Magnetooptical Spectroscopy of the Rare-Earth Compounds: Development and Application
Uyugun Vakhidovich Valiev,John B. Gruber,Gary W. Burdick (2012) Magnetooptical Spectroscopy of the Rare-Earth Compounds: Development and Application: pp. 34-65.
Chapter 2 Optics of the 4f → 4f and 4f → 5d transitions in crystals
The following sections are included:
  • Optical properties of RE ions in crystals
  • Selection rules for the magnetic-dipole and electric-dipole optical transitions in RE ions in crystals
  • Theory of intensities of “forbidden” RE3+ electric-dipole 4f → 4f transitions in crystalline hosts
  • Modern experimental methods of measuring the 4f → 4f optical spectra of RE compounds: site-selective polarized spectroscopy (SSPS) and “hot-band” spectroscopy
  • Explanation regarding parity-allowed 4f → 5d optical transitions in RE ions within the framework of the “strong-weak” crystalline field approximation
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