Prof.
Mircea Darabantu
University
Babes-Bolyai, Cluj-Napoca, Romania
Email:
darab@chem.ubbcluj.ro
Qualifications
2002 Present Full
time Professor
1997–2002 Assist.
Prof.
1990–1997 Full
time Lecturer, University Babes-Bolyai Cluj-Napoca, Chemistry and Chemical
Engineering
1984–1990
Scientist
1983-1984
Chemical Engineer, Chemical Pharmaceutical Research Institute Bucharest
1982–1983 Full
time Chemical Engineer
Publications
(Selected)
-
F. Popa, P.
Lameiras, E. Henon, O. Moldovan, A. Martinez, C. Bâtiu, Y. Ramondenc and M.
Darabantu*,“Amino-s-triazines. Synthesis and Stereochemistry of Restricted
Rotational Phenomena (I). First Use of a C-2-Substituted Serinol in Tandem with
Masked 4-Piperidone for Selective Amination of Cyanuric Chloride”. Can. J.
Chem. 2011, 89(10), 1207-1221.
-
F. Popa, P.
Lameiras, E. Henon, O. Moldovan, A. Martinez, C. Bâtiu, Y. Ramondenc and M.
Darabantu*Can. J. Chem. 2010, accepted.
-
“Synthesis and
Conformational Analysis of the First
3-Oxa-7-thia-1-r-azabicyclo[3.3.0]-c-5-octane Single Functionalised at the C-5
Position”.
-
A. But, P.
Lameiras, I. Silaghi-Dumitrescu, C. Batiu, S. Guillard, Y. Ramondenc and M.
Darabantu*Letters in Organic Chemistry, 2010, 7(4), 283-290.
-
“(Masked)serinols:
molecules, biomolecules, building-blocks, supramolecules Part (II): serinolic
approaches in current organic synthesis”M. Darabantu*Curr. Org. Synth., 2010,
7(3), 235-275.
-
“(Masked)serinols:
molecules, biomolecules, building-blocks, supramolecules Part (I): syntheses
based on serinols’ reactivity with carbonyl electrophiles”M. Darabantu*Curr.
Org. Synth., 2010, 7(2), 120-152.
-
Serinolic Approach
in the Synthesis of the 3-Oxa-7-thia-1-azabicyclo[3.3.0]octane Skeleton
Functionalised at the C-5 position” A. But, C. Batiu, Y. Ramondenc and M.
Darabantu*Revue Roumaine de Chimie, 2009, 54(2), 127-133.
-
“Serinolic
Amino-s-triazines: Iterative Synthesis and Rotational Stereochemistry Phenomena
as N-substituted Derivatives of 2-Aminopropane-1, 3-diols” M. Pintea, M.
Fazekas, P. Lameiras, I. Cadis, C. Berghian, I. Silaghi-Dumitrescu, F. Popa, C.
Bele, N. Plé and M. Darabantu* Tetrahedron, 2008, 64(37), 8851–8870.
-
“Serinolic
Amino-s-triazines: Iterative Synthesis of N-Substituted Amino-1, 3-dioxane
Derivatives from l-(p-Nitrophenyl)serinols and Rotational Stereochemistry
Phenomena” M. Fazekas, M. Pintea, P. Lameiras, A. Lesur, C. Berghian, I.
Silaghi-Dumitrescu, N. Plé and M.
Darabantu*Eur. J. Org. Chem., 2008, 2473-2494.
-
“Electrochemical
Behavior of a New s-Triazine Based Dendrimer”V. Lates, D. Gligor, M. Darabantu
and L. M. Muresan J. Appl. Electrochem., 2007, 37(5), 631-636”First Synthesis
of a G-2 Melamine Dendrimer with Serinolic Peripheral Groups”.
-
M. Darabantu*, M.
Pintea, M. Fazekas, P. Lameiras, C. Berghian, I. Delhom, I. Silaghi-Dumitrescu,
N. Plé and A. TurckLetters in Organic Chemistry, 2006, 3(12), 905-910.
-
“α-(3,7-Dioxa-r-1-azabicyclo[3.3.0]oct-c-5-ylmethoxy)-diazines
(II): Functionalisation via Directed Ortho-Metallation and Cross-Coupling
Reactions”C. Berghian, E. Condamine, N. Plé, A. Turck, I. Silaghi-Dumitrescu,
C. Maiereanu and M. Darabantu*Tetrahedron, 2006, 62(31), 7339-7354.
-
“α-(3,7-Dioxa-r-1-azabicyclo[3.3.0]oct-c-5-ylmethoxy)-diazines
(I): Synthesis and Stereochemistry. Extension to s-Triazine Series”C. Berghian,
P. Lameiras, L. Toupet, E. Condamine, N. Plé, A. Turck, C. Maiereanu and M.
-
Darabantu*Tetrahedron,
2006, 62(31), 7319-7338.
-
“First Synthesis,
Rotamerism and Herbicidal Evaluation of Substituted s-Triazines with Amino-1, 3-dioxane
Groups” M. Fazekas, M. Darabantu*, M. Pintea, P. Lameiras, C. Bele, C. Berghian
and N. PléHeterocyclic Commun., 2006, 12(2), 151-156.
-
“First Synthesis,
Rotamerism and Herbicidal Evaluation of Substituted s-Triazines with Serinolic
Fragment” M. Pintea, M. Darabantu*, M. Fazekas, P. Lameiras, C. Berghian, I.
Delhom, C. Bele and N.Plé Heterocyclic Commun., 2006, 12(2), 135-140.
-
“First Example
of Long Distance
Stereocontrolled Synthesis in
1-Aza-3,7-dioxabicyclo[3.3.0.]octane Series”C. Maiereanu, M. Darabantu*,
E. Condamine, G. Plé, Y. Ramondenc, M.
Fazekas, M. Pintea and C. BerghianHeterocyclic Commun., 2005, 11(3-4), 305-310.
-
“Electroreduction
of (1S,2S)-2-Amino-1-(4-nitrophenyl)-propane-1,3-diol Derivatives. Behaviour of
Electrogenerated Species and Application to Organic Synthesis”C. V. Cristea, C.
Moinet, M. Jitaru and M. Darabantu J. Appl. Electrochem., 2005, 35(9), 845-849.
-
“Aryl-Aryl Bond
Formation in Pyridine and Diazine Series. Diazines Part 41” L. Boully, M.
Darabantu, A. Turck and N. Plé J. Heterocyclic Chem., 2005, 42(7), 1423-1428.
-
“Metalation of
Pyridin-2-yldiazines. Use of Pyridine Ring as Ortho-Directing Group. Diazines
Part 45” C. Berghian, M. Darabantu, A. Turck and N. Plé Tetrahedron, 2005.
-
Synthesis of New
Polyaza Heterocycles. Diazines. Part 42” M. Darabantu, L. Boully, A. Turck and
N. Plé Tetrahedron, 2005, 61(11), 2897-2905.
-
First Examples of
the Conformation Chirality of Heterobicyclo[3.3.0]ctanes: 3,7-Dioxa-r-1-azabicyclo[3.3.0]oct-c-5-yl-methoxypyrazines”C.
Berghian, M. Darabantu*, P. Lameiras, N. Plé and A. TurckHeterocyclic Commun.,
2005, 11(6), 517-522.
-
3,7-Dioxa-1-azabicyclo[3.3.0]octan-2-ones Based
on l-Phenylserinols via the Ring-Ring or Ring-Chain Tautomerism
of their Imino-Derivatives”C. Maiereanu, M.
Darabantu*, G. Plé, Y. Ramondenc and L. ToupetRevue Roumaine de Chimie,2005,
50(2), 103-112.
-
“Ring-Ring
Tautomerism of Some Spirooxazolidines Derived from l-Phenylserinols”.
-
C. Maiereanu, M.
Darabantu*, G. Plé, Y. Ramondenc and C. BerghianRevue Roumaine de Chimie, 2005,
50(1), 29-40.
-
“Adjacent Ring
Directed Ortho Metallation by the 2-Pyridyl Group in 2-Pyridyldiazines”C.
Berghian, M. Darabantu*, N. Plé and A. Turck Revue Roumaine de Chimie, 2005,
50(1), 41-46.
-
“3,7-Dioxa-1-azabicyclo[3.3.0]octanes Substituted
at C-5 position. From Local to Global Stereochemistry”M.
Darabantu*, C. Maiereanu, I. Silaghi-Dumitrescu, L. Toupet, E. Condamine, Y.
Ramondenc, C. Berghian, G. Plé and N. Plé Eur. J. Org. Chem., 2004, 12,
2644-2661.
-
“Quantitative
Structure – Retention Activity Relationship of Some 1,3-Oxazolidine Systems by
RP-HPTLC and PCA” C. Sarbu, D. Casoni, M. Darabantu and C. MaiereanuJ. Pharm.
Biomed. Anal., 2004, 35(1), 213-219.
-
“A Complex Problem
of Diastereoisomerism: Synthesis and Stereochemistry of
1,4-Bis-{r-1-aza-c-5-ethyl-3,7-dioxabicyclo[3.3.0]octane-c-2-yl}-benzene C.
Maiereanu, L. Toupet, E. Condamine, I. Silaghi-Dumitrescu, G. Plé, Y. Ramondenc
and M. Darabantu* Revue Roumaine de Chimie, 2004, 49(7), 595-602.
-
“New
1,4-Disubstituted Phthalazines: Synthesis, Structure and Herbicidal
Evaluation”C. Bele and M. Darabantu* Heterocyclic Commun., 2003, 9(6), 641-646.
-
“Relative
Ortho-directing Power of Fluorine, Chlorine and Methoxy Group for the Metallation
Reaction in the Diazine Series.
Diazines XXXV” F. Toudic, A. Turck, N. Plé, G. Quéguiner, M. Darabantu, T.
Lequeux and J. C. Pommelet J. Heterocyclic Chem., 2003, 40(5), 855-860.