval of time, the amount of total organic carbon in aliquots was analyzed with a Shimadzu TOC-L CSH/CSN device.The textural properties of the mpg-C 3 N 4 , β-AgVO 3 , and the composite samples were investigated by nitrogen adsorption-desorption measurements (Figure 3).The silver vanadate is nonporous showing only a very low nitrogen uptake at a relative pressure p/p 0 ≤ 0.3 due to adsorption of nitrogen at the surface of the large silver vanadate nanorods (ca. 5 m 2 /g).In contrast, the mpg-C 3 N 4 is mesoporous giving rise to a high nitrogen uptake at a high relative pressure of p/p 0 > 0.8.The specific surface area amounts to ca. 44.5 m 2 /g (BET).The specific surface area and pore volume are highest with catalysts containing 20% -30% of silver vanadate.The mesoporosity is highest with the core/shell catalyst.At higher silver vanadate loading the specific surface area pore volume decreases down to ca. 19 m 2 /g and 0.24 cm 3 /g, respectively, with the 70% β-AgVO 3 /C 3 N 4 composite (Table 1).Vibrational spectroscopy.The FTIR-ATR spectra of β-AgVO 3 /mpg-C 3 N 4 and the corresponding β-AgVO 3 /mpg-C 3 N 4 composites in the mid-infrared range between 550 cm −1 and 1600 cm −1 are depicted in Figure 4.The FTIR-ATR spectrum of β-AgVO 3 shows characteristic bands for VO vibrations in the range between 400 -1000 cm −1 [51].The strong and relative broad absorbance at ca. 793 cm −1 can be assigned to symmetric V-O stretching vibrations [52].Additionally, weak absorbances appear at ca. 671, 829, 857, 890, and 966 cm −1 are in line with other observations [43].The vibrational band at ca. 966 cm −1 is assigned to the asymmetric stretching vibrations in the terminal vanadyl groups VO 3 [53].The vibrational band at ca. 890 cm −1 is ascribed to the V = O stretching mode.The stretching vibrations of both V-O and Ag-O-V give rise to the band observed at 857 cm −1 [54].The infrared spectra give no implication for the presence of impurities like vanadium pentoxide, for which vibrations should appear at ca. 1122, 833 or 617 cm −1 arising from the V=O apex stretching of the pyramid [55].Additionally, the absence of N-H, N-O and N=O vibrational bands above 3000 cm −1 and in the range between 1400 -1350 cm −1 , respectively, indicate that the prepared β-AgVO 3 contains no residual ammonia or nitrates.

Results and Discussion
The IR spectrum of the prepared and calcined mesoporous carbonitride shows main vibrational bands in the ranges between 2500 -3600 cm −1 and 800 -1600 cm −1 .In the first region, a broad absorbance appears with the maximum centered at ca. 3160 cm −1 that can be assigned to hydrogen-bonded N-H and O-H (residual water).The C≡N vibration, usually appearing at ca. 2100 cm −1 , was not observed.The complex spectrum observed in the range between 800 -1600 cm −1 is characteristic of the presence of C-N (800 -1300 cm −1 ) and C=N bonds (1500 -1600 cm −1 ).The intense band at 806 cm −1 was assigned to C-C and C-N stretching vibrations.The FTIR-ATR spectra of the β-AgVO 3 /mpg-C 3 N 4 composites resemble the superposition of the spectrum of the β-AgVO 3 and mpg-C 3 N 4 components indicating that no chemical reaction appears during the composite preparation.However, the relative transmittances of the vibrational bands of the two components have changed with the composition.Interestingly, the FTIR-ATR spectrum of the core/shell (20% β-AgVO 3 /mpg-C 3 N 4 ) material is dominated by the vibrational bands of the mpg-C 3 N 4 , arising at ca. 806 cm −1 .The strong vibrational band of the silver vanadate at ca. 793 cm −1 nearly disappeared.This indicates that in the case of core/shell the silver vanadate nanorods are covered by mpg-C 3 N 4 as typically expected for a core/shell catalyst (compare the TEM images (Figure 2).While in the case of a higher content of β-AgVO 3 the nanorods are not completely covered which gives rise to a low energy shoulder at the mpg-C 3 N 4 mode (Figures 4(c)-(d)).In the case of the core-shell catalyst (Figure 4(e)) the 800 cm −1 band is very narrow, which holds also for all the absorbances observed between 1200 -1600 cm −1 and between 2900 -3400 cm −1 .The latter is resolved into three maxima arising at ca. 2900, 3200, and 3300 cm −1 .These findings point to a higher "crystallinity" or "layered arrangement" of the loaded mpg-C 3 N 4 layer in the core/shell catalyst compared to the bulk mpg-C 3 N 4 (Figure 4).Advances in Chemical Engineering and Science Raman spectra of β-AgVO 3 /mpg-C 3 N 4 core/shell and composite materials, as well as the starting components, were recorded using a confocal microscope allowing the spatial-resolved measurements of samples.The complimentary Raman spectrum of a single bare β-AgVO 3 nanorod (Figure 5) is in line with reported spectral data, confirming the structural origin of the prepared material [56].The strong Raman peak at 886 cm −1 is assigned to vibrations of bridged O-V-O units [57] [58] [59].The stretching mode of the VO 3 groups gives rise to a Raman peak at 845 cm −1 .The strong Raman peak at 810 cm −1 can be assigned to the Ag-O-Ag stretching vibrations.The bridged V-O-V entities give rise to asymmetric and symmetric stretching vibrations appearing at 733 and 520 cm −1 , respectively.Additional Raman peaks located at 392, 339, 249, 173, and 132 cm −1 are characteristic signatures of the β-AgVO 3 and can be referred to as the channel-structured β-silver vanadate [55] The pure mpg-C 3 N 4 shows a strong fluorescence.Single Raman peaks cannot be detected.Interestingly, the β-AgVO 3 /mpg-C 3 N 4 core/shell catalysts β-AgVO 3 shows no Raman lines.The C 3 N 4 fluorescence completely overlaps the Raman spectrum of the β-AgVO 3 .This finding is in line with a complete covering of the silver vanadate rods by carbon nitride layers.Uncovered β-AgVO 3 could not be detected indicating the formation of core/shell materials.
Light absorption and band structure.The optical properties of prepared β-AgVO 3 , mpg-C 3 N 4 , and the corresponding β-AgVO 3 /mpg-C 3 N 4 composite core/shell catalysts were studied by Fourier-transform diffuse reflectance UV-Vis spectroscopy.The obtained spectra and derived Tauc plots are shown in Figure 6.The light absorption is extended to the visible light range for all the samples at ca. 600 nm.The light absorbance of silver vanadate β-AgVO 3 is red-shifted compared to carbonitride and silver vanadate/carbonitride samples.The absorption edge is well S-shaped and increases nearly linearly reaching a first absorbance maximum at ca. 440 nm.In contrast, the absorbance of the mpg-C 3 N 4 , and the corresponding β-AgVO 3 /mpg-C 3 N 4 composite catalysts increases in two steps, a slow increase between 600 to 450 nm followed by a steep slope at <450 nm reaching the maximum absorbance at 380 nm.The shape of the spectra is very similar.The differences in absorbance are reflected in the Tauc plots.The band gap of β-AgVO 3 calculated from Tauc plots, or obtained from the UV-Vis absorption edge is of lower energy (2.1 eV) compared to mpg-C 3 N 4 (2.74 eV), the composites and the core-shell catalyst.The absorbance of the silver vanadate in the visible range is distinctly higher (Figure 6 left).The diffuse reflectance UV-Vis spectra of the corresponding β-AgVO 3 /mpg-C 3 N 4 composites are surprisingly dominated by the carbonitride and nearly coincide with it.The optical band gaps of the composites are close to that of the mpg-C 3 N 4 and amount to ca. 2.69 -2.74 eV (461 -452 nm).

Photocatalysis
Photocatalytic performance.The photocatalytic performance of the β-AgVO 3 , mpg-C 3 N 4 , and their composites and core-shell catalysts were checked in the abatement of ibuprofen in an aqueous solution at a very low concentration and low catalyst-to-substrate ratio.Photocatalytic degradation experiments were performed both, under UV-Vis and Visible light irradiation, with comparatively low intensity (room or sun (day) light equivalent).Please note that usually much higher catalyst loadings and irradiation intensity are applied with the commonly used 300 -1000 W xenon, mercury or halogen lamps.
Irradiation with UV light.The absorption changes in UV-Vis spectra of ibuprofen solutions due to irradiation with UV and visible light are shown in Figure 7.For all β-AgVO 3 /mpg-C 3 N 4 composite catalysts, a decrease of the aromatic ring absorbance at 193.5 and 222 nm is observed due to the degradation or cleavage (opening) of the aromatic ring.At the same time, a new absorbance appears at ca. 260 nm.Its intensity increases and later decreases again with prolonged photocatalytic treatment.This band is assigned to the formation of reaction intermediates [6] [49] [60].
The relative abatement of ibuprofen vs. photocatalytic treatment time over different (5% -70% β-AgVO 3 /mpg-C 3 N 4 ) composites compared to pure β-AgVO 3 and mpg-C 3 N 4 are shown in Figure 8.Interestingly, an apparent increase in the abatement is observed in the first 30 min. of photocatalytic treatment, which is not observed in the dark.Obviously, it is due to the formation of reaction intermediates, partial oxidation products or radicals, which show a higher extinction coefficient than the starting IBP solution.Thereafter, a gradual decrease is observed due to the degradation of the IBP and intermediates.About 5% abatement of IBP is achieved after 8 h with the mpg-C 3 N 4 alone.The addition of β-AgVO 3 (composites) leads to an improvement of the degradation to 10% and 22% with 5% and 10% β-AgVO 3 loading.Surprisingly, a boost of the activity is observed with the core/shell (20% β-AgVO 3 /mpg-C 3 N 4 ) material.Ca. 80% abatement is achieved after 8 h of photocatalytic treatment under UV-Vis irradiation.However, further enhancement of the β-AgVO 3 content to 70% leads again to a decrease of the degradation to ca. 55%.It is concluded that the exceptional high activity of the 20% β-AgVO 3 /mpg-C 3 N catalyst is related to the core/shell nature of this material, where the mpg-C 3 N 4 is forming a thin (7 -10 nm) shell around the β-AgVO 3 nanorods as evidenced by TEM.Pure β-AgVO 3 shows only low activity with the formation of some partial oxidation products leading to an increase in the absorption band at ca. 193.5 nm according to UV-Vis spectroscopic studies.Irradiation with visible room light.The degradation behaviour of the β-AgVO 3 / mpg-C 3 N 4 composite catalysts under room light visible irradiation is similar to the results obtained under UV-Vis solarium light irradiation (Figure 9).The photocatalytic degradation of the IBP proceeds somewhat slower.Again, the core/shell catalyst (20% β-AgVO 3 /mpg-C 3 N 4 ) showed superior activity.Namely ca.80% of ibuprofen degradation was achieved after 13 h.Again, the formation of reaction intermediates was observed in UV-Vis spectra of the reaction solution at the beginning of the treatment giving rise to absorbance at ca. 260 nm.
The other composites showed a distinctly lower activity with up to ca. 30% of degradation over 30%, 50% and 70% β-AgVO 3 /mpg-C 3 N 4 composites.Hence, the difference in the photocatalytic degradation activity between the core/shell catalyst is much more pronounced under room light than under UV irradiation.
In summary, the catalyst 20% β-AgVO 3 /mpg-C 3 N 4 shows the best performance resulting from the core/shell structure.
As under UV-Vis irradiation, an increase of the pollutant absorbance was observed in the first two hours of treatment.This effect is highest for the less active catalyst β-AgVO 3 and is assigned to the formation of intermediate partial oxidation products like hydroxylated side chains and benzene products with increased extinction coefficients.The composite catalyst 5% β-AgVO 3 /mpg-C 3 N 4 showed the same effect while it was not observed with the active core-shell catalyst confirming the improved oxidation power of these catalysts.Both, irradiation with sunlight UV as well as with room light, cause similar changes in the UV-Vis spectra of the irradiated solution indicating that there is no difference in the degradation mechanism between the two light sources.
Finally, a 20-time increase of photocatalytic activity was noted with the core/shell catalyst compared to the single mpg-C 3 N 4 , while the increase is markedly lower with the composites (ca. 9 times) or hybrid systems [61].Compared to silver vanadate the activity in the degradation of ibuprofen is enhanced almost by 100 times under sunlight equivalent UV and Visible light.Mineralization.The TOC measurements of the photocatalytic solution show that the photocatalytic treatment over the core/shell catalyst leads to ~75% degradation (mineralization) of the IBP (Figure 10).The determined degradation is in line with the UV-Vis spectroscopic results.However, the degree of mineralization is lower than the abatement determined by UV-Vis spectroscopy.The latter is sensitive to the aromatic ring opening only and not directly related to the complete degradation of the molecules to carbon dioxide and water.
In O − ) can be involved in the photocatalytic degradation process, but the contribution is different from catalyst to catalyst.We have studied the photocatalytic degradation in the presence of the h + , OH • , • OOH scavengers, EDTA, t-butanol and benzoquinone [62] [63] [64] respectively, in order to differentiate between the active species involved with the core/shell and composite catalysts (Figure 11).Advances in Chemical Engineering and Science  The degradation of IBP reaches up to 80% over the pure core/shell catalyst in 8 hours and only ca.50% over the composite catalyst even when the silver vanadate content of the composite was much higher.The core/shell catalyst is superior to the corresponding composites especially considering the atom efficiency based on the noble silver under UV as well as under visible light.In both cases valance band holes and conduction band hydroperoxyl radicals are the predominant species in the photocatalytic degradation, however, the effective number of holes is ca.doubled in the case of the core/shell catalyst according to the above-discussed reasons.Afterward electrons and holes migrate in a one-dimensional random walk motion from one lattice site to another.The motion most likely takes place perpendicular to the carbonitride sheets i.e. the carrier is hopping from plane to plane.

Charge Transport and Possible Mechanism
If the charges meet again the hole and electron recombine leading to a singlet or triplet exciton which seems to decay rapidly.The singlet excitons can radiate during their short lifetime resulting in the detected fluorescence.The described geminate recombination process results in a charge carrier density n which obeys the rate equation The geminate recombination coefficient gem γ depends thereby on the time and the dimensionality of the motion.For a one-dimensional motion, the geminate coefficient reads ( ) ( ) with the recombination rate rec k and the hopping rate hop k .Solving this equa- tion for rec hop k k yields the time depended on photon emission flux [68].

H.
Kosslick et al.DOI: 10.4236/aces.2021.114018295 Advances in Chemical Engineering and Science ments were carried out in the dark.The remaining IBP content in the samples was determined by the change of the intensity of IBP band at 320 nm using a

3. 1 .
Material CharacterizationStructure. The XRD patterns of β-AgVO 3 and composite catalysts measured in the 2θ-range from 5˚ to 65˚ are shown Figure1, respectively.The observed diffraction pattern of the prepared silver vanadate corresponds to the β-AgVO 3 phase (Figure1(a)).The diffraction peaks were well indexed to monoclinic β-AgVO 3 (space group C 2 /m), with lattice constants of a = 18.1060Å, b = 3.5787 Å and c = 8.0430 Å, α and β = 104.44˚.These lattice constants correspond well to those given in the literature (COD: 96-150-9498), and no other patterns from possible impurities/modified lattices were detected.The rather narrow diffraction peaks indicated that the material was highly crystalline.No by-products such as metallic silver nanoparticles could be observed in the XRD pattern.Usually, the XRD pattern of mpg-C 3 N 4 is characterized by a low intense reflection ca.2θ = 13˚ and a high intense peak at ca. 2θ = 27˚.The XRD pattern of mpg-C 3 N 4 of the β-AgVO 3 /mpg-C 3 N 4 composites is different from the reported ones[49] and show a broad and intense reflection at 12˚ -13˚ and a low intense peak at ca.27.5˚These reflections are attributed the (210) and to the (002) plane of mpg-C 3 N 4 , respectively[50].The peak at 13.22˚ related to an in-plane structural packing motif of the tri-s-triazine units of the polymeric chain.The (210) reflection is sensitive to the structural order and its intensity increases with the crystallinity.The (002) peak is related out of plane motif of the polymeric layers.The highest intensity of the (002) peak is observed with the 20% β-AgVO 3 /mpg-C 3 N 4 core/shell catalyst material.It is not observed with 70% β-AgVO 3 /mpg-C 3 N 4 which contains a lot of bulky g-C 3 N 4 .It is concluded that the high intensity diffracted at 27˚ is related to the formation of ordered layers on the crystal surface of β-AgVO 3 nanorods, i.e. the formation of a "core/shell" structure.The parallel alignment of the mpg-C 3 N 4 polymeric chains at the planar crystal faces of the β-AgVO 3 nanorods enhances the crystallinity.Morphology and texture.The TEM images of the prepared β-AgVO 3 and β-AgVO 3 /mpg-C 3 N 4 composites are shown in Figure2.The TEM images show that the silver vanadate consists of rods of the diameter 20 nm to 60 nm, with the length of submicron range.Mostly these rods are stacked together or agglomerated.The appearance of a composite particle depends strongly on the carbonitride content.Interestingly, with the 20% -30% β-AgVO 3 /C 3 N 4 materials complete covering of the body of the β-AgVO 3 nanorods by carbonitride is observed, leading to the formation of the core/shell catalysts.Figure2(b), Figure 2(c) shows β-AgVO 3 /mpg-C 3 N 4 core/shell catalyst particles consisting of a ca. 25 nm thick silver vanadate nanorods completely surrounded by a ca.7 -12 nm thick carbonitride shell (layer).In the case of the low and high silver vanadate content, 5% -10% β-AgVO 3 /C 3 N 4 , or (≥40% β-AgVO 3 , the physical mixing and calcination led to agglomeration of the mpg-C 3 N 4 component and attachment of the β-AgVO 3 particles, as typically found with agglomerated composites.
the case of Visible light irradiation, TOC results show only a minor change in the carbon content in the first 3 h of photocatalytic treatment.This finding is in line with the UV-Vis spectra of room light treated solution which indicates the formation of partial oxidation products, e.g. by hydroxylation of the side chain which causes no loss of carbon.Over pure AgVO 3 and mpg-C 3 N 4 ibuprofen is nearly not mineralized.Reaction intermediates.ESI-TOF-MS measurements in the positive and negative mode were carried out to study the formation of reaction intermediates during the cause of photocatalytic treatment using UV and Visible light irradiation.The negative ESI-TOF-MS spectrum of the starting solution shows the [M-H] − mass peak of the IBP at ca. m = 205 and by-product mass peaks (likely partial oxidation product of IBP) at ca. m = 273, 263, 301 and others.Additionally, mass peaks at ca. m = 433, 501 and 661 were assigned to IBP sodium salt dimers and trimers.Already after 10 min. of treatment with UV-Vis or room light irradiation the appearance of the ESI-TOF-MS spectra markedly changed.A couple of new mass peaks assigned to partial oxidation and higher molecular mass polymerization products appeared.The intensity of the mass peaks generally decreases with prolonged treatment time.The composition of the photocatalytic treated solution regarding the nature of contained species was not markedly changed with only some exceptions.The species with the mass peak m = 112 and in part m = 273 (measured in negative mode) and m = 90.9 and m = 130 (positive mode) are more recalcitrant against the photocatalytic treatment.Overall, the core/shell catalyst leads to more efficient degradation of the organics.After 8 h UV or 13 h visible light irradiation, respectively, substantial degradation of the IBP is evidenced by the negative and positive ESI-TOF-MS spectra, generally confirming the UV spectroscopic and TOC finding of high degradation (80% and 75% respectively).The intensity of the ESI-TOF-MS signals decreases after photocatalytic treatment distinctly after 8h of treatment.Reactive species.Generally, a couple of active species like reductive conduction band electrons (e − ) and oxidative valance band holes (h + ), hydroxyl radicals (OH • ), hydroperoxyl radicals ( • OOH) and oxygen radical anions ( • 2

Figure 12 .
Photoluminescence measurements were carried out in order to get a deeper insight into the charge transfer processes.The charge migration mechanism of the β-AgVO 3 /mpg-C 3 N 4 composite catalyst was investigated by time-resolved photoluminescence spectroscopy.After optical excitation of the mpg-C 3 N 4 -composite at 388 nm, a broad fluorescence spectrum and non-exponential fluorescence decay within several nanoseconds were observed.This temporal behavior was already observed in several investigations of pure mpg-C 3 N 4[65] [66].The results of the Possible mechanism.The most active species in mpg-C 3 N 4 materials are electron-holes and superoxide radical anions.As shown by the scavenger studies above, the number of holes of the core-shell catalyst is doubled compared to the most active other composite catalysts.Both structure and morphology of the core-shell and composite materials are qualitatively different.The core/shell catalyst (Figure13) is superior because the silver vanadate nanorods are 1) completely covered by mpg-C 3 N 4 ; 2) mpg-C 3 N 4 forms thin layers with the 2D plains of the mpg-C 3 N 4 sheets are parallel aligned to the flat surface facets of the β-AgVO 3 nanorods; and 3) compared to the bulky C 3 N 4 composite particles, in the core/shell, the mpg-C 3 N 4 polymers planes are arranged layer by layer and exposed to the outer surface[69].The improved long-range order of the optical tri-s-triazine units in the 2-dimensional mesoscopic polymer matrix enhances markedly the charge carrier mobility[70].The mesoporous structure is good to promote the transportation of charge carriers from/to the β-AgVO 3 core nanorod through the shell to discharge the core, to make it ready again for the light absorption.This special architecture diminishes the surface charge recombination of e-h pairs of β-AgVO 3 , and partially on the mpg-C 3 N 4 at the interface, and improves the charge separation of mpg-C 3 N 4 e-h pairs in the bulky layer.The parallel H. Kosslick et al.DOI: 10.4236/aces.2021.114018309 Advances in Chemical Engineering and Science

β-AgVO 3 /
photocatalytic active in the degradation of ibuprofen under UV and visible room light irradiation.The photocatalytic activity was markedly higher compared to the single components and the highest activity was found with 20% β-AgVO 3 /C 3 N 4, specifically under room light irradiation.The superior activity results from the core/shell structure of this material which boosts photocatalytic degradation.