Production of Fuel Briquettes from Bamboo and Agricultural Residue as an Alternative to Charcoal

The study was done to explore the potential of producing fuel briquettes that could meet the need for energy in Uganda, especially Kampala city. The primary objective of this work was to produce fuel briquettes from homogeneous and heterogeneous combinations of carbonized maize cobs, Bamboo poles and charcoal dust. For the primary objective to be achieved, the main activi-ties which were performed included; chopping bamboo poles, sorting maize cobs, carbonization, crushing, binder preparation, mixing, extrusion, drying and quality assessment of the fuel briquettes. The maize cobs and charcoal dust used for this work were purchased from the farmers and charcoal sellers respectively from the districts of Luwero and Nakaseke. Bamboo poles were provided by Divine bamboo group. The homogenous combinations included 100% maize cob char, 100% bamboo char and 100% charcoal dust. Heterogeneous combinations included 75% bamboo char + 25% charcoal dust and 25% bamboo char + 75% charcoal dust. The test results for both homogenous and heterogeneous combinations of fuel briquettes had ranges of moisture content 8% - 11%, Volatile matter 12% - 23%, Ash content 33% - 39%, Heating Value 16 - 22 MJ/Kg, Fixed Carbon 30% - 51% and moisture content 8% -9%, Volatile ty to use bamboo woody feedstock in combination with other agricultural waste feedstock for the production of fuel briquettes. We can increase the quality and production of fuel briquettes by using alternative feedstock sources rather than degrading the environment through deforestation.


Introduction
The cooking energy mix in Uganda is dominated by unprocessed biomass (as firewood), with charcoal the next most utilized fuel. In Uganda, 95% of all Ugandan households rely on charcoal, wood, or other forms of biomass for their household cooking needs [1]. According to the Global Alliance for Clean Cook stoves [2], unprocessed biomass makes up the majority of cooking fuels in Uganda.
Recent reports [2] [3] have indicated that the majority of rural households use firewood for cooking whilst in urban areas households use both firewood and charcoal. The prices of fuel especially in urban centers continue to rise and are subject to seasonal fluctuations as firewood becomes increasingly unavailable. This is further exacerbated by the decreasing land area covered by forest that is estimated from 15% to 26% of Uganda's land area [2].
Biomass has historically been a cheap and accessible source of fuel for Uganda's population but this is unlikely to continue as a high dependency is raising concerns for the sustainability of the resources as human populations and competing demands increase [4]. Furthermore, the unsustainable depletion of woody biomass reserves portends several negative consequences for the country's population, including increased energy insecurity, unaffordable rise in wood fuel prices, climate change from deforestation and increased rural-urban migration. The conversion of forests to other land uses contributes 38% of Uganda's national GHG emissions [5]. Degeneration of biomass is further exacerbated by the lack of effective interpectoral and institutional coordination, deteriorating feedstock sources, market development challenges and difficulties in changing mindsets and behavior towards the transition to modern forms of energy [6].
The Bamboo plant is now famous for being one of the top solutions to quick economic growth and mitigation of climate change due to its numerous unique characteristics. Uganda has embraced this plant with several small-scale mushrooming bamboos-based businesses [7]. Furthermore, bamboo plants are the fastestgrowing plant species on Earth (approximately 91 -122 cm per day) and have been reported to be widely spread in tropical and subtropical climate regions [8] [9] [10].
Unfortunately, much as several developmental projects on energy are coming up and thriving in other countries using bamboo, Uganda has not yet explored this option. Therefore, the aim of this study was to evaluate the potential of bam-boo for briquette fuel production.

Collection and Sorting and Weighing of the Materials
The maize cobs used for this work were purchased from the farmers from districts of Luwero and Nakaseke. Bamboo poles were provided by Divine bamboo group. Maize cobs and bamboo poles were sorted and chopped to a reduced size respectively, in order to fit in the carbonizer. A known weight of both maize cob and bamboo chopped materials were loaded into the carbonizer at different times for carbonization.

Carbonization of the Materials
Carbonization of the materials was done using a fixed kiln purely made of masonry material such as bricks, cement, sand and some metal pieces of high heat resistance. The exhaust gases leaving the carbonizer were less harmful to the environment due to the auto thermal treatment inside the chimney during biomass material carbonization. The carbonizer has a capacity of 1 ton and efficiency of 25% for agro waste such as maize cobs ( Figure 1).

Crushing System
The crusher used was fabricated with a feeding back, grinding hammer and outlet where the crushed char dust is collected from. Its powered by 7.5 Hp electric motor running on 3 phase with a capacity of at least 1 ton per day.

Preparation of the Binders
For this study, molasses was used as the binding material for all the briquette samples. The mixing proportions of the binder were based on the mixing ratios of each sample.

Material Mixing Process
During the production process, the material was mixed on the floor using a hoe and a sped as shown in Figure 2 below.

Briquettes Extrusion
The extruder which was used was built with different parts such as the feeding bucket, convey channel, extrusion screw and an outlet. The extruder machine is powered by electrical powered motor of 3 phases, 7.5 Hp. The extruder had an output capacity of at least 1 ton per day.

Briquette Drying Process
Drying of the sample briquettes was done under the structure covered with UV foil to enable high concentration of heat with in the structure.

Analysis of Physical and Chemical Parameters
The apparatus used was the computerized Thermographic Analyzer with an in built and integrated ELTRA 84 GmbH Precision Digital weighing scale. The analyser is integrated with a non-oxidizing (99.99% pure argon gas or 99.999% pure Nitrogen gas) environment and an oxidizing (99.99% Pure oxygen) environment which are computer controlled by Tga Software version: Tga 1.4.2.12 with internally programmed application for analyzing physical properties of biomass in four stages namely moisture content, volatile matter, fixed carbon and ash content. Specimens were extracted from each of the samples submitted. They were homogenized by crushing into a powder. The 3 specimens of minimum weight 1100 milligrams are placed in three of the 19 work stations of the Thermographic Analyser. An inbuilt program of the Tga software version 1.4.2.12 for analyzing biomass is triggered to commence the analysis which lasts a minimum of 6 hours. The moisture content, volatile matter and fixed carbon are analyzed in a purely non oxidizing environment and ash content is analyzed in a pure oxidizing environment.

Heating Value
The apparatus used included An IKA C2000 Automated Digital bomb calorimeter and a Precision Denver S1-234 Digital Weighing scale (±0.0001 g). 3 specimens were extracted from each of the sample you submitted and weighed on a Precision Denver S1-234 Digital Weighing scale (±0.0001 g) and its mass recorded. The specimens were then put a crucible and enclosed a bomb carrying out the heating value tests independently. The higher heating value of the samples was measured using an internal programme in the IKA C2000 Digital bomb calorimeter. Samples weighing between 700 mg to 1500 mg are placed in the bomb calorimeter and subject them to complete combustion in an adiabatic environment which is internally stabilized by a computer, heaters and circulating water. The Higher Heating Value (HHV) was calculated from measured temperature increase in the adiabatic system by a software and results are given.

Bulky Density Tests
The apparatus used were ELTRA 84 Digital weighing scale and Vanier caliper. Three specimens were extracted from each of the sample. The specimen's dimensions were measured and weight taken at room temperature using the digital weighing scale and the results were tabulated. The formula below was used for determining the bulky density. m v ρ = where: v = v 1 − v 2 v 1 : Volume based on the external diameter; v 2 : Volume based on the internal diameter.

Compression Tests
Three specimens were extracted from each of the sample by cutting using a hack saw blade and were tested on a Computerized Testometric Universal Testing Machine made in UK and results were tabulated.

Drop Resistance Tests
Each of the two samples was pre weighed, recorded the mass weight as M 1   The present section describes the chemical parameters of the investigated mate-Journal of Sustainable Bioenergy Systems rials, the required levels of which must be respected in practice, otherwise their burning (in the form of bio-briquette fuel) could cause environmental pollution.
Heating value/calorific value is the most important indicator of fuel chemical quality, which indicates the amount of energy released from fuel during burning [11]. The heating values for all feedstock ratios ranged from 16.027 MJ•kg −1 to 21.26 MJ•kg −1 (Figure 3). Therefore, the tested materials exhibited a high level of such an indicator; thus, these results were satisfactory. However, results for briquette sample with 100% BC and sample mixture of 75% BC/25% CD were very good, thus proving the significant potential of bamboo for fuel briquette production as reported by other researchers [8] [12] [13].
As observed in Figure 4,   The range of values for volatile matter (11.97% and 23.2%) of briquettes produced in this study ( Figure 5) is lower than range of 24.2% to 34.95% obtained by falemara et al. [15] for briquettes produced from agricultural wastes and wood residues, 43% to 49% obtained by Adegoke et al. [16] for briquettes produced from mixed sawdust of tropical hardwood species, 72.33% to 77.44% for briquettes produced from three hardwood species Emerhi et al. [17], and 68% stated by Ige et al. [18]. However, results for briquette sample with 100% BC (11.97%) and sample mixture of 75% BC/25% CD (13.3%) were very good, thus proving the significant potential of bamboo material for fuel briquette production.
Volatile matter is a mixture of short-and long-chain hydrocarbons such as combustible or incombustible gases or combination of both released during burning.
These gases strongly affect the combustion behavior of briquettes [15] [19]. Lower volatile matter is an indication that the briquettes might not be easy to ignite, but once ignited they will burn smoothly, while high volatile matter results in high combustibility at low ash content [15]. As such, blending of higher volatile material (wood residues) with lower volatile material (agro wastes) resulted in the production of optimum quality briquette. In contrast, the higher the volatile matter of a briquettes, the higher the amount of emissions during burning. This implies that low volatile matter is required for good quality briquette which agrees with the results of the present study.
As observed in (Figure 6), high ash content values were observed in the present study and it ranged from 26.8% to 44%. The results of the present study matches those that were reported by Ige, et al. [18], Ikelle and Anyigor [20], Ogbuagu, et al. [21] and Emerhi [17] which ranged from 18%, 18.67% to 22.06%, 10.44% to 43% and 19.07% to 21.72% respectively. The high ash content could be a reflection of contamination of material due to external impurities (dust, soil) as reported by Brunerová, et al. [8]. Higher ash content in a fuel usually leads to higher dust emissions, air pollution, and affects the combustion volume and efficiency of combustion.  Fixed carbon gives an indication of the proportion of char that remains after volatile matter is distilled off. It gives a rough estimate of the heating value of a fuel and acts as the main heat generator during burning [15] [22]. The fixed carbon content of briquettes produced ranged from 30.4% to 50.6% for all the samples. However, the fixed carbon as reported in this study is relatively higher than 9.06% to 11.46% obtained by Adegoke, et al. [16], 5.75% to 8.28% stated by Emerhi [17], 16.80% -20.90% quantified by Adetogun, et al. [23] and 15% fixed carbon estimated by Ige, et al. [18] who all worked on briquettes produced from homogenous particles. A good quality and efficient fuel briquette is dependent on lower volatile matter and ash content with a higher fixed carbon content which agrees with results of the present study [24] (Figure 7).

Physical Properties (Drop Resistance (DR), Compressibility Strength (CS) and Bulky Density (BD))
The present section describes the physical/mechanical parameters of the investigated materials, the required levels of which must be respected in practice.
Drop resistance refers to the ability of briquettes to withstand drops and collisions during transportation and storage [25] [26]. By referencing to UNBS US 765-2: 2019 (Uganda National Bureau of Standards National Standard), where the required drop resistance to meet the good quality of briquette ranges from 2.5% to 10%, the results from the present study, were slightly higher than the standard except for sample with 100% BC with a value of 7%. Kaliyan and Morey [27] reported a lower drop resistance value of 0.50% -0.97% for corn Stover briquettes.
The variance from the required standard can be attributed to the lower particle size due to mechanical interlocking of relatively short fibers [28] (Figure 8).
The ability of briquettes to withstand destructive forces during handling, storage, and transportation can be evaluated by compressive strength. The compressive strength of the briquettes indicates the amount of force required to break the briquette structure [25]. As shown in Figure 9, the compressibility strength  for all the samples was lower than that reported by other researchers. The deviation in the results might have come about because of the mixing ratios and process temperatures. The effect of mixing ratios and process temperatures on the compressive strength of briquettes has been reported in recent publications [26] [29].
Observed bulky density ρ data proved satisfactory results for all cases except sample with 100% BC. A bulk density of 869.1 kg/m 3 was observed for the heterogeneous mixture of 75% BC and 25% CD, which indicates high quality bio-briquette fuel. As reported previously, bio-briquette fuel mechanical quality increases with increasing bulk density ρ [8] [11] [30] because it indicates bio-briquette fuels' longer burning time and larger amount of produced heat [31]. According to other

Conclusions
The study examined the physical and chemical properties of briquettes produced from wood residues (Bamboo and Charcoal dust) and agricultural wastes (corn cobs) as well as heterogeneous combination of the particles. The study affirmed that briquettes produced from 100% MC, 100% BC and a mixture of 75% BC and 25% CD, had better quality in terms of density, agglomeration, compaction, and combustion properties with respect to high volatile matter, low ash content, high fixed carbon, and high heating value. There were little variations in the quality of the briquette produced from these three particle types compared to other heterogeneous particle types. This study has been able to confirm that agricultural wastes alongside wood waste can be utilized in producing quality briquettes. As such, wood wastes from Bamboo and a combination of Bamboo and charcoal dust particle type using molasses as a binder are suitable for briquette production due to better combustion performance. Furthermore, utilization of bamboo plant will provide alternative biomass feedstock sources for briquette production and help in the restoration of already destroyed forests in Uganda.
More studies to establish the combustion properties of more heterogeneous particle types that promote the utilization of wood and agro-wastes such as bamboo and Maize cobs are highly recommended. In order to reduce deforestation, the use of charcoal dust for briquette production should completely be discouraged.