Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK)

Changsha,China,10.16-10.18,2010

ISBN: 978-1-935068-41-9 Scientific Research Publishing, USA

E-Book 2313pp Pub. Date: October 2010

Category: Chemistry & Materials Science

Price: $360

Title: Preparation and Antibacterial Activity of Modified Palygorskite with Quaternary Phosphonium Cations
Source: Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK) (pp 1832-1834)
Author(s): Guang-jian Dai, Department of Chemistry, Jinan University, Guangzhou, China
Xiang Cai, Department of Chemistry, Jinan University, Guangzhou, China
Xue-mei Li, Department of Chemistry, Jinan University, Guangzhou, China
Shao-zao Tan, Department of Chemistry, Jinan University, Guangzhou, China
Abstract: Modified palygorskite (DTP-PA) were prepared by introducing different content of quaternary phosphonium cation of Dodecyl triphenyl phosphonium bromide (DTP) into sodium palygorskite (Na-PA) through ion-exchange method, and the structure and performance were characterizated. The results of TGA show that the onset temperatures of the decomposition for DTP in the DTP-PA are all higher than 220℃, indicating preferable thermal stability. The SEM images show that Na-PA displays a lath-like or fibrous structure, DTP-PA is irregular shape, and the specific surface area of the DTP-PA decreased. The antibacterial activity of the DTP-PA increases with the increase of the content of DTP. DTP-PA-5 containing 18.8 % of DTP shows good antibacterial activity with the Minimal Inhibitory Concentrations (MIC) against E. coli and S. aureus of 600 mg·L-1 and 100 mg·L-1, respectively. DTP-PAs display excellent long-acting antibacterial activity.
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