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Prof. Mikio Nakamura
Toho University
, Japan


Email: mnakamu@med.toho-u.ac.jp


1974  Ph.D., Physical Organic Chemistry, University of Tokyo, Japan.

Publications (selected)

1. Formation and characterization of six-coordinate iron(III) complex with the most ruffled porphyrin ring, A. Ikezaki, M. Nakamura, Dalton, in press, DOI: 10.1039/C1DT10042D, 2011

2. Electronic Structure of Highly Ruffled Low-Spin Iron(III) Porphyrinates with Electron Withdrawing Heptafluoropropyl Groups at the meso Positions. A. Tozuka, Y. Ohgo, A. Ikezaki, M. Taniguchi, M. Nakamura, Inorg. Chem. 49, 10400-10408, 2010

3. Models for Cytochromes c’: Observation of an Extremely Labile Spin State in Mono(Imidazole) Complexes of Saddle Shaped Iron(III) Porphyrinates. A. Ikezaki, M. Takahashi, M. Nakamura,  Angew. Chem. Int. Ed. 48, 6300-6303, 2009.

4. Is cyanide really a strong field ligand? M. Nakamura, Angew. Chem. Int. Ed. 48, 2638-2640, 2009.

5. NMR studies on the electronic structure of one-electron oxidized complexes of iron(III) porphyrinates, A. Ikezaki, Y. Ohgo, M. Nakamura, Coord. Chem. Rev. 253, 2056-2069 2009.

6. Electronic structure of five- and six-coordinate iron(III) tetraazaporphyrin complexes: Pyrrole-Ca chemical shift as a useful probe,  T. Ikeue, S. Kurahashi, M. Handa, T. Sugimori, M. Nakamura J. Porphyrin. Phthalocyanines, 9, 1041-1049, 2008.

7. Factors That Stabilize the (dxz, dyz)3(dxy)1(dz2)1 Electron Configuration in Iron(III) Porphyrinates: A Case of Bis(benzaldehyde) Complex, A. Ikezaki, Y., Ohgo, T. Watanabe, M. Nakamura, Inorg. Chem. Commun. 11, 1199-1202, 2008.

8. Electronic Structure of Six-Coordinate Iron(III) Monoazaporphyrinates. K. Nakamura, A. Ikezaki, Y. Ohgo, T. Ikeue, S. Neya, M. Nakamura, Inorg. Chem. 47, 10299-10307, 2008.

9. Bis(1-methylimidazole) Complex of Iron(III) Oxypyriporphyrin Adopting an Intermediate-spin State.  H Eguchi, Y. Ohgo, A. Ikezaki, S. Neya, M. Nakamura, Chem. Lett. 37, 768-769, 2008.

10. Electronig ground state of low-spin iron(III) porphyrinoids, M. Nakamura, Y. Ohgo, A. Ikezaki, J. Inorg. Biochem., 102, 433-445, 2008

11. Control of electronic structure of six-coordinate iron(III) porphyrin radical by means of axial ligands, A. Ikezaki, H. Tukada, M. Nakamura, Chem. Commun. 2257-2259, 2008.

12. Metal Orbital Interactions in Highly Saddled Low-Spin Iron(III) Porphyrin Complexes. Y. Ohgo, A. Hoshino, T. Okamura, H. Uekusa, D. Hashizume, A. Ikezaki, M. Nakamura, Inorg. Chem., 46, 8193-8207, 2007.

13. 13C NMR Studies of the Electronic Structure of Low-spin Iron(III) Tetraphenylchlorin Complexes, A. Ikezaki, M. Nakamura, S. Juillard, G. Simonneaux  Inorg. Chem. 45, 6728-6739, 2006

14. Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(III) porphyrin complexes at extremely low temperatures, Y. Ohgo, Y. Chiba, D. Hashizume, H. Uekusa, T. Ozeki, M. Nakamura, Chem. Commun. 2006, 1935-1937.

15. Electronic structures of highly deformed iron(III) porohyrin complexes, M. Naksmura, Coord. Chem. Review. 250, 2271-2294, 2006.