Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK)

Changsha,China,10.16-10.18,2010

ISBN: 978-1-935068-41-9 Scientific Research Publishing, USA

E-Book 2313pp Pub. Date: October 2010

Category: Chemistry & Materials Science

Price: $360

Title: The Preparation and Electrochemical Performance of Li3V2(PO4)3 Cathode Material for Lithium-Ion Battery
Source: Proceedings of the 7th National Conference on Functional Materials and Applications (FMA 2010 E-BOOK) (pp 434-437)
Author(s): Jia-wei Wang, Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024
Jing Liu, Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024
Gui-ling Yang, Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024
Rong-shun Wang, Institute of Functional Materials, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024
Abstract: The Li3V2(PO4)3/C composite cathode material is synthesized via a simple carbothermal reduction reaction route using polyvinyl alcohol (PVA) as both reduction agent and carbon source. The XRD pattern shows that the as-prepared Li3V2(PO4)3/C composite has a monoclinic structure with space group P21/n. The Raman spectrum reveals that the residual carbon contains much amounts of sp2-type carbon. The sp2-type carbon can largely enhance the electronic conductivity of the Li3V2(PO4)3/C composite. This cathode material exhibits excellent electrochemical performance. The initial discharge capacities are as high as 121.4 mAh/g (0.3 C), 110.8 mAh/g (1 C), 103.2 mAh/g (3 C) and 95.3 mAh/g (5 C). The cycle ability of this material is perfect.
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