Study on a Novel Composite Eco-Friendly Corrosion and Scale Inhibitor for Steel Surface in Simulated Cooling Water

Abstract

The use of organophosphorus inhibitor is diminishing because of its toxic effects on aquatic and other life. In this study, a composite eco-friendly phosphate-free corrosion and scale inhibitor HS has been developed using hydrolyzed polymaleic anhydride (HPMA), sodium gluconate, Zn2+ synergist and sulfamic acid. And the formula ratio of each component is 9:5:4:2. The performance of the corrosion and scale inhibitor was evaluated by weight loss experiment and the static scale inhibition test, respectively. The results indicated that HS had positive corrosion and scale inhibition effect at a dosage of 40 mg.L–1 or higher. Potentiodynamic polarization curves indicated that HS inhibits the corrosion of steel based on controlling the anodic reaction. And the surface morphology of the carbon steel was studied by scan-ning electronic microscope (SEM). The inhibition effects were due to the formation of protective films.

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D. Zeng and W. Qin, "Study on a Novel Composite Eco-Friendly Corrosion and Scale Inhibitor for Steel Surface in Simulated Cooling Water," Journal of Surface Engineered Materials and Advanced Technology, Vol. 2 No. 3, 2012, pp. 137-141. doi: 10.4236/jsemat.2012.23022.

Conflicts of Interest

The authors declare no conflicts of interest.

References

[1] S. H. You, D. H. Tseng, G. L. Guo and J. J. Yang, “The Potential for the Recovery and Reuse of Cooling Water in Taiwan,” Resources, Conservation and Recycling, Vol. 26, No. 1, 1999, pp. 53-70. doi:10.1016/S0921-3449(98)00075-5
[2] R. F. Zhuang and X. Xie, “Synthesis of 1-Amino-ethy- lidenediphosphonic Acid (AEDP) and Its Performance as Scale and Corrosion Inhibitor,” Chinese Journal of Applied Chemistry, No. 5, 1988, pp. 90-92.
[3] K. Gehan, A. Lockey and M. Rao, “Chemical Treatments to Control Corrosion in Open Cooling Water Systems,” Corrs. Assoc., Corrosion/91, 1991, pp. 15.
[4] Z. Amjad and R. W. Zuhl, “Calcium Carbonate Precipitation in the Presence of Inhibitors,” Materials Performance, No. 47, 2007, pp. 46-48. E. Wit and J. McClure, “Statistics for Microarrays: Design, Analysis, and Inference,” 5th Edition, John Wiley & Sons Ltd., Chichester, 2004.
[5] C. G. Sinn, R. Dimova and M. Antonietti, “Isothermal titration Calorimetry of the Polyelectrolyte Water Interaction and Binding of Ca2+: Effects Determining the Quality of Polymeric Scale Inhibitors,” Macromolecules, Vol. 37, No. 9, 2004, pp. 3444-3450. doi:10.1021/ma030550s
[6] K. Ravichandran, N. M. Kumar, K. Subash and T. S. N. S. Narayanan, “Mannich Base Derivatives—A Novel Class of Corrosion Inhibitors for Cooling Water Systems,” Corrosion Reviews, Vol. 19, No. 1, 2001, pp. 29-42.
[7] R. J. Ross, K. C. Low and J. E. Shannon, “Polyaspartate Scale Inhibitors—Biodegradable Alternatives to Polyacrylates,” Materials Performance, Vol. 36, No. 4, 1997, pp. 53-57.
[8] L. J. Xi and Y. J. Zhang, “Study on the Corrosion and Scale Inhibitions of Phytic Acid,” Industrial Water Treatment, Vol. 25, No. 12, 2005, pp. 27-28.
[9] R. C. Xiong, Q. Zhou and G. Wei, “Corrosion Inhibition of a Green Scale Inhibitor Polyepoxysuccinic Acid,” Chi- nese Chemical Letters, Vol. 14, No. 9, 2003, pp. 955-957.
[10] H. Q. Gao and T. He, “Research Progress on Green Corrosion and Scale Inhibitors,” Fine and Specialty Chemicals, Vol. 14, No. 9, 2006.
[11] X. P. Ou Yang and X. Q. Qiu, “Corrosion and Scale Inhibition Properties of Sodium Lignosulfonate and Its Potential Application in Recirculating Cooling Water System,” Industry & Engineering Chemistry Research, Vol. 45, No. 16, 2006, pp. 5716-5721. doi:10.1021/ie0513189
[12] C. A. Grillo, M. V. Mirí?co, M. L. Morales, M. A. Rei-gosa and M. F. L. de Mele, “Assessment of Cytotoxic and Cytogenetic Effects of a 1,2,5-Thiadiazole Derivative on CHO-K1 Cells. Its Application as Corrosion Inhibitor,” Journal of Hazardous Materials, Vol. 170, No. 2-3, 2009, pp. 1173-1178. doi:10.1016/j.jhazmat.2009.05.107
[13] R. Touir, N. Dkhireche, M. Ebn Touhami, M. Lakhrissi, B. Lakhrissi and M. Sfaira, “Corrosion and Scale Processes and Their Inhibition in Simulated Cooling Water Systems by Monosaccharides Derivatives: Part I: EIS Study,” Desalination, Vol. 249, No. 3, 2009, pp. 922-928.
[14] J. L. Parks, A. Kashayap, A. Atassi, O. Schneider and M. Edwards, “Effect of Zinc and Orthophosphate Corrosion Inhibitors on Cement-Based Pipes,” Journal American Water Works Association, Vol. 104, No. 1, 2012, pp. E1- E14.
[15] R. Touir, M. Cenoui, M. El Bakri and M. Ebn Touhami, “Sodium Gluconate as Corrosion and Scale Inhibitor of Ordinary Steel in Simulated Cooling Water,” Corrosion Science, Vol. 50, No. 6, 2008, pp. 1530-1537.
[16] S. Ramachandran, P. Fontanille and A. Pandey, “Gluconic Acid: Properties, Applications and Microbial Production,” Food Technology and Biotechnology, Vol. 44, No. 2, 2006, pp. 185-195.
[17] A. M. Abdel-Gaber, B. A. Abd-El-Nabey, E. Khamis and D. E. Abd-El-Khalek, “A Natural Extract as Scale and Corrosion Inhibitor for Steel Surface in Brine Solution,” Desalination, Vol. 278, No. 1-3, 2011, pp. 337-342. doi:10.1016/j.desal.2011.05.048

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