Using Image Analysis for Structural and Mechanical Cha-racterization of Nanoclay Reinforced Polypropylene Com-posites
Turup Pandurangan Mohan, Krishnan Kanny
.
DOI: 10.4236/eng.2010.210103   PDF    HTML     5,304 Downloads   9,489 Views   Citations

Abstract

This paper focuses on the micromechanical study of the tensile property of Polymer-Clay Nanocomposites (PCN). Polypropylene (PP) filled with nanoclay is chosen as the PCN. Measurements of optical dispersion parameters (as discussed by Basu et al., namely, exfoliation number (ξn), degree of dispersions (χ) and agglomerate %) in PCN system were carried out using Transmission Electron Microscopy (TEM) and Optical Microscopy (OM). The experimentally obtained tensile modulus is compared with theoretically obtained modulus values from the optical dispersion parameters and observed a close matching between these values. Also, the tensile values are compared with other standard theoretical models and observed that the results obtained from optical dispersion parameters are suited well with experimental results.

Share and Cite:

T. Mohan and K. Kanny, "Using Image Analysis for Structural and Mechanical Cha-racterization of Nanoclay Reinforced Polypropylene Com-posites," Engineering, Vol. 2 No. 10, 2010, pp. 802-812. doi: 10.4236/eng.2010.210103.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] F. Perrin-Sarazin, M.-T. Ton-That, M. N. Bureau and J. Denault, “Micro- and Nano-Structure in Polypropylene /Clay Na-nocomposites,” Polymer, Vol. 46, No. 25, 2005, pp. 11624-11634.
[2] B. Q. Chen and J. R.G. Evans, “Impact and Tensile Energies of Fracture in Polymer-Clay Nanocomposites,” Polymer, Vol. 49, No. 23, 2008, pp. 5113-5118.
[3] S. Pavlidou and C. D. Papaspyrides, “A Review on Poly-mer-Layered Silicate Nanocomposites,” Progress in Polymer Science, Vol. 33, No. 12, 2008, pp. 1119-1198.
[4] C. E. Powell and G. W. Beall, “Physical Properties of Polymer/Clay Nanocomposites,” Current Opinion in Solid State and Materials Science, Vol. 10, No. 2, 2006, pp. 73 -80.
[5] N. Sheng, M. C. Boyce, D. M. Parks, G. C. Rutledge, J. I. Abes and R. E. Cohen, “Multiscale Micromechanical Modeling of Polymer/Clay Na-nocomposites and the Effective Clay Particle,” Polymer, Vol. 45, No. 2, 2004, pp. 487-506.
[6] G. Scocchi, P. Posocco, A. Danani, S. Pricl and M. O. Fermeglia, “To the Nanoscale, and beyond: Multiscale Molecular Modeling of Polymer-Clay Na-nocomposites,” Fluid Phase Equilibria, Vol. 261, No. 1-2, 2007, pp. 366 -374.
[7] T. D. Fornes and D. R. Paul, “Modeling Properties of Nylon 6/Clay Nanocomposites Using Composite Theories,” Polymer, Vol. 44, No. 17, 2003, pp. 4993-5013.
[8] S. Boutaleb, F. Za?ri, A. Mesbah, M. Na?t-Abdelaziz, J. M. Gloaguen, T. Boukharouba and J. M. Lefebvre, “Micromechanics-Based Modelling of Stiffness and Yield Stress for Silica/Polymer Nanocomposites,” International Journal of Solids and Structures, Vol. 46, No. 7-8, 2009, pp. 1716-1726.
[9] J.-J. Luo and I. M. Daniel, “Characterization and Modeling of Mechanical Behavior of Polymer/Clay Nano-composites,” Composites Science and Technology, Vol. 63, No. 11, 2003, pp. 1607-1616.
[10] G. Tanaka and L. A. Goettler, “Predicting the Binding Energy for Nylon 6,6/Clay Nanocom-posites by Molecular Modeling,” Polymer, Vol. 43, No. 2, 2002, pp. 541-553.
[11] Y.-P. Wu, Q.-X. Jia, D.-S. Yu and L.-Q. Zhang, “Modeling Young’s Modulus of Rubber-Clay Nano-composites Using Composite Theories,” Polymer Testing, Vol. 23, No. 8, 2004, pp. 903-909.
[12] S. K. Basu and Tewari, “Transmission Electron Microscopy Based Direct Mathematical Quantifiers for Dispersion in Nanocomposites,” Applied Physics Letters, Vol. 91, No. 5, 2007, p. 053105.
[13] J. C. Halpin and J. L. Kardos, “The Halping-Tsai Equations: A Review,” Polymer Engineering and Science, Vol. 16, No. 5, 1976, pp. 344-352.
[14] D. A. Bruce and J. Bicerano, “Micromechanics of Nanocomposites: Comparison of Tensile and Compressive Elastic Modulii, and Prediction of Effects of Incomplete Exfoliation and Imperfect Alignment on Modulus,” Polymer, No. 43, No. 2, 2002, pp. 269-287.
[15] T. Mori and K. Tanaka, “Average Stress in Matrix and Average Elastic Energy of Materials with Misfitting Inclusions,” Acta Metallurgica, Vol. 21, No. 5, 1973, pp. 571-574.
[16] L. J. Xiang, K. J. Jiao, W. Jiang and B. Z. Jiang, “Tensile Modulus of Polymer Nano-composites,” Polymer Engineering and Science, Vol. 42, No. 5, 2002, pp. 483-493.

Copyright © 2024 by authors and Scientific Research Publishing Inc.

Creative Commons License

This work and the related PDF file are licensed under a Creative Commons Attribution 4.0 International License.